镁合金表面电沉积铝工艺的研究进展

doi:10.11896/cldb.201903014

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Abstract Magnesium alloys are widely used in various fields such as military, aerospace, automobile, and electronic communication, owing to their desirable properties, including light weight, high specific strength and specific modulus, good workability, high shock resistance and impact resistance, environmental protection and recyclability, and excellent electromagnetic shielding property. However, the poor corrosion resistance of Mg alloys seriously limits their wider applications. Thus, surface protection treatment must be adopted to magnesium alloys.
The aluminum coating deposition on the surface of the magnesium alloys is considered to be the most ideal one among the many surface treatment methods, which has aroused widespread attention by virtue of its improved corrosion and wear resistance, the metal properties, light weight and easily recycled properties. The main methods of aluminum coating deposition on magnesium alloy are spray coating method, liquid diffusion method, aluminizing method, high energy beam cladding method and deposition method. Additionally, the deposition method can be further classified to sputter deposition, physical/chemical vapor deposition, and electro-deposition. Among them, the electro-deposition method is attracting increasingly attention on account of its simple equipment, convenient operation, low cost and controllable thickness and quality of the coating.
The processes of electro-deposition aluminum technology mainly include pre-treatment, electrolyte type, electrodeposition process parameters and post-plating treatment process and coating performance. Pre-treatment process is crucial which consists of grinding, alkaline degreasing, acid etching, activation treatment and pre-deposited metal underlayer. The electrolytes for electro-deposited aluminum include three types: organic solvents, ionic liquids and inorganic molten salts. Organic solvents are rarely used due to their volatility. Ionic liquids are environment-friendly and recyclable, while the high cost limits their quantity production. The low-cost inorganic molten salts demand for high deposition temperature and instrumentation. The electro-deposition process parameters are similar to the conventional aqueous solutions, including current density, electro-deposition temperature, agitation rate, additives and moisture content. Special attention should be paid to the moisture content, since even slight moisture can severely affect the quality of Al coating and even lead to unable to deposit aluminum. The post-plating treatment processes, including heat treatment and anodization, are extremely pivotal to the poor adhesion between the electro-deposited aluminum coating and the substrate. Heat treatment significantly promotes the adhesion of the coating by forming metallurgical bonding between the coating and the interface. Anodization can further ameliorate the corrosion resistance and hardness of the Al coating. Moreover, electro-deposition of alloy coating is an effective way to comprehensively improve the properties of the aluminum coating.
In this paper, the research progress of aluminum coating by electro-deposition on magnesium alloy surface is illuminated from four aspects of pre-treatment, electrolyte type, electrodeposition aluminum process parameters and post-plating treatment and properties of the coatings. The crucial technical barriers of electrodeposited aluminum on the surface of magnesium alloy are analyzed and the future development view are prospected combined the research experience on aluminum plating in our group.

Key words： Mg alloy electro-deposition Al coating pre-treatment post-treatment

Published: 13 February 2019

CLC number:

TQ15

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	YAO Tianyu
	YANG Haiyan
	ZHOU Suhong
	YE Bing
	JIANG Haiyan

Cite this article:

YAO Tianyu,YANG Haiyan,ZHOU Suhong, et al. Research Progress on the Aluminum Electro-deposition on Magnesium AlloySurface: a Review[J]. Materials Reports, 2019, 33(3): 470-478.

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http://www.mater-rep.com/EN/10.11896/cldb.201903014 OR http://www.mater-rep.com/EN/Y2019/V33/I3/470

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