METALS AND METAL MATRIX COMPOSITES |
|
|
|
|
|
Effect of Li/Sc Composite Addition on Microstructure and Hardness of As-cast Al-Cu-Mg Alloys |
FAN Hanghang1, LIU Fei1,2,*, ZHENG Yiwei1, BAI Pucun1, CUI Xiaoming1, WANG Haibo3, JIN Liang3
|
1 College of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China 2 Bin Zhou Bohai Piston Co., Ltd., Binzhou 256602, Shangdong, China 3 Inner Mongolia Synthetic Chemical Engineering Institute, Hohhot 010010, China |
|
|
Abstract Al-Cu-Mg alloys have many advantages, such as excellent specific strength, processing performance and corrosion resistance, which are widely used in aerospace and other fields. However, when the alloys are in service in an environment above 250 ℃, the nanoscale precipitated phases should be coarsen rapidly, and the strengthening effect decreases significantly, which results in a serious deterioration of the alloys’ performance. In this work, took the Al-Cu-Mg alloys with Li/Sc composite addition as research materials, analyzed the as-cast microstructure, hardness and second phase of the alloys by OM, XRD, SEM, TEM and Vickers hardness tester. The results showed that with Li/Sc addition, the Al-Cu-Mg alloys changed from coarse dendrite structure to equiaxed crystal structure, the average grain size of α-Al decreases from 83.58 μm to 29.75 μm, and the refinement effect reached 64.41%. The hardness was increased from HV88.73 to HV116.70, an increase of 31.52%. The strengthening mechanism of the alloys was fine grain strengthening and second phase strengthening. There was composition segregation in the alloys. some Cu elements are enriched on the grain boundary, forming a network distribution of Al2CuMg phase and bulk Al2Cu phase, while in the grain there were bulk Al6CuLi3 quasicrystal phase, Al3Sc phase and AlCuSc phase, and chain distribution of Al2CuMg phase. Among them, AlCuSc phase, as a harmful phase in the alloy, consumed a part of Sc and Cu elements during nucleation, which would result in a decrease in the volume fraction of other strengthening phases to decrease the strengthening effect. The formation of this phase should be reduced.
|
Published: 25 December 2024
Online: 2024-12-20
|
|
Fund:Natural Science Foundation of Inner Mongolia Autonomous Region (2022FX06,2023LHMS05015),Basic Research Funds for Universities Affiliated to Inner Mongolia Autonomous Region (JY20220184,ZTY2023047),Research Program Supported by Inner Mongolia University of Technology (BS2021043),and Central Government Funds for Guiding Local Science and Technology Development (2023ZY0012). |
|
|
1 Li H Z, Liao H J, Liang X P, et al. Materials Science Forum, 2014, 788, 208. 2 Williams J C, Starke E A. Acta Materialia, 2003, 51, 5775. 3 Wang S, Guo E J, Feng Y C, et al. Materials Reports, 2023, 37(11), 150 (in Chinese). 王帅, 郭二军, 冯义成,等. 材料导报, 2023, 37(11), 150. 4 Chen J, Liao H, Wu Y, et al. Materials Science and Engineering: A, 2020, 772, 138819. 5 Fu J W, Cui K, Wang J C. The Chinese Journal of Nonferrous Metals, 2021, 31(7), 1827 (in Chinese). 付俊伟, 崔凯, 王江春. 中国有色金属学报, 2021, 31(7), 1827. 6 Gao Y H, Liu G, Sun J. Acta Metallurgica Sinica, 2021, 57(2), 129 (in Chinese). 高一涵, 刘刚, 孙军. 金属学报, 2021, 57(2), 129. 7 Feng C H, Yu J, Hao M, et al. Journal of Aeronautical Materials, 2020, 40(1), 1 (in Chinese). 冯朝辉, 于娟, 郝敏, 等. 航空材料学报, 2020, 40(1), 1. 8 Yang R, Yang J, Xie K, et al. Journal of Materials Research, 2019, 34(15), 2714. 9 Ball M D, Lloyd D J. Scripta Metallurgica, 1985, 19(9), 1065. 10 Vecchio K S, Williams D B, et al. Philosophical Magazine B: Physics of Condensed Matter, 1988, 57, 535. 11 Yang C, Zhang P, Shao D, et al. Acta Materialia, 2016, 119, 68. 12 Ding Q, Xu X J, Wang C S. Chinese Journal of Rare Metals, 2017, 41(8), 850 (in Chinese). 丁清, 许晓静, 汪成松. 稀有金属, 2017, 41(8), 850. 13 Xue H, Yang C, Geuser F D, et al. Nature Materials, 2023, 22(4), 434. 14 Zhang X, Wu G, Zhang L, et al. Journal of Alloys and Compounds, 2019, 788, 367. 15 Wu G, Zhang X, Zhang L, et al. Journal of Alloys and Compounds, 2021, 875, 1. 16 Liu X, Guo Z, Xue J, et al. Materials Science and Engineering, 2020, 771, 138657. 17 Bai Z H, Luo B H. Materials Reports, 2003(7), 6 (in Chinese). 柏振海, 罗兵辉. 材料导报, 2003(7), 6. 18 Zhang X L. Study on microstructural evolution and mechanical behaviors of cast Al-2Li-2Cu alloys. Ph. D. Thesis, Shanghai Jiao Tong University, China, 2020 (in Chinese). 张小龙. 铸造Al-2Li-2Cu合金微观组织和力学行为研究. 博士学位论文, 上海交通大学, 2020. 19 Tan Y T. Experimental investigation of equilibrium phase diagram and liquidus surface in the Al-rich part of Al-Cu-Mg-Zn quaternary system. Master’s Thesis, Guang Xi University, China, 2016 (in Chinese). 覃雨婷. Al-Cu-Mg-Zn四元系富铝端平衡相图及液相面投影图的实验研究. 硕士学位论文, 广西大学, 2016. 20 Tao H J, Li S T, Liu J L, et al. Materials Science and Engineering of Powder Metallurgy, 2008(5), 249 (in Chinese). 陶辉锦, 李绍唐, 刘记立, 等. 粉末冶金材料科学与工程, 2008(5), 249. 21 Wang R H, Hu C Z, Gui J N. Quasicrystal physics, Science Press, China, 2004, pp.95 (in Chinese). 王仁卉, 胡承正, 桂嘉年. 准晶物理学. 科学出版社, 2004, pp.95. 22 Meng X R, Wu R Z, Zhang M L. Foundry Technology, 2009, 30(1), 116 (in Chinese). 孟祥瑞, 巫瑞智, 张密林. 铸造技术, 2009, 30(1), 116. 23 Ludwig T H, Schaffer P, Arnberg L. In:14th international conference on aluminium alloys (ICAA14), Trondheim, Norway, 2014. 24 Cui X M, Meng C, Shi B, et al. Rare Metal Materials and Engineering, 2022, 51(7), 2529 (in Chinese). 崔晓明, 孟闯, 石博, 等. 稀有金属材料与工程, 2022, 51(7), 2529. 25 Deng A H. Nonferrous Metal Materials and Engineering, 2000, 21(4), 190 (in Chinese). 邓安华. 有色金属材料与工程, 2000, 21(4), 190. |
|
|
|