钒酸铋可见光催化材料的改性研究进展

doi:10.11896/cldb.20040162

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Abstract Environmental pollution and energy shortage are the two major problems that need to be solved urgently in the 21st century. Solar energy is inexhaustible energy, how to use solar energy to control environmental pollution and alleviate energy shortage has become the focus. Bismuth vanadate (BiVO₄) is a promising solar-driven semiconductor photocatalyst due to its low cost, non-toxicity, high photostability, narrow band gap, good response to visible light, and has become a hotspot in photocatalyst field.
Among the three crystal types of BiVO₄, the monoclinic phase BiVO₄ exhibits the best photoactivity due to the smaller band gap and special electronic structure. However, the fast recombination of photoinduced carriers of pure BiVO₄ as a result of narrow energy gap, coupled with its low adsorption and small specific surface area, limit the improvement of photocatalytic performance and practical application.
In order to improve the visible light photocatalytic activity of BiVO₄, researchers mainly focus on modifying BiVO₄ from two aspects including the controlled synthesis of BiVO₄ micro/nanostructure so as to improve the specific surface area and adsorption, as well as the conductivity of photogenerated carriers or constructing composite materials to promote the separation of photogenerated electron-hole pairs, thus reduce their recombination probability, further broaden the visible light response range and improve the adsorption and stability of materials, etc. The research has achieved encouraging results. At present, the photocatalytic efficiency of bismuth vanadate material has been improved greatly.
This article provides a review on the recent advances of bismuth vanadate photocatalytic materials based on different modification methods, including the controlled synthesis of BiVO₄ micro/nanostructure, noble metal deposition, element doping, semiconductor coupling, and BiVO₄ loa-ding, which mainly focus on the application of the materials in the degradation of toxic organic pollutants in wastewater, hydrogen production from water splitting, CO₂ reduction and organic synthesis, etc. Finally, some problems that need to be solved and the future development direction are pointed out, so as to provide a reference for the development of stable and efficient BiVO₄ photocatalytic materials.

Key words： bismuth vanadate photocatalytic modification

Published: 26 September 2021

CLC number:

TQ426

Fund:Sichuan Science and Technology Program (2019YFG0259), Provincial Undergraduate Training Program for Innovation and Entrepreneurship (S201911360055).

About author:: Jingjing Liu, received her Ph.D. degree in organic chemistry from Sichuan University in 2012. She was appointed as lecturer at College of Vanadium and Titanium in Panzhihua University, in 2015. Currently, her research interests are the development and research of vanadium-titanium functional materials.

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	LIU Jingjing
	ZHANG Zelan
	LI Shi
	LIU Yu
	YANG Peipei
	LI Xing

Cite this article:

LIU Jingjing,ZHANG Zelan,LI Shi, et al. Research Progress on Modification of Bismuth Vanadate Visible Light Photocatalytic Materials[J]. Materials Reports, 2021, 35(17): 17163-17177.

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http://www.mater-rep.com/EN/10.11896/cldb.20040162 OR http://www.mater-rep.com/EN/Y2021/V35/I17/17163

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