基于双向脉冲电沉积下的Ni-纳米TiC复合镀层结构及耐磨性能

doi:10.11896/cldb.20010072

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Abstract In order to investigate the influence of the second-phase (TiC particles) on the microstructure and wear resistance of Ni-based composite coatings, pure Ni coating, Ni-micro TiC composite coating and Ni-nano TiC composite coating were prepared on the Q235 steel by double-pulse electrodeposition, respcetively. The surface morphology, phase structure and composition of the coatings were characterized by FESEM, XRD and EDS, and the surface roughness, microhardness and wear resistance of the coatings were compared, respectively. The results show that after adding TiC particles, the surface morpholgogy of the coating changes from a cellular structure to a cauliflower structure, and the deposition orientation behavior of the nickel matrix also changes. The average grain size of Ni-nano TiC composite coating is 24.9 nm, approximately 1/3 of Ni-micro TiC composite coating. Compared with the Ni-micro TiC composite coating, Ni-nano TiC composite coating has a smaller surface roughness (R_a=3.500 μm) and a higher surface hardness (820.5HV_0.1). The results of the abrasion test indicate that the wear mechanism of the composite coating is a mixture of slight abrasive wear and adhesive wear, and the wear rate of the nickel-based coating decreases due to the presence of TiC particles. Among them, the average wear rate of the Ni-nano TiC composite coating is 5.6 mg/(cm²·min), which is about 1/2 of the Ni-micro TiC composite coating, showing better wear resistance to the substrate.

Key words： double-pulse electrodeposition TiC particles nickel-based composite coating microstructure wear resistance

Published: 24 December 2020

CLC number:

TG174

Fund:This work was financially supported by the Science and Technology Research Funding Project of Liaoning Education Department (LJ2020JCL027); the Liaoning Province Doctoral Research Startup Fund Project (20170520151).

About author:: Shuangquan Wu graduated from Liaoning Technical University and with a bachelor′s degree in engineering in June 2017. He is currently studying for a master′s degree in materials science and engineering at Liaoning Technical University, and is mainly engaged in the research of surface modification and protection of metal materials.
Xin Ren received his Ph.D. degree in materials science from Nanjing University of Science and Technology in Jul. 2005. He is currently a professor and master supervisor of the Liaoning Technical University. He has published more than 50 journal papers as the first author. His research interests focus on material surface modification, material corrosion and protection.

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	WU Shuangquan
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Cite this article:

WU Shuangquan,REN Xin,CHU Xin, et al. Structure and Wear Resistance of Ni-nano TiC Composite Coatings Based on Double-pulse Electrodeposition[J]. Materials Reports, 2020, 34(24): 24080-24085.

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http://www.mater-rep.com/EN/10.11896/cldb.20010072 OR http://www.mater-rep.com/EN/Y2020/V34/I24/24080

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