碳纤维石墨化技术综述

doi:10.11896/cldb.20120255

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Abstract High-performance carbon fiber has great application prospects. The carbon content of carbon fiber can reach 99% after graphitization. The tensile modulus and conductivity can be improved greatly, and the coefficient of thermal expansion approaches to 0, which is suitable for the space environment involving a great diurnal temperature variation. Therefore, graphitized carbon fiber is extensively applied to cutting-edge technology fields such as space flight and aviation. Graphitization equipment and methods are the key aspect for preparing high-performance carbon fiber. In this paper, graphitization equipment is divided into continuous and discontinuous, indirect heating and direct heating, according to production process and heating method. Introductions were given to graphitization techniques including resistance heating, induction heating, plasma heating, microwave heating, laser heating, γ-ray heating and catalytic heating. In addition, the advantages and disadvantages of graphitization methods and equipments were summarized, meanwhile the microstructure change of carbon fiber in graphitization and its correlation with carbon fiber properties were analyzed. It will be the future development trend to optimize the traditional graphitization equipment and overcome the disadvantages of existing graphitization equipment such as high energy consumption, high cost and low efficiency. It provides important reference and experience for the future research and development of emerging graphitization process, equipment and the preparation of graphite fibers with complete structure and excellent performance.

Key words： carbon fiber graphitization structure and performance plasma

Published: 10 September 2022 Online: 2022-09-10

CLC number:

TQ342+.74

Fund:National Natural Science Foundation of China (11575252, 11775270) and Institute of Energy of Hefei Comprehensive National Science Center (19KZS206).

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	Articles by authors
	WEI Xinyu
	ZHANG Wenjin
	CHEN Longwei
	LIU Chengzhou
	LIN Qifu
	JIANG Yiman
	WANG Xiaojie

Cite this article:

WEI Xinyu,ZHANG Wenjin,CHEN Longwei, et al. Review of Graphitization Technology of Carbon Fibers[J]. Materials Reports, 2022, 36(17): 20120255-8.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20120255 OR http://www.mater-rep.com/EN/Y2022/V36/I17/20120255

1 Xu L H, Cao W Y, Hu L Q, et al. PAN-based carbon fiber, National Defense Industry Press, China, 2018, pp. 14 (in Chinese).
徐樑华, 曹维宇, 胡良全, 等. 聚丙烯腈基碳纤维, 北京国防工业出版社, 2018, pp. 14.
2 Tian Y H, Qiao W J, Zhang X J, et al. Materials Reports B:Research Papers, 2018, 32(5), 1668 (in Chinese).
田艳红, 乔伟静, 张学军, 等. 材料导报:研究篇, 2018, 32(5), 1668.
3 Tehrani M, Haugh T P, Hartman T B, et al. Composites Science and Technology, 2013, 75(2), 42.
4 Chand S. Journal of Materials Science, 2000, 35(6), 1303.
5 Kwei T K. Polymers for Advanced Technologies, 1992, 3(1), 47.
6 Guo Q F, Li W, Dong J H, et al. Advanced Engineering Materials, 2011, 194(196), 1558.
7 He F. Application and technology of carbon fiber, Chemical Industry Press, China, 2004 (in Chinese).
贺福.碳纤维及其应用技术, 化学工业出版社, 2004.
8 Khayyam H, Reza N J, Srinivas N, et al. Progress in Materials Science, 2020, 107(1), 100575.1.
9 Liu J, Wang P H, Li R Y, et al. Applied Polymer, 1994, 52(7), 945.
10 Rahaman M, Ismail A F, Mustafa A. Polymer Degradation and Stability, 2007, 92(8), 1421.
11 He F. Carbon fiber and graphite fiber, Chemical Industry Press, China, 2010 (in Chinese).
贺福. 碳纤维及石墨纤维, 化学工业出版社, 2010.
12 Sun D J, Yang J X, Zhou W H, et al. Materials Reports B:Research Papers, 2017, 31(12), 129 (in Chinese).
孙东健, 杨建校, 马国芝, 等. 材料导报:研究篇, 2017, 31(12), 129.
13 Maghe M, Creighton C, Henderson L C, et al. Journal of Materials Chemistry A, 2016, 4(42), 16619.
14 Yu Y Y, Tan J, Kai W Z, et al. Journal of Beijing University of Chemical Technology(Natural Science Edition), 2019, 46(6), 21 (in Chinese).
于瑶瑶, 谭晶, 开吴珍,等. 北京化工大学学报(自然科学版), 2019, 46(6), 21.
15 Tan J, Sha Y, Li S Y, et al. Carbon Techniques, 2016, 35(6), 47 (in Chinese).
谭晶, 沙扬, 黎三洋,等.炭素技术, 2016, 35(6), 47.
16 White T L, Paulauskas F L, Bigelow T S. US patent, US9427720, 2016.
17 Kim S Y, Lee S, Jo S, et al. Polymer, 2015, 56, 590.
18 松田至康, 隐善厚生. 中国专利, CN106458595A, 2017.
19 陈新谋, 陈刚. 中国专利, CN1696365, 2005.
20 Li B, Feng Y, Qian G, et al. Journal of Nuclear Materials, 2013, 443(1-3), 26.
21 Tzeng S S, Lin Y H. Carbon, 2008, 46(3), 555.
22 Wen Y, Xiao H, Lu Y G, et al. Materials & Design, 2012, 36(4), 728.
23 Sha Y, Yang W M, Li S Y, et al. RSC Advances, 2018, 8(21), 11543.
24 Zhang Z H, Yang W M, Tan J, et al. Chemical Industry and Engineering Progress, 2019, 38(3), 1434 (in Chinese).
张政和, 杨卫民, 谭晶,等. 化工进展, 2019, 38(3), 1434.
25 Li D F, Yang H J, Zhu M X, et al. Chemical Industry and Engineering Progress, 2004, 23(2), 168 (in Chinese).
李东风, 王浩静, 朱星明,等. 化工进展, 2004, 23(2), 168.
26 王浩静, 刘颖, 周立公.中国专利, CN1399017, 2003.
27 王浩静, 刘颖, 周立公. 中国专利, CN1399016, 2003.
28 谭晶, 王浩静, 李东风, 等. 中国专利, CN1746344, 2006.
29 Xu X J, Chu D C. Physics of gas discharge, Fudan University Press, China, 2018 (in Chinese).
徐学基, 诸定昌. 气体放电物理, 复旦大学出版社, 1996.
30 Felix P L, Kenneth Y D, Thomas M T. US patent, US6372192, 2002.
31 陈新谋,陈刚. 中国专利, CN1690261, 2005.
32 Zhang P Z. New Carbon Materials, 2002, 17(3), 52 (in Chinese).
张蓬洲. 新型炭材料, 2002, 17(3), 52.
33 Zhao C. Experimental research on energy utilization efficiency and me-dium absorption characteristics in the process of microwave heat utilization. Master's Thesis, Shandong University, China, 2015 (in Chinese).
赵超. 微波热利用过程中能量利用效率及介质吸波特性的试验研究. 硕士学位论文, 山东大学, 2015.
34 Huang M, Peng J H, Wang J Q, et al. Journal of Kunming University of Science and Technology(Science and Technology), 2005, 30(6), 15 (in Chinese).
黄铭, 彭金辉, 王家强, 等. 昆明理工大学学报(理工版), 2005, 30(6), 15.
35 Pankaj K. Dielectric materials and applications, Nova Science Press, US, 2019.
36 Tong Z F, Bi S W, Yang Y H, et al. Journal of Materials and Metallurgy, 2004, 3(2), 117 (in Chinese).
佟志芳, 毕诗文, 杨毅宏. 材料与冶金学报, 2004, 3(2), 117.
37 Santos T, Valente M A, Monteiro J, et al. Applied Thermal Engineering, 2011, 31(16), 3255.
38 张蓬洲. 中国专利, CN1385567, 2002.
39 Wu Z J, Meng L H, Liu L. Journal of Reinforced Plastics and Composites, 2014, 33(3), 242.
40 Xu Z W, Liu L S, Huang Y D, et al. Materials Letters, 2009, 63(21), 1814.
41 Li D F, Wang H J, Wang X K. Spectroscopy and Spectral Analysis, 2007, 27(11), 2249 (in Chinese).
李东风, 王浩静, 王心葵.光谱学与光谱分析, 2007, 27(11), 2249.
42 Huang Z H, Zhou H H, Peng Q L, et al. Transactions of Nonferrous Metals Society of China, 2010, 20(8), 1418.
43 Lu Y G. High performance carbon fiber, Chemical Industry Press, China, 2018 (in Chinese).
吕永根.高性能炭纤维, 化学工业出版社, 2018.
44 Tian Y H, Chang W P, Sheng Z M, et al. New Carbon Materials, 1999, 14(1), 3 (in Chinese).
田艳红, 常维璞, 沈曾民, 等. 新型炭材料, 1999, 14(1), 3.
45 Sheng Z M, Tian Y H, Chang W P, et al. Acta Materiae Compositae Sinica, 2004, 21(1), 7 (in Chinese).
沈曾民, 田艳红, 常维璞, 等. 复合材料学报, 2004, 21(1), 7.
46 Hishiyama Y, Inagaki M. Carbon, 2001, 39(1), 150.
47 Northolt M G, Veldhuizen L H, Jansen H. Carbon, 1991, 29(8), 1267.
48 Liu F, Zhu Z P, Fan L D, et al. Journal of Materials Science, 2008, 43(12), 4316.
49 Tyson C N. Journal of Physics D-Applied Physics, 1975, 8(7), 749.
50 Newcomb B A. Composites Part A: Applied Science and Manufacturing, 2016, 91(1), 262.
51 Xiao H, Lu Y G, Zhao W Z, et al. Journal of Materials Science, 2014, 49(14), 5017.
52 Fischer L, Ruland W. Colloid and Polymer Science, 1980, 258(8), 917.
53 Li D H, Lu C X, Wang L, et al. Materials Science & Engineering: A, 2017, 685, 65.
54 Zhang W X, Liu J, Gang W. Carbon, 2003, 41(14), 2805.
55 Li D H, Lu C X, Wu G P, et al. Journal of Materials Science & Techno-logy, 2014, 30(10), 1051.
56 Franklin R E. Proceedings of the Royal Society of London Series a-Mathematical and Physical Sciences, 1951, 209(1097), 196.
57 Kobayashi T, Sumiya K, Fujii Y, et al. Carbon, 2012, 50(3), 1163.
58 Sauder C, Lamon J, Pailler R. Carbon, 2004, 42(4), 715.
59 Xiao H, Lu Y G, Zhao W Z, et al. Journal of Materials Science, 2014, 49(2), 794.
60 Ye C, Wu H, Huang D, et al. Carbon Letters, 2019, 29(5), 497.
61 Qian X, Zhi J H, Chen L Q, et al. Composites Part A: Applied Science and Manufacturing, 2018, 112, 111.
62 Gupta A, Dhakate S R, Pal P, et al. Diamond and Related Materials, 2017, 78, 31.
63 Zhang Z H, Yang W M, Cheng L S, et al. ACS Sustainable Chemistry & Engineering, 2020, 8(48), 17629.
64 Wang H J, Li D F, Wang X K. New Carbon Materials, 2006, 21(2), 114.
65 Yu Y, Wu H, Huang D, et al. Carbon Techniques, 2020, 39(5), 35 (in Chinese).
余洋, 吴晃, 黄东, 等. 炭素技术, 2020, 39(5), 35.
66 Qin X, Lu Y G, Xiao H, et al. Carbon, 2012, 50(12), 4459.
67 Gong M Q, Zhang C T, Wang R H. Journal of Chongqing University of Technology (Natural Science), 2021, 35(3), 106 (in Chinese).
龚美琦, 张春涛, 王汝恒. 重庆理工大学学报(自然科学), 2021, 35(3), 106.