高比电容MOF衍生的介孔球状Co<sub>3</sub>O<sub>4</sub>/NiO/CuO

doi:10.11896/cldb.22110033

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (19556KB)
Export: BibTeX | EndNote (RIS)

Abstract CoNiCu-MOF metal-organic frames were synthesized by a solvothermal method, and the Co₃O₄/NiO/CuO electrode materials were prepared by a subsequent calcination of CoNiCu-MOF. The morphology, specific surface area, cyclic voltammetric curves at different scanning speeds, galvanostatic charge/discharge curves at different current densities, and the cyclic stability of the materials were measured. An asymmetric supercapacitor device was assembled with Co₃O₄/NiO/CuO and activated carbon as the positive and negative electrodes, respectively, and its electrochemical properties were measured. Results showed that the Co₃O₄/NiO/CuO material had a porous structure and a large specific surface area (50.24 m²·g^-1). The specific capacitance of Co₃O₄/NiO/CuO was as high as 3 682.2 F·g^-1 at a current density of 1 A·g^-1. The maximum energy density of the assembled Co₃O₄/NiO/CuO∥AC asymmetric supercapacitor achieved up to 186.8 Wh·kg^-1 within a potential window of 1.45 V and a power density of 7 249.8 W·kg^-1. The excellent performance of Co₃O₄/NiO/CuO as a supercapacitor electrode material makes it have a wide application prospect as energy storage devices.

Key words： supercapacitor metal-organic frame electrochemistry activated carbon

Published: 25 June 2024 Online: 2024-07-17

CLC number:

O614

Fund:Major Scientific and Technological Innovation Projects in Shandong Province (2019JZZY010343).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	GAO Yaqian
	ZHAO Yajuan
	XIE Huidong
	HU Changyu
	WANG Yibo
	WANG Kangkang
	YANG Chang

Cite this article:

GAO Yaqian,ZHAO Yajuan,XIE Huidong, et al. Mesoporous Spherical Co₃O₄/NiO/CuO Derived from MOF with High Specific Capacitance[J]. Materials Reports, 2024, 38(12): 22110033-7.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.22110033 OR http://www.mater-rep.com/EN/Y2024/V38/I12/22110033

1 Khan I, Baig N, Ali S, et al. Energy Storage Materials, 2021, 35, 443.
2 Wu Z P, Lu X F, Zang S Q, et al. Advanced Functional Materials, 2020, 30(15), 1910274.
3 Chen S H, Qiu L, Cheng H M. Chemical Reviews, 2020, 120(5), 2811.
4 Chen J X, Zhu R J, Sheng N, et al. Journal of Chemical Industry and Engineering, 2022, 73(9), 4194 (in Chinese).
陈健鑫, 朱瑞杰, 盛楠, 等. 化工学报, 2022, 73(9), 4194.
5 Dou Q, Park H S. Energy & Environmental Materials, 2020, 3(3), 286.
6 Choudhary N, Li C, Moore J, et al. Advanced Materials, 2017, 29(21), 1605336.
7 Liu Y, Li G, Guo Y, et al. ACS Applied Materials & Interfaces, 2017, 9(16), 14043.
8 Raza W, Ali F, Raza N, et al. Nano Energy, 2018, 52, 441.
9 Wang Y G, Song Y F, Xia Y Y. Chemical Society Reviews, 2016, 45, 5925.
10 Ren J W, Wang Y, Cai W F. Chemical Industry and Engineering, 2022, 39(5), 78 (in Chinese).
任建伟, 王燕, 蔡旺锋. 化学工业与工程, 2022, 39(5), 78.
11 Chen X, Paul R, Dai L. National Science Review, 2017, 4(3), 453.
12 Hosaka T, Kubota K, Hameed A S, et al. Chemical Reviews, 2020, 120(14), 6358.
13 Zuo W H, Li R Z, Zhou C, et al. Advanced Science, 2017, 4(7), 1600539.
14 Zhou Y, Mao Z, Wang W, et al. ACS Applied Materials & Interfaces, 2016, 8(42), 28904.
15 Cheng J Y, Chen S M, Chen D, et al. Journal of Materials Chemistry A, 2018, 6(41), 20254.
16 Silva P, Vilela S M F, Tome J P C, et al. Chemical Society Reviews, 2015, 44, 6774.
17 Xia W, Mahmood A, Zou R, et al. Energy & Environmental Science, 2015, 8, 1837.
18 Sun L, Hendon C H, Minier M A, et al. Journal of the American Chemical Society, 2015, 137(19), 6164.
19 Wang L, Han Y, Feng X, et al. Coordination Chemistry Reviews, 2016, 307, 361.
20 Hong D H, Shim H S, Ha J, et al. Bulletin of the Korean Chemical So-ciety, 2021, 42(7), 956.
21 Xiao Y, Guo X, Yang N, et al. Journal of Energy Chemistry, 2021, 58, 508.
22 Han Y, Zhao M, Dong L, et al. Journal of Materials Chemistry A, 2015, 3(45), 22542.
23 Li S, Duan Y, Teng Y, et al. Applied Surface Science, 2019, 478, 247.
24 Bigdeli H, Moradi M, Hajati S, et al. Physica E-Low-Dimensional Systems & Nanostructures, 2017, 94, 158.
25 Salunkhe R R, Tang J, Kamachi Y, et al. ACS Nano, 2015, 9(6), 6288.
26 Zheng J H, Zhang R M, Wang X G, et al. Research on Chemical Intermediates, 2018, 44(9), 5569.
27 Liu Y, Cao X, Jiang D, et al. Journal of Materials Chemistry A, 2018, 6(22), 10474.
28 Mustaqeem M, Naikoo G A, Rahimi F, et al. Journal of Energy Storage, 2022, 51, 104330.
29 Wang G, Huang J, Chen S, et al. Journal of Power Sources, 2011, 196(13), 5756.
30 Veeman S, Karuppuchamy S. Ceramics International, 2022, 48(18), 26806.
31 Zhang Y X, Kuang M, Wang J J. CrystEngComm, 2014, 16, 4892.
32 Fang Z, Rehman S U, Sun M, et al. Journal of Materials Chemistry A, 2018, 6(42), 21131.
33 Vijayakumar S, Nagamuthu S, Muralidharan G. ACS Sustainable Chemistry & Engineering, 2013, 1(9), 1110.
34 Yan L, Niu L, Shen C, et al. Electrochimica Acta, 2019, 306, 529.
35 Guan C, Zhao W, Hu Y, et al. Nanoscale Horizons, 2017, 2(2), 99.
36 Jana S, Mondal A, Ghosh A. Applied Catalysis B-Environmental, 2018, 232, 26.
37 Mohamed S G, Hussain I, Sayed M S, et al. Journal of Alloys and Compounds, 2020, 842, 155639.
38 Wang Y, Liu Y, Wang H, et al. ACS Applied Energy Materials, 2019, 2(3), 2063.
39 Zhang Y, Wang G, Ma W, et al. Dalton Transactions, 2018, 47(32), 11176.
40 Hussain I, Iqbal S, Hussain T, et al. Materials Today Physics, 2022, 23, 100655.
41 Khalafallah D, Miao J, Zhi M, et al. Journal of the Taiwan Institute of Chemical Engineers, 2021, 122, 168.
42 Garakani M A, Abouali S, Xu Z L, et al. Journal of Materials Chemistry A, 2017, 5(7), 3547.
43 Lai F, Miao Y E, Zuo L, et al. Small, 2016, 12(24), 3235.
44 Su X L, Chen J R, Zheng G P, et al. Applied Surfance Science, 2018, 436, 327.
45 Li S, Duan Y, Teng Y, et al. Applied Surface Science, 2019, 478, 247.
46 Zhu F F, Liu Y, Yan M, et al. Journal of Colloid & Interface Science, 2017, 512, 419.