铝基催化剂催化水解羰基硫研究进展

doi:10.11896/cldb.22040149

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Abstract Carbonyl sulfide is widely found in blast furnace gas, coke oven gas, yellow phosphorus tail gas and various industrial waste gases, which will cause huge harm to human health, industrial production and ecological environment. Catalytic hydrolysis had received wide attention due to its good efficiency and low energy consumption. The development of hydrolysis catalysts with good catalytic activity and high stability has become the focus of research. Aluminum-based catalysts are the most widely used hydrolysis catalysts in industry at present. Among them, alumina not only has large surface area and high activity, but also has catalytic activity. Aluminum-based hydrotalcite has also been widely studied because of its unique structure and excellent performance. However, poisoning and too rapid deactivation are still a major problem that plagues hydrolysis catalysts in practical applications. This paper introduces the relevant research results of aluminum-based hydrolysis catalysts in recent years, including the more mature industrial catalysts and aluminum-containing hydrotalcite catalysts, as well as the effects of different metal modifications on hydrolysis catalysts and explains the atmospheric effects of carbonyl sulfur hydrolysis. Finally, the kinetics and mechanism of the hydrolysis reaction are reviewed, which can provide a reference for the design and research of subsequent hydrolysis catalysts with high activity and high stability.

Key words： carbonyl sulfide catalytic hydrolysis aluminum-based catalyst modification atmosphere effect

Published: 25 October 2023 Online: 2023-10-19

CLC number:

X511

Fund:National Natural Science Foundation of China (21876010).

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	Articles by authors
	ZHU Changsheng
	ZHAO Shunzheng
	TANG Xiaolong
	GAO Fengyu
	YU Qingjun
	LIU Jun
	ZHOU Yuansong
	WEN Yanfeng
	YI Honghong

Cite this article:

ZHU Changsheng,ZHAO Shunzheng,TANG Xiaolong, et al. Research Progress in Catalytic Hydrolysis of Carbonyl Sulfide by Aluminum Based Catalysts[J]. Materials Reports, 2023, 37(20): 22040149-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22040149 OR http://www.mater-rep.com/EN/Y2023/V37/I20/22040149

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