金属有机框架材料在光催化还原CO<sub>2</sub>中的应用

doi:10.11896/cldb.20070204

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Abstract Although human beings rely on fossil fuels to accelerate the development of modern society, the over-use of fossil fuels has raised a series of problems such as tough energy crisis and environmental exacerbation. Excessive depletion of fossil fuels leads to the sharp increase of CO₂ content in the atmosphere, which is the main cause of the global greenhouse effect. Among the abundant technologies for reducing CO₂ emissions, the photocatalytic reduction of CO₂ technology not only reduces the CO₂ content in the atmosphere, but also converts CO₂ into valuable chemicals through solar energy, which is considered to be one of the most promising technologies.
Metal-organic frameworks (MOFs), also known as porous coordination polymers, are three-dimensional porous materials with a periodic network structure composed of inorganic metal ions (or metal clusters) and organic ligands. MOFs are particularly promising materials due to large surface area, adjustable structure, unique electronic band structures and abundant catalytic active sites, which make it more and more favored by researchers in the photocatalytic reduction of CO₂. At present, MOFs used for photocatalytic reduction of CO₂ mainly include single MOFs photocatalyst and composite photocatalyst based on MOFs. The article lists specific examples to illustrate the advantages and uniqueness of MOF-based photocatalytic materials in the reduction of CO₂ and modified methods to improve photocatalytic activity.
This review summarizes recent research progresses in MOF-based photocatalysts for photocatalytic reduction of CO₂. Besides, it discusses strategies in rational design of MOF-based photocatalysts (MOFs functionalization, semiconductor/MOFs, photosensitizer/MOFs and noble me-tal/MOFs) with enhanced performance on CO₂ reduction. Moreover, challenges and outlook on using MOFs-based photocatalysts for CO₂ reduction are also put forward.

Key words： catalyst metal-organic framework photocatalytic reduction composite materials carbon dioxide

Published: 30 November 2021

CLC number:	O643.36
	O644.1

Fund:National Key R & D Program of China (2018YFB0605002) and the National Natural Science Foundation of China (21546014,50616114).

About author:: Zhongwei Zhang graduated from Jinan University in June 2018 with a bachelor's degree in engineering. He is currently a master student in the College of Energy and Mechanical Engineering, Shanghai University of Electric Power. He is conducting research under the gui-dance of professor Ruitang Guo and professor Weiguo Pan. His research focuses on photocatalytic reduction of carbon dioxide.
Ruitang Guo received his B.S. and Ph.D. degrees from Zhejiang University. In 2015, he worked as a professor of energy science in Shanghai University of Electric Power. His current research interests focus on the pre-paration and performance study of SCR catalysts and photocatalysts used in CO₂ reduction, H₂ evolution and degradation of organic pollutants. He published more than 90 papers as the first or corresponding author, including more than 60 SCI papers.
Weiguo Pan earned his Ph. D. in 1997 from Zhejiang University. He is currently the party secretary at College of Energy and Mechanical Engineering, Shanghai University of Electric Power, and the chairman of the Environmental Protection Committee of the Chinese Society of Power Engineering. His current research interests include clean and efficient utilization of energy and photocatalytic process for energy conversion and environmental protection. He presided over and participated in the National Plan “973” “863”, Science and Technology Support Plan, Key Research and Development Plan, and the National Natural Science Foundation of China. He published more than 160 papers as the first or corresponding author, and more than 60 authorized patents.

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Cite this article:

ZHANG Zhongwei,GUO Ruitang,QIN Yang, et al. Application of Metal-Organic Framework in CO₂ Photocatalytic Reduction[J]. Materials Reports, 2021, 35(21): 21058-21070.

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http://www.mater-rep.com/EN/10.11896/cldb.20070204 OR http://www.mater-rep.com/EN/Y2021/V35/I21/21058

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