相变复合纳米纤维的研究与应用

doi:10.11896/cldb.21060061

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Abstract Organic phase change materials(PCMs) are considered to be ideal thermal energy-storage materials due to their high energy-storage capacity, good compatibility and low cost. And polymer nanofibers display broad prospect for applications in textiles, energy sources and so on, because of their advantages of large specific surface area, regulated diameter and good flexibility. Therefore, organic PCMs and polymer nanofibers are combined to fabricate phase-change composite nanofibers with good structural-stability through various composite technologies. The composite nanofibers show potential applications in smart temperature-controlling clothing, medical care, and flexible wearable devices.
In order to comprehensively utilize the advantages of PCMs and nanofibers, and solve the leakage problem of organic PCMs in composite nanofibers, encapsulation technology of PCMs (including physical mixing method, graft co-polymerization method and nano-confinement techno-logy) and preparation methods of composite nanofibers (including hollow fiber filling method, coating method, composite spinning method and microcapsule hybrid spinning method) are compared and analyzed. Among them, the nano-constraint technology shows a variety of encapsulation types and excellent encapsulation effects. The composite spinning method has a good advantage in fiber size controllability, while the microcapsules included spinning method is quite agile for nanofibers preparation. Most researches further introduce thermally conductive fillers into fiber matrix to overcome the low thermal conductivity of phase change composite nanofibers. The fillers form an interconnected thermally conductive path in the composite material to improve the overall thermal conductivity. In addition, the application of phase-change composite nanofibers in flexible wearable devices and drugs’ delivery and controlled release is further introduced according with the frontier information of science and technology, and the expansion of its application fields is proposed.
In a word, this article summarizes the characteristics and preparation methods of phase change composite nanofibers, and it is pointed out that composite spinning method can solve the problem of leakage of phase change materials to some extent at the same time. And we clarify the research progress and shortcomings of the method to improve the low thermal conductivity of phase change composite nanofibers by adding high thermal conductivity fillers. We also have focused on the applications of phase change composite nanofibers in flexible wearable devices and drugs’ delivery and controlled release. At last, we prospect the research direction of the phase-change composite nanofibers. This review provides a reference for the preparation, exploration and application of new phase-change composite nanofibers.

Key words： phase change composite nanofiber packaging technology heat conductivity enhancement smart application

Published: 10 April 2023 Online: 2023-04-07

CLC number:

TQ342+.8

Fund:National Natural Science Foundation of China (51863005, 51462006, 51102230, 51671062, 51871065, 51971068), the Guangxi Natural Science Foundation Project (2018GXNSFDA281051, 2014GXNSFAA118401, 2020GXNSFGA297004), and the Guangxi Bagui Scholars Fundation Project.

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	Articles by authors
	SUN Zongxu
	ZHANG Huanzhi
	JING Rui
	WU Bojing
	XU Fen
	XIA Yongpeng
	SUN Lixian

Cite this article:

SUN Zongxu,ZHANG Huanzhi,JING Rui, et al. Research and Application of Phase Change Composite Nanofibers[J]. Materials Reports, 2023, 37(7): 21060061-8.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.21060061 OR http://www.mater-rep.com/EN/Y2023/V37/I7/21060061

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