物理化学活化法制备红麻杆基活性炭及其表征

doi:10.11896/cldb.201901024

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1698KB)
Export: BibTeX | EndNote (RIS)

Abstract The activated carbon was prepared from kenaf rod by conventional chemical activation and physico-chemical coupling activation. The appropria-te preparation parameters of kenaf rod based activated carbon prepared by physico-chemical coupling activation were investigated by taking three factors including activation time, activation temperature and phosphoric acid concentration into consideration. The surface functional groups, morphology characteristics, specific surface area and pore structure characteristics of the prepared activated carbon were characterized by Fourier transform infrared spectrometer(FTIR), scanning electron microscopy(SEM), automatic specific surface area and pore size analyzer(ASAP). The results indicated that the optimum preparation conditions of kenaf rod based activated carbon were phosphoric acid mass concentration of 5%, activation time of 120 min, activation temperature of 850 ℃. Under this preparation conditions, the activated carbon prepared by physico-chemical coupling activation possessed well developed mesoporous structure and contained abundant functional groups like carbonyl group, hydroxyl group and carboxyl group. The iodine adsorption value, specific surface area and total pore volume of the prepared activated carbon were 1 148 mg/g, 1 636.94 m²/g and 0.95 cm³/g, which were about 1.4 times, 2 times and 2 times of that of the ones prepared by conventional chemical activation. Compared to single chemical activation process, physico-chemical coupling activation plays an important role in the formation, developing and regulation of activated carbon pore structure by taking the advantage of synergistic activation of phosphoric acid and water vapor.

Key words： physico-chemical coupling activation kenaf rod phosphoric acid mesoporous activated carbon adsorption

Published: 24 January 2019

CLC number:

TQ424.1

Fund:This work was financially supported by the Natural Science Foundation of China (31400510, 31770611), Fujian Special Fundation for Science and Technology (2014NZ0003), Youth Research Projects in Fujian Provincial Education Hall (JAT160684), Fujian University’s New Century Talents Support Program.

About author:: Xing Lin received his B.S. Degree in material science and engineering from Fujian Agriculture and Forestry University in 2015. He is currently pursuing his M.S. Degree at Fujian Agriculture and Forestry University under the supervision of Prof. Biao Huang. His research has focused on biomass activated carbon material.
林星,男,硕士研究生。2015年6月毕业于福建农林大学,获得工学学士学位。同年9月,在本校材料工程学院攻读硕士学位,主要从事生物质炭材料的研究。

Biao Huang received his B.S. degree in chemical industry of forest product from Fujian College of Forestry in 1988 and received his Ph.D. degree in forestry engineering from Nanjing Forestry University in 2004. He is currently teaching at College of Material Engineering, Fujian Agriculture and Forestry University. He is an amiable professor who not only has made great achievements in his academic career, but also was strict with himself in life. His research interests include plant fiber chemistry and application, fine chemicals forest products and activated carbon material.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LIN Xing
	LIN Guanfeng
	HUANG Biao

Cite this article:

LIN Xing,LIN Guanfeng,HUANG Biao. Synthesis of Activated Carbon from Kenaf Rod by Physico-chemical Coupling Activation and Its Characterization[J]. Materials Reports, 2019, 33(1): 198-202.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.201901024 OR http://www.mater-rep.com/EN/Y2019/V33/I1/198

Wang G P,Zhang L,Zhang J J.Chemical Society Reviews,2012,41(2),797.2 Zhang X X, Wang X. Journal of Forestry Engineering,2016,1(3),58(in Chinese).张晓雪,王欣.林业工程学报,2016,1(3),58.3 Chang K L, Chen C C, et al. New Carbon Materials,2014,29(1),47.4 Guo H, Zhang J S, Zhu T X, et al. Materials Review B: Research Papers,2016,30(2),24(in Chinese).郭晖,张记升,朱天星,等.材料导报:研究篇,2016,30(2),24.5 Mazlan M A F,Uemura Y,et al. Procedia Engineering,2016,148(6),530.6 Xu J T, Qi J M, et al. Straits Science,2016,7(1),128(in Chinese).徐建堂,祁建民,等.海峡科学,2016,7(1),128.7 Mastosh I, Sato M A. Journal of Wood Science,2009,55(4),283.8 Inagaki M, Nishikawa T, Sakuratani K, et al. Carbon,2004,42(4),890.9 Cuerda C E M, Maci G A, Dazdez M A, et al. Microporous and Mesoporous Materials,2008,111(1-3),523.10 Yang Y, Li L, Sun Z Y, et al. Science Technology and Engineering,2012,12(24),6132(in Chinese).杨颖,李磊,孙振亚,等.科学技术与工程,2012,12(24),6132.11 Qiu J, Ning P, Wang X, et al. Frontiers of Environmental Science & Engineering,2016,10(1),11.12 Ramanujan R V, Purushothama S, Chia M H. Materials Science and Engineering C,2007,27(4),659. 13 Pak S H, Jeon M J, Jeon Y W, et al. International Biodeterioration ＆ Biodegradation,2016,113(4),195. 14 Hu L J, Wu F, Peng S Z, et al. Chemistry,2016(3),205(in Chinese).胡立鹃,吴峰,彭善枝,等.化学通报,2016(3),205.15 Sun L M, Zhang L P, Xue J H, et al. Journal of Chemical and Biological Engineering,2016,33(3),5(in Chinese).孙龙梅,张丽平,薛建华,等.化学与生物工程,2016,33(3),5.16 Lin X, Yang X, Cai Z H, et al. Biomass Chemical Engineering,2018,52(3),29(in Chinese).林星,杨旋,蔡政汉,等.生物质化学工程,2018,52(3),29.17 Wei X Q, Li Q H, et al. New Carbon Materials,2015,30(6),579.18 Chen W T, Ran Q C, Cai X Z, et al. CIESC Journal,2016,67(S1),353(in Chinese).陈文婷,冉启成,蔡献宗,等.化工学报,2016,67(S1),353.19 Islam M A, Ahmed M J, Khanday W A, et al. Journal of Environmental Management,2017,203(1),237.20 Abdel-ghani N T, Chaghaby G A, Gammal M H, et al. New Carbon Materials,2016,31(5),492.21 Kwiatkowski M, Broniek E. Colloids and Surfaces A,2017,529(6),443.22 Yu L W, Daisuke T, Zuo S L, et al. Bio Resources,2015,10(2),2406.23 Zhang G Z, Zhao S X, Chen M H, et al. Forestry Machinery and Woodwoking Equipment,2017,45(2),35(in Chinese). 张冠中,赵师辛,陈梦涵,等.2017,45(2),35.24 Jiang Z H, Zhang D S, Yue Y D, et al. New Carbon Materials,2008,19(4),249(in Chinese).江泽慧,张东升,岳永德,等.新型炭材料,2008,19(4),249.25 Li Y, Zhang X, Yang R, et al. RSC Advances,2015,5(41),32626.26 Song L, Zhang B, Chen J Y, et al. Chemical Industry and Engineering Progress,2014,33(6),1498(in Chinese).宋磊,张彬,陈家元,等.化工进展,2014,33(6),1498.27 Yorgun S, Yildiz D. Journal of the Taiwan Institute of Chemical Engineers,2015,53(2),122.28 Qin C, Chen Y, Gao J. Materials Letters,2014,135(2),123.29 Diana C S, Azevedo J, Cassia S, et al. Microporous and Mesoporous Materials,2007,100(1),361.30 Zuo S L. Chemistry and Industry of Forest Products,2017,37(3),1(in Chinese).左宋林.林产化学与工业,2017,37(3),1.31 Chen Y D, Huang B, Huang M J, et al. Journal of the Taiwan Institute of Chemical Engineers,2011,42(5),837.32 Qian Q R, Machida M, Tatsumoto H. Bioresource Technology,2007,98(2),353.33 Chen H L, Song L. Journal of Huaqiao University (Nature Science),2014,35(5),558(in Chinese). 陈虹霖,宋磊.华侨大学学报(自然科学版),2014,35(5),558.34 Nowicki P, Kazmierczak J, Pietrzak R. Powder Technology,2015,269(2),312.35 Niu Y L, Ma C Y, Li D X, et al. Chemical Journal of Chinese Universities,2010,31(10),1929(in Chinese).牛耀岚,马承愚,李登新,等.高等学校化学学报,2010,31(10),1929.