高熵合金抗氧化性能研究现状及展望

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Abstract High-entropy alloys (HEAs) are newly developed alloys which exhibit better mechanical properties than conventional alloys. After 15 years of development, a series of excellent alloy systems have been developed. 3d transition HEAs have good mechanical properties and fracture toughness under low temperature. Refractory HEAs have a special high temperature strength. Lightweight HEAs have extremely high specific strength compared with conventional light alloys. Compared with traditional alloys, there is a wider space for HEAs design on composition and structure.
It is necessary to pay attention to both the mechanical properties and environmental resistance of the materials, especially the oxidation resis-tance, for practical industrial applications. In recent years, researchers have realized that rapid oxidation under high-temperature conditions limits the application under high temperature of HEAs. The addition of alloying elements and their content are the key factors affecting the corrosion resistance and application of traditional alloys and HEAs. The main method of improving the oxidation resistance of HEAs is by adding an approp-riate amount of antioxidant components, and research is being conducted to improve the oxidation resistance without reducing their mechanical properties too much.
At present, some alloy systems with both high-temperature mechanical properties and oxidation resistance have been developed, such as AlCrMoNbTi, which have good mechanical properties and retain good antioxidation resistance at the same time. It has been confirmed in various HEAs systems that the addition of Al and Cr, which are used as conventional antioxidation elements in various alloys, effectively improve the oxidation resistance. In addition, some composite oxide coatings also exhibit a good protective effect, such as CrTaO₄. However, it has also been found that the combination of some elements, such as the addition of Ti in the Al-containing alloy and the addition of Nb in the Cr-containing alloy, will reduce the oxidation performance and invalidate the protective film.
This review will summarize the basic oxidation behavior of HEAs and examine the effects of key alloying elements such as Al, Cr, Si and other conventionally used elements on the oxidation resistance of HEAs in recent works. This work will provide a reference for the design of balanced HEAs mechanics and antioxidation corrosion performance by analyzing the current data as well as provide ideas for the industrial application of HEAs.

Key words： high-entropy alloy oxidation resistance key alloy elements

Published: 25 November 2019

CLC number:

TG146. 4+18

Fund:This work was financially supported by the National Natural Science Foundation (91860202).

About author:: Xiaomeng Yang received his bachelor’s degree from Dalian University of Technology in 2017. He is currently pursuing his master’s degree at the Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology under the supervision of Prof. Yanhui Chen. His research has focused on the oxidation resistance of high entropy alloys.
Yanhui Chen received her Ph.D. degree in condensed matter physics in Beijing University of Technology (BJUT) in Sep. 2008. She worked as postdoct fellow in 2008.10—2010.10 in University of Science and Techno-logy (USTB) and then move to Trinity college Dublin Ireland (TCD) for IRSCSET postdoc research in 2010.11—2014.2. 2014.3 she began to work in BJUT in Institute of Microstructure and Property of Advanced Materials. She got excellent paper of microscopy society (2008) and Ministry of Science and Technology in 2009. Her research focused on relationship between microstructure of metal and their properties, especially on superalloys. She had published more than 60 papers and presi-ding over the fund including National Natural Science Foundation of China and Beijing Natural Science Foundation.

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Cite this article:

YANG Xiaomeng,AN Zibing,CHEN Yanhui. Review and Perspective on Oxidation Resistance of High-Entropy Alloys[J]. Materials Reports, 2019, 33(Z2): 348-355.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2019/V33/IZ2/348

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