| NEW ENVIRONMENTAL FUNCTIONAL MATERIALS |
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| Fabrication and Water Purification Applications of MIL-53(Al)-based Functional Materials: a Review |
| SUN Xuezi1,2, WANG Chongchen1,2,*, LI Yuhang1,2
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1 Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation,Beijing University of Civil Engineering and Architecture, Beijing 100044, China
2 School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China |
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Abstract This paper reviews the fabrication strategies, morphology regulations and application (fluorescence sensors, adsorbents and photocatalysts for detecting and eliminating pollutants from water) of MIL-53(Al), NH2-MIL-53(Al) and their composites. The fabrication approaches like hydro/solvothermal methods, microwave-assisted synthesis and homogeneous phase direct synthesis along with the reaction conditions are introduced. MIL-53(Al) and NH2-MIL-53(Al) show excellent performance in detecting pollutants in water, with the characteristics of fast response time and high sensitivity. MIL-53(Al) and NH2-MIL-53(Al) can achieve adsorptive removal toward pollutants in water due to their ‘respiratory effect’, large surface area and rich active sites. The performance of MIL-53(Al) in adsorption, advanced oxidation degradation, sensing detection can be improved by compositing with other functional materials. In a word, MIL-53(Al) and NH2-MIL-53(Al), as environment-friendly environmental functional materials, show great application potential in water purification field.
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Published:
Online: 2022-10-26
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| Fund:National Natural Science Foundation of China (51878023), Beijing Natural Science Foundation (8202016), Great Wall Scholars Training Program Project of Beijing Municipality Universities (CIT&TCD20180323) and Beijing Talent Project (2020A27). |
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2022, Vol. 36 
