POLYMERS AND POLYMER MATRIX COMPOSITES |
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Research Progress of Clay Mineral-based Nanocomposite Flame Retardants |
XIE Weimin1, LIANG Xiaozheng1, ZHAO Xiaoguang1, YANG Huaming1,2,3
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1 School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China 2 Key Laboratory for Mineral Materials and Application of Hunan Province, Central South University, Changsha 410083, China 3 Key Laboratory of Clay Mineral Functional Materials in China Building Materials Industry, Central South University, Changsha 410083, China |
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Abstract Polymer nanocomposites have been widely used in various fields of national production and life due to their excellent properties such as light weight, corrosion resistance, electrical insulation and easy processing. However, most polymer materials are extremely flammable, which seriously limits their practical application in many fields. Therefore, it is of great significance to enhance the flame retardant property of polymer. In recent years, with the increasing awareness of environmental protection and health, the preparation of polymer composites with high strength, high toughness, high oxidation resistance and good flame retardancy by environmentally friendly methods has been attracted more and more researchers at home and abroad. High-efficiency green flame retardants will have great market potential. Nanoclay is a natural, non-toxic, low-cost, biodegradable and biocompatible material, which is often used to synthesize polymer nanocomposites. Due to its high specific surface area, ba-rrier property and thermal stability, it can effectively improve the flame retardancy and mechanical properties of polymer materials. This paper summarizes the related research on the flame retardant and thermal stability of natural clay minerals reinforced polymer nanocomposites in recent years. According to different sources, polymer materials can be divided into natural polymer materials and synthetic polymer materials. The enhancement effect of clay minerals on the flame retardant properties of various polymer nanocomposites is discussed respectively. The flame retardant mechanism of natural clay minerals in polymer nanocomposites is also summarized. Compared with common polymer composites, natural clay minerals in polymer composites can capture flammable volatiles, block the transfer of heat and mass due to its unique structure (fibrous, tubular and layered). In addition, natural clays can form a strong barrier layer on the polymer surface to delay the heat and mass transfer processes. Finally, it points out the current problems existing in the flame retardant research of nanocomposites. The in-depth investigation of the current literature provides useful information for the efficient utilization of polymer/clay nanocomposites and also provides theoretical guidance for the design of new high-performance polymer/clay nanocomposites.
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Published: 10 December 2021
Online: 2021-12-23
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Fund:National Key R & D Program of China (2017YFB0310903) and the Fundamental Research Funds for the Central Universities of Central South University (2020zzts728, 2019zzts887) |
Corresponding Authors:
hmyang@csu.edu.cn
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About author: Weimin Xie received her B.E. degree in Mineral Processing Engineering from Wuhan Institute of Technology (WIT) in 2018. She is currently pursuing her master's degree in the School of Minerals Processing and Bioengineering at Central South University under the supervision of Prof. Huaming Yang. Her research is focused on the mineral functional materials. Huaming Yang is a professor of mineral materials in the School of Minerals Processing and Bioengineering, Central South University, China. He received his Ph.D. degree in mineral processing from Central South University of Technology, China, and went to the University of Bristol and the University of Queensland as a visiting professor. He is currently the director of Hunan Key Lab of Mineral Materials & Application, and Hunan International Scientific & Technological Cooperation Base of Mineral Materials. His primary research interest is in mineral materials, including the structure modulating of nanoclay minerals, functional design of minerals, synthesis strategy for advanced materials from natural minerals, and comprehensive utilization of solid waste, especially focused on the interdisciplinary intersection of mineral processing, material science, physics, biomedicine, etc. He has published 7 book contributions and more than 180 scientific papers in international journals, including Adv. Funct. Mater., Chem. Mater., Appl. Catal. B, J. Mater. Chem., J. Phys. Chem., ChemComm, Adv. Mater. Interface, Am. Mineral., Clay Clay Miner., Appl. Clay Sci., et al. He was elected a leading talent of the National Ten Thousand Tal- ents Program”, and awarded the National Science Fund for Distinguished Young Scholars in China and the National Leading Young Talent in Science and Technology Innovation. Now he is the vice chairman of Mineral Materials Branch of the Chinese Ceramic Society, and the standing director of the Chinese Non-Metallic Minerals Industry Association. He has served as the associa-te editor for Clay Minerals, the guest editor for Minerals. He acted as the convenor of Mineral Materials Session of the 22nd Meeting of the International Mineralogical Association (Melbourne). |
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