MULTI SCALE RARE EARTH CRYSTAL MATERIALS AND THEIR APPLICATIONS |
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Research Progress of Cerium Dioxide Supported Catalyst |
SUN Fuli, ZHANG Wei, YU Yifan, SHENG Yinxiao, ZHUANG Guilin*
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Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China |
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Abstract At present, the transformation of the global energy structure is accelerating the construction of green, safe and sustainable development. The energy conversion is one of the most important. The exploration of efficient catalyst is an important branch to solve this problem. Cerium dioxide(CeO2), as a rare earth oxide catalyst or an excellent carrier of heterogeneous catalysts, has unique geometric and electronic structural properties (such as rich oxygen site, Ce valence tautomization(Ce3+↔Ce4+), etc.), which can effectively affect the performance of catalysts through geometric and electronic effects. In recent years, CeO2-based supported catalysts have been widely explored and applied in chemical, energy, environment, materials and other fields, effectively helping to solve urgent problems such as energy conversion, environmental pollution. Although there have been reviews on CeO2-based supported catalysts, they mainly focus on single catalytic directions(such as electrocatalysis or thermal catalysis)and lack a systematic overview. In this paper, the research progress of CeO2-based supported catalysts is summarized from two aspects: (Ⅰ) preparation and synthesis of CeO2 and CeO2-based supported catalysts; (Ⅱ) study on the structure-activity of various CeO2 catalysts in electrocatalysis, photocatalysis, thermal catalysis and photothermal catalysis. A comprehensive review of CeO2-based supported catalysts will be helpful for its practical application in various fields.
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Published: 10 February 2023
Online: 2023-02-23
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Fund:The National Natural Science Foundation of China(22072135), the Natural Science Foundation of Zhejiang Province(LR19B010001), the Fund of Zhejiang China Tobacco Industry Co., Ltd(ZJZY2019C001) and the Natural Science Foundation of Shandong Province(ZR2020ZD35). |
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