耐原子氧聚酰亚胺材料的研究进展

doi:10.11896/cldb.20020053

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Abstract Since 21st century, the rapid development of aerospace has provided important technical support means for human daily communication, observation of astronomical gas phase, and exploration of the universe. Polyimide (PI) has become one of the indispensable spacecraft materials by virtue of its excellent high and low temperature resistance, mechanical properties, radiation resistance, electrical properties, and solvent resistance. It’s widely used as flexible substrate for solar cell arrays, multi?layer thermal insulation blanket and insulating protective layer for circuit systems of the spacecraft.
However, the spacecraft works in low earth orbit containing atomic oxygen (AO). High?throughput AO with strong oxidizing properties can ra?pidly erode the main thermal control material PI on the surface of the spacecraft, degrading its optical, electrical, mechanical and other important properties, resulting in decreased efficiency and shortened service life of the spacecraft,which leads to the failure of the system’s targets and seriously hinders the development of the space industry.
Over the years, researchers proposed a variety of solutions to the above problems and made great progress. Among them, the method of applying a protective coating on the surface of the material can not only protect the substrate from atomic oxygen erosion, but also maintain the original performance of the base material. It’s suitable for making a variety of different surfaces, has a simple process, a wide range of applications as well. As for the new material of atomic polyimide resistant polyimide, researchers have also overcome difficulties and developed new materials with better performance and longer service life. In addition, due to the limitations of special test conditions, the development of atomic oxygen?resistant ground simulation experiments has developed rapidly. So far, a variety of simulation theories have been proposed and simulators have been manufactured to assist in research.
This article compares the resistance to atomic oxygen of polyimide materials that are currently commercially available, introduces the principles and classification of ground simulation test methods for atomic oxygen resistance, summarizes the types of polyimide materials against atomic oxygen, including protective coating and novel atomic oxygen resistant polyimide material, and made a reasonable judgment on the advantages and disadvantages of various types of protection methods. At the same time, it also points out the development direction and prospect of atomic oxygen resistant polyimide materials in the future.

Key words： atomic oxygen polyimide self-healing AO resistance test method low-earth-orbit

Published: 25 June 2021

CLC number:

TB35

Fund:This work was financially supported by the National Basic Research Program of China (2014CB643604, 2014CB643606), the National Natural Science Foundation of China (51673017, 21404005, 51273018, 5179500011), Special Fund for Fundamental Scientific Research Business of Central Universities (XK1802-2), China Aviation Science Foundation (201718S9001), Jiangsu Province Outstanding Youth Fund (BK20140006) and Equipment Pre-research Shared Technology Project(41422040401).

About author:: Ruihan Wang received her B.S. degree from Beijing University of Chemical Technology in 2018. She is currently pursuing her M.S. degree at the institute of Materials Science and Engineering, Beijing University of Chemical Technology under the supervision of Prof. Shengli Qi. At present, her research has focused on the structure and performance of atomic resistant polyimide materials.Ruohong Zhao enrolled in Beijing University of Chemical Technology in 2017, majoring in polymer materials and engineering. Under the guidance of Prof. Shengli Qi during the undergraduate study, she studied atomic and oxygen resistant polyimide materials.Gang Liu graduated from Harbin Institute of Technology in 2011 with a Ph.D. degree in materials science, currently working at the Shanghai Satellite Equipment Research Institute, mainly engaged in technical research work in the fields of spacecraft materials and manufacturing and space environmental engineering.Shengli Qi received his Ph.D. degree from Beijing University of Chemical Technology in 2008, and engaged in post-doctoral research in JSPS at Nagoya University in Japan from 2009 to 2011. He is currently a professor and doctoral tutor of Materials Science and Engineering, Beijing University of Chemical Technology. He is currently a professor and doctoral tutor at the institute of Materials Science and Engineering, Beijing University of Chemical Technology. He was supported by the Jiangsu Provincial Outstanding Youth Fund (2014), published more than 60 SCI papers as the first author and corresponding author, and has more than 36 authorized patents. His main research direction is molecular structure design and its application in flexible display, information storage and secondary energy systems of high performance and functional polyimide materials.

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	WANG Ruihan
	ZHAO Ruohong
	ZOU Wanyan
	WANG Min
	ZHOU Bo
	QI Shengli
	LIU Gang
	Wu Dezhen

Cite this article:

WANG Ruihan,ZHAO Ruohong,ZOU Wanyan, et al. Research Progress of Atomic Oxygen Resistant Polyimide Materials[J]. Materials Reports, 2021, 35(11): 11187-11195.

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http://www.mater-rep.com/EN/10.11896/cldb.20020053 OR http://www.mater-rep.com/EN/Y2021/V35/I11/11187

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