热致变色过渡金属配合物的变色机理及应用

doi:10.11896/cldb.21010049

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Abstract The development of smart technology is a ubiquitous trend in modern society. As they are the basis of this smart technology revolution, smart materials are the focus of much recent research. Thermochromic materials are smart materials that change their color in response to a change in external temperature. They are used in diverse applications such as smart windows, temperature sensing, anti-counterfeiting, smart textiles and color-changing paints, among many others. Several types of thermochromic materials exist. Thermochromic transition metal comp-lexes have several properties that make them attractive for application development. These include lower color-changing temperatures, distinct color changes and unique electron transfer characteristics.
The early work on thermochromic transition metal complexes focused on determining their structures and the thermochromic mechanisms. Application development was limited because of intrinsic shortcomings, such as low molar extinction coefficients and the need for solvents. In the last decade, the number of applications of thermochromic transition metal complexes has increased substantially. This is a result of advances in the use of ionic liquids, new ligands, and the integration of transition metal complexes into composites with other functional materials. Despite this progress, reviews of this area are rare.
To properly design smart thermochromic materials for specific applications, a deep understanding of the color-changing mechanism is needed. This article first describes the color-changing mechanisms of thermochromic transition metal complexes, primarily geometry changes, ligand changes and spin crossover. The article next summarizes recent progress on the applications of these complexes in temperature sensing, smart windows and other fields, and then concludes with comments on the direction of future research.

Key words： smart materials thermochromism transition metal complexes temperature sensors

Published: 25 February 2023 Online: 2023-03-02

CLC number:	O614
	TB381

Fund:Youth Program of National Natural Science Foundation of China (21805045), and Science and Technology Program of University of Jinan (XKY2067).

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	LI Liang
	ZHAO Xiuxian
	WANG Binbin
	YANG Shuaijun
	NIE Yong
	JIANG Xuchuan

Cite this article:

LI Liang,ZHAO Xiuxian,WANG Binbin, et al. Color-changing Mechanisms and Applications of Thermochromic Transition Metal Complexes:a Review[J]. Materials Reports, 2023, 37(4): 21010049-11.

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http://www.mater-rep.com/EN/10.11896/cldb.21010049 OR http://www.mater-rep.com/EN/Y2023/V37/I4/21010049

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