POLYMERS AND POLYMER MATRIX COMPOSITES |
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Synthesis and Characterization of Oligomers of Fluorinated with Silane Coupling |
LI Ruichao1,2,3,4,5, GUI Taijiang2, CONG Weiwei2, ZHANG Dun1,4,5, GUO Lisha2, WANG Peng1,4,5
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1 Key Laboratory of Marine Environmental Corrosion and Biofouling, Institute of Oceanology,Chinese Academy of Sciences, Qingdao 266071, China; 2 Marine Chemical Research Institute, Qingdao 266071, China; 3 University of Chinese Academy of Sciences, Beijing 100049, China; 4 Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, China; 5 Qingdao National Laboratory for Marine Science and Technology, Qingdao 266237, China |
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Abstract Ecofriendly fouling release coating has limited antifouling efficiency under static conditions. In this work, a representative silane coupling agent and three different types of vinyl unsaturated fluoromonomers were used as raw materials. We studied the influence of polymerization conditions (reaction temperature, the types and application amount of initiator) on the products by varying the polymerization process and obtained copolymers with the number average molecular weight of less than 1 000 Da and a narrow distribution. On-line calorimetry system, Raman spectroscopy, infrared spectroscopy, and online infrared technology were used to characterize the polymerization process. The experimental results show that the functional oligomer was obtained through the free radical copolymerization of the alkene group, and the exothermic reaction is concentra-ted in the first dripping stage. The attachment test of biofouling of sample plates in the sea proves that the addition of oligomer can effectively improve antifouling perfomance of the fouling release coating.
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Published: 28 January 2021
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Fund:National Natural Science Foundation of China (41576079, 41924040), Qingdao National Laboratory for Marine Science and Technology (QNLM2016ORP0413), Aoshan Talent Program Supported by Qingdao National Laboratory for Marine Science and Technology (2017ASTCP-ES02). |
About author:: Ruichao Liis a graduate student of the Institute of Oceanology, Chinese Academy of Sciences. His research interest are the improvement and effect evaluation of the fouling release coating. 李锐超,中国科学院大学海洋研究所在读研究生。研究方向为污损释放型防污涂料的改良与效果评价。
Peng Wang, the researcher of the Institute of Oceano-logy, Chinese Academy of Sciences, has been selected as the member of National Natural Science Foundation of China “Excellent Youth Fund”, the first China Corrosion and Protection Outstanding Youth Academic Award (Zuo Jingyi Award), Qingdao National Laboratory for Marine Science and Technology, Laoshan Talent Training Program-Outstanding Young Scholar, Chinese Academy of Sciences Ocean Research Institute “Huiquan Young Scholar”. He has received the second prize of marine technology and technology, and the outstanding young science and technology ta-lent award of Shenyang Branch of Chinese Academy of Sciences. His research interest is the research of marine corrosion and biofouling protection technology development. He has conducted more than 10 projects, including the National Key Basic Research and Development Program Subproject, the National Natural Science Foundation Project, and the National Natural Science Foundation Youth Project. He has published more than 100 research papers, published in the journal Top 5% journal Corrosion Science and ACS Applied Materials and Interfaces.Currently, he is a member of the editorial board of international journals such as NPJ-Materials Degradation, a journal of the Nature Publishing Group. |
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