METALS AND METAL MATRIX COMPOSITES |
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Effect of Tensile Stress on Critical Pitting Temperature and Pitting Corrosion Behavior of 2205 Duplex Stainless Steel |
HOU Yan, CHENG Congqian, ZHAO Jie, FENG Xue, LI Ran, MIN Xiaohua
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School of Material Science and Engineering, Dalian University of Technology, Dalian 116024 |
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Abstract The effect of tensile stress on the critical pitting temperature (CPT) for 2205 duplex stainless steel (SS) was investigated using potentiostatic measurements. Potentiodynamic polarization, potentiostatic polarization, electrochemical impedance spectroscopy (EIS) were adopted to study the electrochemical corrosion behavior of 2205 duplex SS subjected to different tensile stresses at 40 ℃ and 60 ℃. The results confirmed the inverse correlation between CPT and tensile stress, with a singular point of 140 MPa, under which no pitting was observed even at 85 ℃. Potentiodynamic polarization, potentiostatic polarization and EIS indicated that below CPT the breakdown potential (Eb) and the stability of passive film declined with a tensile stress was exerted on the specimen. And moreover, the steel surface maintained in passive status during the potentiostatic polarization process. At a temperature above the CPT, stable pitting occured. With the increasing temperature, the decrease of Eb became more noticeable. The specimen which subjected to 140 MPa tensile stress underwent no pitting. This may be attributed to the crack-tip expansion and subsequent repassivation of the microcracks on surface of 2205 duplex SS under the effect of tensile stress and polarization. And in this circumstance, the electrochemical characteristic cannot denote its pitting corrosion resistance.
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Published: 03 April 2019
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Fund:This work was financially supported by the National Natural Science Foundation of China (51571051) and Collaborative Innovation Center of Major Machine Manufacturing in Liaoning. |
About author:: Yan Hou received successive postgraduate and doctoral programs of study in Dalian University of Technology since September in 2016, focusing on the research of the corrosion behavior of stainless steel.Congqian Cheng received his Ph.D. degree in mate-rials from Dalian University of Technology in 2010. |
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