米粒型氯插层NiFe层状双金属氢氧化物作为新概念氯离子电池正极材料

doi:10.11896/cldb.23070158

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Abstract The new type of anion shuttle battery representing by thechloride-ion battery (CIB), is considered to be one of the competitor for the ‘next generation' large-scale electrochemical energy storage system, owing to their significant safety advantages and low cost. However, it is still a great challenge to exploit high performance cathode materials for the practical application of CIBs. Layered double hydroxides (LDHs) have been considered as highly potential cathodes for CIBs because of their tunable interlayer spacing and unique topological transformation characte-ristic. Herein, the chloride inserted grain-like NiFe LDH (g-NiFe-Cl LDH) with large specific surface area is prepared using the MIL-88A as precursor through the hydrolysis process followed by anion exchange methode. The g-NiFe-Cl LDH could not only overcome the inherent defects of laminated stack by LDHs nanosheets, but also increase the exposure rate of electrochemical active sites, which accordingly improves the effective contact between electrode and electrolyte and promotes the chloride ion diffusion kinetics. The g-NiFe-Cl LDH is then used as cathode for CIB, which delivers a maximum discharge specific capacity of 286.1 mAh/g and a stable capacity of 155.3 mAh/g over 200 cycles. The Cl-storage mechanism of g-NiFe-Cl LDH cathode is also revealed that the reversible intercalation/deintercalation of chloride ions in LDH gallery along with the oxidation state changes in Ni²⁺/Ni³⁺ and Fe²⁺/Fe³⁺ oxidation couples. This work proviedes some new insights for the design and performance enhancement for the new LDHs-based anionic energy storage system.

Key words： chloride ion batteries (CIBs) layered double hydroxides (LDHs) metal-organic framework (MOF) anionic energy storage system chloride ions intercalation/de-intercalation mechanism

Published: 10 November 2023 Online: 2023-11-10

CLC number:

O646

Fund:Fundamental Research Funds for the Central Universities (2022QN1090).

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	Articles by authors
	YIN Qing
	YANG Shuhan
	SONG Zhihao
	ZHAO Zeyu
	LI Yongzhi
	ZHAO Danyang
	QI Jiqiu
	SUI Yanwei

Cite this article:

YIN Qing,YANG Shuhan,SONG Zhihao, et al. Chloride Inserted Grain-like NiFe Layered Double Hydroxide Cathode for the New Concept of Chloride Ion Battery[J]. Materials Reports, 2023, 37(21): 23070158-8.

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http://www.mater-rep.com/EN/10.11896/cldb.23070158 OR http://www.mater-rep.com/EN/Y2023/V37/I21/23070158

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