杂环砌块构筑的有机分子对钢和铜的缓蚀性能研究进展

doi:10.11896/cldb.22010137

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Abstract In modern industry, steel and copper are easily corroded by inorganic acids. In particular, acid rain is aggravated by industrial development, which can lead to serious corrosion of steel and copper. As a consequence, serious safety and economic loss and environmental pollution may be caused by copper corrosion. Therefore, it is significantly important to prevent corrosion of metals in acid media. The organic inhibitor approach receives intensive research attention to inhibit dissolution of steel and copper in acid media, because it shows various advantages such as low toxicity, high efficiency, low cost as well as environmental amicable. Adsorption of organic inhibitors on steel and copper surface can be strengthened by carried heteroatoms based on strong chemical interactions, and thus protection films may be formed. As a result, efficient corrosion inhibition of steel and copper in acid media can be achieved. Hence, carried polar heterocyclic blocks in organic corrosion inhibitors can promote tough adsorption and included apolar long fatty chains may exhibit stable orientation arraying on metal surface. Therefore, aggressive corrosion species are isolated from metal surface to achieve corrosion inhibition. Hence, in the light of research situation in corrosion inhibition of steel and copper in acid media, this paper emphasized recent two decade progress of heterocyclic blocks-based organic corrosion inhibitors for inhibiting corrosion of steel and copper in acid environments. Besides, a brief description of corrosion and corrosion inhibition of steel and copper is introduced. The corrosion inhibition efficiency of heterocyclic-contained organic compounds through chemical strategy is also analyzed and discussed, which include numbers of heterocyclic rings, numbers of carbon chains (fatty linkers) and numbers of heteroatomic functional groups and so on. The relationship between the chemical structures of organic inhibitor molecules and the corrosion inhibition properties are particularly analyzed and discussed based on experimental studies, molecular modeling and material theoretical simulation. The key future research direction and target in the field of organic corrosion inhibitors of steel and copper are also presented.

Key words： heterocyclic blocks steel and copper corrosion organic corrosion inhibitor corrosion inhibition mechanism acidic media

Published: 10 September 2023 Online: 2023-09-05

CLC number:

O626

Fund:National Natural Science Foundation of China (21376282, 21676035, 21878029), Postgraduate Innovation Project of Chongqing University (CYB18046), and Natural Science Foundation of Shandong Province (ZR2020QB180).

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	CHEN Lingli
	SHI Yueting
	LI Hongru
	WANG Xinchao
	ZHANG Shengtao
	GAO Fang

Cite this article:

CHEN Lingli,SHI Yueting,LI Hongru, et al. Research Progress on Corrosion Inhibition of Steel and Copper by Organic Molecules Constructed by Heterocyclic Blocks[J]. Materials Reports, 2023, 37(17): 22010137-15.

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http://www.mater-rep.com/EN/10.11896/cldb.22010137 OR http://www.mater-rep.com/EN/Y2023/V37/I17/22010137

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