Fe-基形状记忆合金的研究进展

doi:10.11896/cldb.18120204

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Abstract Shape memory alloys are classified into three categories according to practical application values: NiTi-based alloys, Cu-based alloys and Fe-based alloys. The field of shape memory alloys has been dominated by NiTi alloys. However, NiTi-based shape memory alloys have the di-sadvantages of high material cost and poor cold workability. The Cu-based shape memory alloys have good hot workability and shape memory effect, but the Cu-based shape memory alloy have unstable memory performance, coarse grain and poor fatigue resistance, which hinders its research and application. Fe-based shape memory alloys have attracted much attention for their low cost, excellent workability and good weldability, and have been identified as a new shape memory material with promising development.
The martensitic transformation of Fe-based shape memory alloys is mainly divided into three types, namely, face-centered cubic fcc (γ) → face-centered square fct, body-centered square bct, and close-packed hexagonal hcp (ε). Alloys with fcc(γ)→fct martensitic transformation and reverse phase transformation to achieve shape memory effect are Fe-Pd and Fe-Pt alloys. Alloys obtained by fcc(γ)→bct martensitic transformation and reverse phase transformation to obtain shape memory effects include Fe-Ni-Ti-C and Fe-Ni-Co-Ti alloys. The shape memory effect of the Fe-Mn-Si alloy exhibites the fcc(γ)→hcp(ε) martensitic transformation and its reverse phase transformation. Because Pd and Pt are expensive, the Fe-Pt/Fe-Pd shape memory alloys are not very practical and only used for academic research. Fe-Mn-Si shape memory alloy has a phase transition temperature close to room temperature and a relatively good shape memory effect, which makes it have a good application prospect. Because of Ms and large hysteresis, it hinders the wide range of applications of Fe-based shape memory alloys. However, the Fe-Ni-Co-Ti martensite interface has a initiative that does not change due to the thermal hysteresis. When the alloy is cooled or heated, it grows and contracts due to the movement of the martensite interface. Major success is now within reach with new class of Fe-Mn-Al-Ni alloys on the basis of the superelastic study of Fe-Ni-Co-Ti alloy. They exhibit superior superelastic properties and undergo superelasticity response at room temperature with low stress hysteresis. One of the characteristics of Fe-Mn-Al-Ni alloy is that the stress required to induce martensitic transformation has a low temperature dependence over a broad range, -196 ℃ to 240 ℃. This greatly broadens the application of Fe-based SMAs.
In this paper, the research progress of Fe-based shape memory alloys and their related properties are introduced in recent years. In particular, the effects of various elements in Fe-Mn-Si shape memory alloys on alloys are introduced in detail, which is related to the composition design of alloys. In the aspect of alloy composition design, this paper provides a reference for relative researchers and points out the existing problems at the present stage.

Key words： shape memory effect martensitic transformation alloying elements nonthermoelastic

Published: 30 September 2019

CLC number:

TB381

Fund:This work was financially supported by Natural Science Foundation of Hebei Province, China (E2015203232), the Program for the Top Young Talents of Hebei ([2016]9) and the Special Funds for the Danfeng Chaoyang Talent Plan ([2019]3).

About author:: Qin Zou received her B.E.degree in chemistry from Yanshan University in 2001 and received her Ph.D. degree from the Kochi University of Technology in 2008.After two-year postdoctoral research at Yanshan, she is currently a full professor in Yanshan University. Her research interests are new type of superhard tool, maintenance-free bearing, and high entropy alloy.
Mingzhi Wang has been engaged in scientific research on superhard materials and superhard composite mate-rials and special compound related materials for many years. He has won the second prize of scientific and technological progress of the Ministry of Machinery Industry and the third prize of the State Education Commission for scientific and technological progress. In 1995, he was awarded the title of Chinese science and technology expert by the Ministry of Machinery Industry. In 1998, he was granted a special government allowance issued by the State Council.

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Cite this article:

ZOU Qin,DANG Shang,LI Yanguo, et al. Research Progress of Iron-based Shape Memory Alloys: a Review[J]. Materials Reports, 2019, 33(23): 3955-3962.

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http://www.mater-rep.com/EN/10.11896/cldb.18120204 OR http://www.mater-rep.com/EN/Y2019/V33/I23/3955

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