INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Formation, Interaction Mechanisms and Application of Layered Double Hydroxides in Cement Concrete |
XU Chuang, ZHANG Zuhua, CHEN Muchong, SHI Caijun, LI Ning, LIU Yiwei
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Key Laboratory for Green and Advanced Civil Engineering Materials and Application Technology of Hunan Province,College of Civil Engineering,Hunan Univer-sity,Changsha 410082,China |
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Abstract Carbonization, sulfate attack and chloride-induced corrosion are the three common durability problems for concrete, and the mechanisms behind are due to the physical and chemical reactions between the cement paste or steel bar and external ions entering via concrete body. Laye-red double hydroxides (LDHs) are characterized by anion adsorption and unique layer structure, which can act as anion adsorbents in concretes and improve their durability. Although the application of LDHs in cement concrete is still at an early stage, the research on the interaction mechanisms of LDHs is relatively rich and rapidly developing. This paper provides a review on the formation mechanism of hydrotalcite-like compounds (MgAl-LDHs) and AFm phase (CaAl-LDHs) in cement concrete (including complex Portland cement and alkali-activated material systems), illustrates the interaction mechanism between LDHs and ions in concrete, and evaluates the influences of MgAl-LDHs and CaAl-LDHs on strength development and durability of cement concrete. The key problems and application prospects of LDHs as a concrete mineral additive are also proposed in this paper.
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Published:
Online: 2022-06-09
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Fund:National Natural Science Foundation of China (51638008, 51878263 ,U2001225). |
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