低温等离子体改性技术制备功能材料的研究进展

doi:10.11896/cldb.20100119

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Abstract Low-temperature plasma modification technology is a commonly used material modification method. It generates a large number of energetic particles and various forms of light radiation through ionized gas to act on the surface of the material, thereby improving the hydrophobicity, flame retardancy and antibacterial properties, to achieve the purpose of preparing materials with one or more specific functions. Low-temperature plasma modification technology is favored in material modification thanks to four major advantages: (Ⅰ) low temperature required for the reaction environment, (Ⅱ) high processing efficiency, (Ⅲ) wide application range, (Ⅳ) the undamaged nature of the material itself.
In recent years, low-temperature plasma modification technology has been widely used in biomass materials, polymer materials, metal materials and other fields. Its research in the field of biomass materials is particularly active. The superhydrophobicity prepared by low-temperature plasma surface treatment ,flame retardant and other functional materials have harvested widely reported. In the field of polymer materials, the low-temperature plasma modification method is often used to prepare super-hydrophobic plastic film materials, medical antibacterial masks, and anti-fouling non-woven fabrics. The metal deposited by plasma chemical vapor deposition at low temperature can resist corrosion and wear. In addition, low temperature plasma modification technology have harvested fruitful research achievements in various fields such as the three waste treatment, semiconductor materials, electronic products, electronic circuits, superconducting materials and others.
Scientists have always applied far more research on low-temperature plasma modification technology than mechanism research, which limits its development in material modification. However, studying the mechanism of low-temperature plasma on different materials is instructive for the preparation of the required functional materials. In fact, a series of physical and chemical reactions such as desorption, doping, etching, sputtering, cross-linking, surface grafting and interfacial polymerization occur on the surface of plasma. The specific reactions are closely related to the type of plasma, material type, discharge mode and technological parameters. The classification of low-temperature plasma modification technology according to different action mechanisms is conducive to the accurate preparation of the required functional materials.
This article reviews three different low-temperature plasma modification methods: (Ⅰ) low-temperature plasma surface treatment, (Ⅱ) low-temperature plasma chemical vapor deposition, (Ⅲ) low-temperature plasma graft polymerization. Based on the properties of different materials and different modification mechanisms, the applications of low-temperature plasma modification technology in superhydrophobicity, flame retardancy and antibacterial functional materials are summarized. Based on the analysis of the mechanism of low-temperature plasma modification, this paper summarizes how to use different types of low-temperature plasma system to prepare the required specific functional materials, and points out the shortcomings and development prospects of low-temperature plasma modification technology applying to modified materials.

Key words： low temperature plasma modification technology surface treatment graft polymerization chemical vapor deposition functional material

Published: 10 November 2022 Online: 2022-11-03

CLC number:

TG156.99

Fund:Fujian Provincial Science and Technology Plan Spark Project (2018S0038, 2018S0026), and the Fujian Provincial Development and Reform Commission Project (K1515863A).

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	Articles by authors
	WU Jianfei
	YUAN Hongmei
	XIA Linmin
	ZHAO Hongyan
	LIN Jinguo
	LI Jiqing

Cite this article:

WU Jianfei,YUAN Hongmei,XIA Linmin, et al. Research Progress in the Preparation of Functional Materials by Low Temperature Plasma Modification Technology[J]. Materials Reports, 2022, 36(21): 20100119-9.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20100119 OR http://www.mater-rep.com/EN/Y2022/V36/I21/20100119

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