MATERIALS AND SUSTAINABLE DEVEL OPMENT: MATERIALS REMANUFACTURING AND WASTE RECYCLING |
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Research Progress on the Vitrification of High Level Radioactive Wastes in Phosphate Glassy Matrices |
LI Xiuying, XIAO Zhuohao, TAO Xinyue, WANG Yongqing, YANG Ke, SHI Jijun, DENG Bo
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School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, China |
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Abstract Long-term, efficient and safe immobilization of high level radioactive wastes (HLWs) can be achieved by vitrifying them in glassy matrices to prepare waste forms with high loadings, chemical durability, thermal stability and radiation resistance stability. Phosphate glasses are chosen as matrices to vitrify some HLWs due to their low melting temperatures, excellent melt fluidity, short melt time and high loadings. It can make up for the shortages of widely used borosilicate glasses during the immobilization process of some HLWs. Research progress on the vitrification of some HLWs in phosphate glassy matrices is reviewed in the present paper. Phosphate glassy matrices that have been currently used or have the potential to be used in the vitrification of HLWs are listed and their distinct advantages and disadvantages are clarified. Moreover, the compositions, preparation and properties of phosphate glassy waste forms are summarized. Future researches are proposed at the end of this paper.
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Published: 12 March 2021
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Fund:National Natural Science Foundation of China (51962013, 51762023), National Key Research and Development Program of China (2018YFC1903406), Jiangxi Provincial Natural Science Foundation or Key Research and Development Program of Jiangxi Province (20202BABL204020, 20192ACB20018, 20192ACB80007, 20192BBEL50020, 20201BBE51011), Jingdezhen Science and Technology Project (20192GYZD008-34). |
About author:: Xiuying Li received her bachelor’s and master’s degrees in applied chemistry from Hunan Normal University in 2002 and 2005 respectively, and then achieved her Ph.D. degree in materials science from Central South University in 2010. She engaged in postdoctoral research in Central South University from 2011 to 2013. Now she is an associate professor as well as a postgra-duate tutor in Jingdezhen Ceramic Institute. She has engaged in the research about iron phosphate glasses for about ten years. Her research interests include glass, glass-ceramics and advanced ceramics. Over forty papers have been published in Journals such as Journal of Non-Crystalline Solids, Ceramics International, Nano Letters, Bulletin of Materials Science and Journal of Central South University. Zhuohao Xiao received his Ph.D. degree at the School of Materials Science and Engineering, Central South University in 2009. He was in Nanyang Technological University as a visitor scholar from July 2017 to July 2018. Now he is a full professor in Jingdezhen Ceramic Institute. His research interests include advanced ceramics, nanomaterials, glass and glass-ceramics, and ceramic pigments and glazes. |
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1 Li H J. Research of containing characteristics with calcium iron phosphate glass nuclear waste forms. Master’s Thesis, Southwest University, China,2013(in Chinese). 李海建.钙铁磷酸盐玻璃固化体包容特性研究.硕士学位论文,西南科技大学,2012. 2 Wang Hong. Research of structure and property of iron sodium phosphate glass-ceramics wasteforms. Master’s Thesis, Southwest University, China,2014(in Chinese). 王红.铁钠磷酸盐玻璃陶瓷固化体的结构与性能的研究.硕士学位论文,西南科技大学,2014. 3 Gao J, Ye G, Chen S Z, et al. Atomic Energy Science and Technology,2017,47(6),911(in Chinese). 高杰,叶钢,陈崧哲,等.原子能科学技术,2017,47(6),911. 4 Xu K. Materials China,2016,355(7),481(in Chinese). 徐凯.中国材料进展,2016,355(7),481. 5 Chu H R, Ruan J S, Zhang Y. Shangdong Chemical Industry,2017,46(16),65(in Chinese). 褚浩然,阮佳晟,张禹.山东化工,2017,46(16),65. 6 Donald I W. Journal of Materials Science,1997,32(22),5851. 7 Bingham P A, Hand R J, Forder S D. Materials Research Bulletin,2006,41,1622. 8 Yudintsev S V, Shiryaev A A. Technical Physics,2018,483(4),513. 9 Donald I W, Metcalfe B L, Fong S K, et al. Journal of Nuclear Mate-rials,2007,361,78. 10 Sales B C, Boatner L A. Science,1984,226,45. 11 Shih P Y. Materials Chemistry and Physics,2003,80,299. 12 Reis S T, Karabulut M, Day D E. Journal of Nuclear Materials,2002,304,87. 13 Marasinghe G K, Karabulut M, Ray C S, et al. Journal of Non-Crystalline Solids,2000,263-264,146. 14 Kim C W, Ray C S, Zhu D, et al. Journal of Nuclear Materials,2003,322,152. 15 Huang W, Day D E, Ray C S, et al. Journal of Nuclear Materials,2004,327,46. 16 Day D E, Wu Z, Ray C S, et al. Journal of Non-Crystalline Solids,1998,241,1. 17 Toshinori Okura, Tomoko Miyachi, Hideki Monma. Journal of the Euro-pean Ceramic Society,2006,26,831. 18 Pranesh Sengupta. Journal of Hazardous Materials,2012,235-236,17. 19 Aleksandrova E V, Malkovsky V I, Yudinstsev S V. Geochemistry,2018,482,1349. 20 Meskoa M G, Day D E, Bunker B C. Waste Management,2000,20,271. 21 Sun Y P. Vitrification of radioactive wastes containing fluorides from MSRs by phosphates and the properties of waste forms. Ph.D. Thesis, The University of Chinese Academy of Science, China,2016(in Chinese). 孙亚平,熔盐堆含氟放射性废物磷酸盐固化方案及固化体性能研究.博士学位论文,中国科学院大学,2016. 22 Sun Yaping, Xia Xiaobin, Qiao Yanbo, et al. Science China Materials,2016,59(4),279. 23 Liu Xueyang, Qiao Yanbo, Qian Zhenghua, et al. Journal of Nuclear Materials,2018,508,286. 24 乔延波,马洪军,孙亚平,等.中国专利,CN 105741897B,2018. 25 Karabulut M, Marasinghe G K, Ray C S, et al. Journal of Non-Crystalline Solids,1999,249,106. 26 Hu T H, Bao W M, Song C L, et al. Radiation Protection,2001,21(6),354(in Chinese). 胡唐华,鲍卫民,宋崇立,等.辐射防护,2001,21(6),354. 27 Hu T H, Xu S P, Bao W M,et al. Bulletin of the Chinese Ceramic Society,2003(2),86(in Chinese). 胡唐华,徐世平,鲍卫民,等.硅酸盐通报,2003(2),86. 28 Kitheri Joseph, Govindan Kutty K V,Chandramohan P, et al. Journal of Nuclear Materials,2009,384,262. 29 Kitheri Joseph, Sajal Ghosh, Govindan Kutty K V, et al. Journal of Nuclear Materials,2012,426,233. 30 Li Xiuying, Xiao Zhuohao, He Yongtao, et al. Journal of Non-Crystalline Solids,2019,523,119588. 31 Bai Jincheng, Hsu Jenhsien, Sandineni Prashanth, et al. Journal of Non-Crystalline Solids,2019,510,121. 32 Li X Y, Tao X Y, Xiao Z H, et al. Journal of Ceramics,2020,41(6),904(in English). 李秀英,陶歆月,肖卓豪,等.陶瓷学报,2020,41(6),904. 33 Liu Jingfeng, Zhu Yuying,Wang Fu, et al. Journal of Non-Crystalline Solids,2018,500,92. 34 Qian Bin, Yang Shiyuan, Liang Xiaofeng, et al. Journal of Molecular Structure,2012,1011,153. 35 Lai Yuanming, Liang Xiaofeng,Yang Shiyuan, et al. Journal of Alloys and Compounds,2014,617,597. 36 Rincón J Ma, Ramos C, Arboleda P, et al. Materials Letters,2018,227,82. 37 Stefanovsky S V, Stefanovsky O I, Danilov S S, et al. Ceramics International,2019,45,9331. 38 Moguš-Milanković A, Santi A, Gajović A, et al. Journal of Non-Crystalline Solids,2003,325,76. 39 Li Xiuying, Xiao Zhuohao, Luo Minhua, et al. Journal of Non-Crystalline Solids,2017,469,62. 40 Kitheri Joseph, Asuvathraman R, Venkata Krishnan R, et al. Journal of Nuclear Materials,2014,452,273. 41 Jen-Hsien Hsu, Jincheng Bai, Cheol-Woon Kim, et al. Journal of Nuc-lear Materials,2018,500,373. 42 Wang Fu, Liao Qilong, Chen Kuiru, et al. Journal of Alloys and Compounds,2014,611,278. 43 Naoto Kitamura, Akira Nomura, Akira Saitoh, et al. Journal of the Ceramic Society of Japan,2018,126(11),948. 44 Moguš-Milanković A, Santi A, Liina V, et al. Journal of Non-Crystalline Solids,2005,351,3235. 45 Santić A, Moguś-Milanković A, Furić K, et al. Journal of Non-Crystalline Solids,2007,353,1070. 46 Liang X F, Ren H. Glass,2014(2),8(in Chinese). 梁晓峰,任慧.玻璃,2014(2),8. 47 Kai Xu, Pavel Hrma, Wooyong Um, et al. Journal of Nuclear Materials,2013,441,262. 48 Li X Y, Jiang T, Yang H M, et al. Materials Reports A: Review Reports,2012,26(2),36(in Chinese). 李秀英,姜涛,杨华明,等.材料导报:综述篇,2012,26(2),36. 49 Li Xiuying, Yang Huaming, Song Xiaolan, et al. Journal of Non-Crystalline Solids,2013,379,208. 50 Reis S T, Pontuschka W M, Mogus-Milankovic A, et al. Journal of the American Ceramic Society,2017,100,1976. 51 Moguš-Milanković A, Gajović A, Santić A, et al. Journal of Non-Crystalline Solids,2001,289,204. 52 Karabulut M, Yuce B, Bozdogan O, et al. Journal of Non-Crystalline Solids,2011,357,1455. |
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