金属硫化物/g-C<sub>3</sub>N<sub>4</sub>异质结的构建及其光催化性能改善与应用

doi:10.11896/cldb.20100188

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Abstract Metal sulfides and graphite phase g-C₃N₄ are two kinds of typical photocatalytic semiconductor materials with visible light activity. The heterojunctions formed by the combination of metal sulfides and g-C₃N₄ have been widely concerned by researchers due to its excellent photocatalytic performance, which has important application prospect in environmental pollution control and new energy development. However, the hete-rojunctions still suffer from high electron-hole recombination rate, poor catalytic activity and low energy conversion efficiency. In this paper, the recent research progress in the construction of metal sulfide/g-C₃N₄ heterojunctions, improvement of photocatalytic performance and application are reviewed. In the aspect of metal sulfide/g-C₃N₄ heterojunctions construction, the type Ⅱ heterojunction, Z-scheme heterojunction (direct Z-shceme and indirect Z-scheme), P-N heterojunction and S-scheme heterojunction are summarized respectively, and the improvement of hete-rojunctions photocatalytic performance is concluded from the aspects of heterojunctions morphology control and surface/interface modification. At the same time, the applications of metal sulfide/g-C₃N₄ heterojunctions in hydrogen production, CO₂ reduction, organic pollutants degradation, photocatalytic nitrogen fixation and photocatalytic sterilization are also summarized. The challenges faced by metal sulfide/g-C₃N₄ heterojunctions in the process of photocatalysis are put forward. It is pointed out that the reasonable construction of heterojunctions by using energy band matching is the key to improving the photocatalytic activity of metal sulfides and g-C₃N₄. Large-scale and cheap fabrication of metal sulfide/g-C₃N₄ heterojunctions is a problem to be solved in practical application.

Key words： metal sulfides g-C₃N₄ heterojunction degradation of organic pollutants hydrogen production

Published: Online: 2022-05-24

CLC number:

Q643

Fund:Hubei Provincial Department of Education Research Project (D20171405).

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	Articles by authors
	GAN Jianchang
	HU Haiping
	SU Ming
	CHEN Feng
	WANG Huihu

Cite this article:

GAN Jianchang,HU Haiping,SU Ming, et al. Construction, Photocatalytic Performance Improvement and Application of Metal Sulfide/g-C₃N₄ Heterojunctions[J]. Materials Reports, 2022, 36(10): 20100188-10.

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http://www.mater-rep.com/EN/10.11896/cldb.20100188 OR http://www.mater-rep.com/EN/Y2022/V36/I10/20100188

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