MATERIALS AND SUSTAINABLE DEVEL OPMENT:ENVIRONMENT-FRIENDLYMATERIALS AND MATERIALS FOR ENVIRONMENTAL REMEDIATION |
|
|
|
|
|
Removal Efficiency of Cu(Ⅱ) by Fe-Si-B Amorphous Alloy |
ZHANG Xiangyun, DU Jinying, YUAN Zizhou, LI Jinqi
|
State Key Laboratory of Gansu Advanced Processing and Recycling of Non-ferrous Metal, Lanzhou University of Technology, Lanzhou 730050, China |
|
|
Abstract In this work, the Fe-Si-B amorphous alloy ribbons were successfully prepared by melt-spinning technique and compared with commercial 300 mesh iron powders for Cu(Ⅱ) removal efficiency. The results show that Fe-Si-B amorphous alloy ribbons were efficient in removing Cu(Ⅱ) from aqueous solution containing 100 mg/L of Cu(Ⅱ), where more than 98% of Cu(Ⅱ) was removed within 60 min using 1 g/L Fe-Si-B amorphous alloy ribbons, and the removal process can be described by a pseudo-first-order kinetic model. Under the same conditions, the surface normalized reaction rate constants for the removal of Cu(Ⅱ) by Fe-Si-B amorphous alloy ribbons is 167 times than that of 300 mesh iron powders. And the removal rate is proportional to solution pH and temperature, but inversely proportional to Cu(Ⅱ) concentration. In addition, it was found that the ribbons still exhibited 67% removal efficiency after six repeated uses.
|
Published: 10 April 2020
|
|
About author:: Xiangyun Zhangreceived her Ph.D. degree in June 2015 from Lanzhou University of Technology. She is currently an associate professor in Lanzhou University of Technology. Her research interests are metallic glasses. She has published more than 20 articles in important journals at home and abroad. Zizhou Yuanreceived his Ph.D. degree in June 2008 from Lanzhou University of Technology. He is currently a professor in Lanzhou University of Technology. His research interests are metallic glasses and lost-foam casting technology. He has published more than one hundred articles in important journals at home and abroad |
|
|
1 Lien H L, Wilkin R T. Chemosphere, 2005, 59(3),377. 2 Lo I M C, Lam C S C, Lai K C K. Water Research, 2006, 40(3),595. 3 Clancy T M, Hayes K F, Raskin L. Environmental Science & Technology, 2013, 47(19),10799. 4 Wang J, Liu G, Li T, et al. Australian Journal of Chemistry, 2015, 68(8), 1305. 5 Cheng Y, Jiao C, Fan W. Desalination and Water Treatment, 2015, 54(2),502. 6 Fu F, Dionysiou D D, Liu H. Journal of Hazardous Materials, 2014, 267C(3), 194. 7 Tang Y. Synthesis and azo dye degradation properties of iron-based amorphous alloys. Doctoral Thesis, Tsinghua University, China, 2015(in Chinese). 唐尧.铁基非晶合金制备及偶氮染料降解性能研究. 博士学位论文,清华大学,2015. 8 Singh S, Ediger M D, De Pablo J J. Nature Materials, 2013, 12(2), 139. 9 Yu H B, Luo Y, Samwer K. Advanced Materials, 2013, 25(41), 5904. 10 Wang P, Bian X F, Li Y X. Chinese Science Bulletin, 2012, 57(1), 33. 11 Tang Y, Shao Y, Chen N, et al. RSC Advances, 2015, 5(43),34032. 12 Lin B, Bian X, Wang P, et al. Materials Science & Engineering: B (Advanced Functional Solid-State Materials), 2012, 177(1), 92. 13 Nam S, Tratnyek P G. Water Research, 2000, 34(6), 1837. 14 Zhang C, Zhu Z, Zhang H, et al. Journal of Non-Crystalline Solids, 2012, 358(1), 61. 15 Karabelli D, Üzuüm C R, Shahwan T, et al. Industrial & Engineering Chemistry Research, 2008, 47(14), 4758. 16 Üzüm Ç, Shahwan T, Erogˇlu A E.Applied Clay Science, 2009, 43(2), 172. 17 Mirbagheri S A, Hosseini S N. Desalination, 2005, 171(1), 85. 18 Hatfield T L, Pierce D T. Journal of Applied Electrochemistry, 1998, 28(4), 397. 19 Huang W F, Xu J. Mineral Engineering, 2005, 3(4), 36(in Chinese). 黄万抚, 徐洁. 矿业工程, 2005, 3(4), 36. 20 Zhou X Y, Tian Y Y, Zhang J B. Water Treatment Technology, 2015(2), 56. 周晓勇, 田亚运, 张举斌. 水处理技术, 2015(2), 56. 21 Rudnick I, Hubick I, Kolodynsk A. Chemical Engineering Journal, 2014, 252(252), 362. 22 Zhang C, Zhang H, Lv M, et al. Journal of Non-Crystalline Solids, 2010, 356(33), 1703. 23 Parra S, Guasaquillo I, Enea O, et al. The Journal of Physical Chemistry B, 2003, 107(29), 7026. 24 Rani R D, Sasidhar P. Aquatic Geochemistry, 2012, 18(4), 281. 25 Dong C, Wang Q, Qiang J B, et al. Journal of Physics D: Applied Phy-sics, 2007, 40(15), R273. 26 Miracle D B. Nature Materials, 2004, 3(10),697. |
|
|
|