INORGANIC MATERIAL S AND CERAMIC MATRIX COMPOSITES |
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Recent Progress of Secondary Rechargeable/discharged Battery Tin Selenide Anode Materials |
CHENG Yayi1,2, HUANG Jianfeng2, LI Jiayin2, XIE Hui1, ZHOU Yingying1
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1 School of Materials Science & Engineering, Xi'an Aeronautical University, Xi'an 710077, China 2 Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China |
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Abstract Tin selenide (SnSe, SnSe2) is considered to be a kind of potential lithium/sodium ion battery anode materials due to its special layered crystal structure and high electrical conductivity. However, tin selenide materials still exist several issues during lithium/sodium ions storage process. On the one hand, the huge volumetric change of tin selenide anode can result in the destruction of electrode structure and SEI film (solid-electrolyte interface film). This cracked structure without good electric contact will lead to rapid decay of the cycling performance. On the other hand, the electrical conductivity of intermediate products Li2Se/Na2Se is poor, hindering the charge transfer and lowering the electrochemical reaction kinetics of tin selenide electrode. Based on the issues in lithium/sodium ions storage process, we summarize several strategies that have been used to enhance the electrochemical property of tin selenide, and review the domestic and foreign scholars from build special nano structure and composite structure level to reveal the electrochemical storage mechanism as well as the improved electrochemical performance.
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Published: 02 September 2020
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Fund:Natural Science Foundation of Shaanxi Province (2019JQ-911), the Scientific Research Program Funded by Shaanxi Provincial Education Department (19JK0428), the National Natural Science Foundation of China (51672165, 51702198) |
About author:: Yayi Cheng obtained her B.S. degree from Shaanxi University of Science & Technology in 2018. She is now a full teacher in Xi'an Aeronautical University. Her research interests has focused on tin-based nanomaterials for energy storage. |
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