| MATERIALS AND SUSTAINABLE DEVEL OPMENT:ENVIRONMENT-FRIENDLYMATERIALS AND MATERIALS FOR ENVIRONMENTAL REMEDIATION |
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| Research Progress of Graphene Oxide/Metal Organic Frameworks Composite Membrane in Organic Wastewater Treatment |
| LIU Yucheng1,2, ZHU Meng1, CHEN Mingyan1,2, TU Wenwen1, GAN Dong1
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1 College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China;
2 Institute of Industrial Waste Disposal and Resource Utilization, Southwest Petroleum University, Chengdu 610500, China |
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Abstract Graphene has attracted much attention due to its mechanical properties, electronic effects, optical properties, thermal properties and other chemical properties. Its oxidation product, graphene oxide (GO), has both the above excellent properties and rich hydroxyl and carboxyl groups. GO is a two-dimensional material with unique atomic thickness and micron transverse size, excellent mechanical strength, large surface area and strong hydrophilicity. It has broad application prospects in water treatment. In recent years, great progress has been made in the preparation and application of GO composite membranes. However, in the treatment of organic wastewater, the instability of composite membranes hinders its development.
GO membrane has a higher removal rate of organics, but the low flux, low rejection, poor stability and the layer spacing limit its application in water treatment. Therefore, in addition to investigate the factors affecting the treatment effect of graphene oxide membrane, researchers consi-dered add appropriate porous metal organic frameworks (MOFs) into grapheme oxide to prepare functional composite membrane. In addition, some achievements have been achieved. At present, the removal rate of organic dyes such as methylene blue and Congo red by GO/MOFs composite membrane can reach 99%, which is about 55% higher than that of pure GO membrane.
In the study of organic wastewater treatment by composite membranes, the composite membranes with better treatment effect are as follows: graphene oxide/copper-based (HKUST-1) composite membrane, graphene oxide/zirconium-based (UiO-66) composite membrane and graphene oxide/zinc-based (ZIF-8) composite membrane. Copper-based MOFs and GO composite membranes are widely used in organic and oily wastewater treatment and gas separation. The addition of MOFs can effectively increase the interlayer spacing of GO, and improve the hydrophilicity of composite membranes. It can be also provide an effective channel and driving force for the passage of water molecules. In addition, the flux and decontamination performance of the composite membranes can be improved.
In this paper, the research and application at home and abroad of GO/MOFs composite membrane is introduced. The research progress of GO/MOFs composite membrane in the treatment of refractory organic matter and organic dye wastewater is mainly discussed. The mechanism of organic matter removal by composite membrane is further discussed. In addition, development prospects of GO/MOFs composite membranes are prospected. Based on the characteristics of two excellent adsorbents, the composite membranes with high throughput, high removal rate and superior anti-fouling performance will be applied in more fields.
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Published: 10 April 2020
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| Fund:This work was financially supported by Sichuan Science and Technology Plan Key Research and Development Project Funding (2018GZ0421). |
About author:: Yucheng Liu, Ph.D. supervisor, professor, College of Chemistry and Chemical Engineering, Southwest Petroleum University, dean of Institute of Industrial Dangerous Waste Disposal and Resource Utilization. In June 1999, he received a bachelor’s degree from the College of Chemistry and Chemical Engineering of Southwest Petroleum University, a master’s degree from the College of Chemistry and Chemical Enginee-ring of Southwest Petroleum University in June 2001, a doctorate in environmental engineering of Sichuan University in 2012—2017, and a visiting scholar in environmental engineering of the University of Connecticut in 2015—2016. He has won the Sichuan Youth Science and Technology Award and the reserve candidates for Sichuan Academic and Technological Leaders. He is also a member of the Expert Committee of Sichuan Eco-civilization Promotion Association, a member of the Expert Advisory Committee of Sichuan Circular Economy Association, a technical review expert of Sichuan Environmental Protection Department, and a project evaluation expert of Sichuan Science and Technology Department. Mainly engaged in oil and gas field environmental chemistry, pollution control, oil contaminated soil microbial remediation research work. In recent years, more than 80 papers have been published in the field of environmental chemistry in oil and gas fields, including Applied Energy, Sensors and Actuators B: Chemical, Biosensors and Bioelectronics, Chemical Engineering Journal, International Journal of Greenhouse Gas Control, Engineering Chemistry Research and Bioresource Technology.
Meng Zhugraduated from Southwest Petroleum University in 2017 with a bachelor’s degree in enginee-ring. Now she is a Ph.D. postgraduate student of College of Chemistry and Chemical Engineering, Southwest Petroleum University, under the guidance of Professor Liu Yucheng. At present, the main research area is the application of graphene oxide-based materials in water treatment. She has published an article in the Chemical Engineering Journal. |
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2020, Vol. 34 
