均相光催化制氢体系有机染料光敏剂的研究进展

doi:10.11896/cldb.20100177

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Abstract Hydrogen energy is kind of an ideal clean new energy and plays an important role in renewable energy. At this stage, the development of hydrogen energy in China still faces many challenges, such as the low production efficiency due to the immature technologies, the instability of hydrogen production system, and the high cost of hydrogen energy applications, which hinders the development of hydrogen energy industry. China has obtained leading technological advantages in hydrogen productions from alkaline electrolytic water and coal gasification. Although China ranks first in the scale of hydrogen productions, there is still a big gap between China and the international top technologies in renewable energy hydrogen production, such as photocatalytic and electrocatalytic hydrogen production.
Generally, photocatalytic hydrogen production technology can be divided into two types, heterogeneous and homogeneous hydrogen production technologies. Since most heterogeneous hydrogen production systems use semiconductors as photocatalysts, their light absorption efficiency is low and hydrogen production efficiency is not high. For a homogeneous system composed of photosensitizers, catalysts and sacrificial electron donors, it is a potential hydrogen production technology because of its flexible structure easy to design and adjust systematically. Among them, the photosensitizer is used as the energy harvester for the hydrogen production reaction, and its selection is particularly critical. Recently, noble metals and their complexes photosensitizers have been widely studied. Owing to its limited resource and high cost, the research and development of noble metals based photosensitizers are restricted. As an alternative, the use of pure organic dyes to construct non-noble metal photocatalytic hydrogen production systems is expected to bring a new breakthrough in the development of homogeneous photocatalytic hydrogen production system.
In the non-noble metal photocatalytic hydrogen production system, the pure organic photosensitizers are mainly divided into nitrogenous heterocycles, xanthenes, bodipys and coumarins. The current research on the photocatalytic performance of pure organic dyes for hydrogen production shows that their hydrogen production efficiency is much higher than that of metal-based photosensitizers. Because organic dyes have good structure-activity characteristics, the performance of photosensitizers can be changed and optimized by structural design and modification. In addition, pure organic dyes do not contain metal elements, are cost-effective, rich in resources, and easy to synthesize, and thus have gradually arose much attention in hydrogen production.
In this review,we firstly discussed the homogeneous photocatalytic hydrogen production system, including its basic composition, structure types, photochemical theoretical basis, hydrogen production mechanism analysis and performance research. The advances of non-noble metal photocatalytic hydrogen production system with organic dyes as photosensitizer is reviewed with particular emphasis. Finally, current trends related to the screening design of using organic dyes as photosensitizers for hydrogen production system is outlined, and we further clarified the development direction of hydrogen energy technology.

Key words： photocatalysis hydrogen production homogeneous system organic photosensitizers

Published: 28 December 2022 Online: 2023-01-03

CLC number:

TQ116

Fund:Science Foundation of China University of Petroleum,Beijing (2462020XKJS02), Shanxi Province Science and Technology Major Project (20181101013), and National Natural Science Foundation of China (21625601).

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	Articles by authors
	YANG Zhenqing
	XIANG Wenli
	JIAO Yuqiu
	WANG Guochen
	YU Yuening
	XU Huiying
	SHAO Changjin

Cite this article:

YANG Zhenqing,XIANG Wenli,JIAO Yuqiu, et al. Research Progress of Organic Photosensitizers for Homogeneous Photocatalytic Hydrogen Production System[J]. Materials Reports, 2022, 36(24): 20100177-15.

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http://www.mater-rep.com/EN/10.11896/cldb.20100177 OR http://www.mater-rep.com/EN/Y2022/V36/I24/20100177

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