硼氢化钠循环再生工艺的研究进展

doi:10.11896/cldb.20090358

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Abstract Sodium borohydride(NaBH₄) has high hydrogen storage density, which could be stored and transported under normal pressure and temperature in alkaline solution. Simultaneously, sodium borohydride emerged as hydrogen storage candidate for proton exchange membrane fuel cell (PEMFC) and direct borohydride fuel cell (DBFC) system. But the development was constrained for the problems, such as the high cost of hydrogen production, the difficulty of regeneration and the need of noble metal catalyst.
Many researchers have made many researches on the process of regenerating sodium borohydride, including industrial synthesis process and direct reduction process. The process of direct sodium borohydride reduction is an one-step synthesis method of heating sodium metaborate, magnesium hydride and magnesium in the presence of hydrogen or argon atmosphere. This is a fairly attractive process from the perspective of one-step reaction and high product yield, but there are some risks associated with high pressure, high temperature, and high energy consumption. In recent years, the process of mechanical-chemical reduction, especially high-energy ball milling process, has been studied too much. Sodium borohydride can be regenerated by ball milling at different speeds and ball milling time under normal temperature and pressure, and the regeneration process is convenient and economical. In addition, sodium borohydride can be synthesized by electrochemical reduction process with simple process and mild conditions, selecting appropriate electrode and electrolytic solution to product sodium borohydride in the electrolytic cell. However, the product yield obtained by this process is pretty low, furthermore, the mechanism had rarely studied.
In this paper, the regeneration processes of sodium borohydride at home and abroad are reviewed. Industrial synthesis process, direct reduction process, mechanical-chemical reduction process and electrochemical reduction process are discussed. Meanwhile, the mechanism, process route and their relative merits of each method are summarized and analyzed.

Key words： sodium borohydride hydrogen storage fuel cell regeneration process electrochemical reduction

Published: 31 August 2021

CLC number:

TK91

Fund:National Natural Science Foundation of China (21606115), Postgraduate Research and Practice Innovation Project of Jiangsu Province (KYCX20_2214, SJCX20_0910), Xuzhou Science and Technology Project (KC20195),Innovation and Entrepreneurship Training Program for College Students of Jiangsu Province (XSJCX10093).

About author:: Wenying Fu received her B.S. degree from Shandong University of Technology in 2019. She is currently pursuing her Ph.D. at the School of Physics and Electronic Engineering, Jiangsu Normal University under the supervision of Prof. Yongsheng Wei. Her research has focused on the synthesis of sodium borohydride by electrolysis reduction process.
Yongsheng Wei received his bachelor’s degree in Chemical Engineering and Technology from China University of Mining and Technology in 2006 and received his Ph.D. degree from Beijing Jiaotong University in 2011. He did a year of doctoral research at University of Miami in 2008—2009 and received postdoctoral degree at Beijing University of Chemical Technology in 2013. His research interests are fuel cell, electrocatalyst of hydrogen generation, the synthesis of sodium borohydride by electrolysis reduction process. He is currently an associate professor in Jiangsu Normal University.

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	FU Wenying
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Cite this article:

FU Wenying,SI Si,WEI Yongsheng, et al. Research Progress of Sodium Borohydride Regeneration Process[J]. Materials Reports, 2021, 35(15): 15017-15025.

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http://www.mater-rep.com/EN/10.11896/cldb.20090358 OR http://www.mater-rep.com/EN/Y2021/V35/I15/15017

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