芳纶纳米纤维的制备及应用研究进展

doi:10.11896/cldb.18120041

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Abstract With the advancement of nanoscience and technology, various nanomaterials like nanocellulose, carbon nanotube, graphene nanosheet and metal nanorod are gradually coming into people’s view. Based on the special nanometer effect, nanomaterials exhibit physical or chemical properties those conventional macroscopical materials do not have, which have been developed rapidly in the various fields of science. Among them, high-performance nanoscale building blocks such as aramid nanofibers (ANFs) are one of the research hotspots. However, it is quite difficult to achieve the nanoscale preparation of aramid fibers due to their characteristics like high strength and modulus, high crystallinity and excellent corrosion resistance. Therefore, it really remains an urgent need to seek for a simple, quick and effective ANFs preparation technique to achieve the functionalization, high-performance and multipurpose utilization of the intersection of various scientific fields of ANFs.
　　At present, there are just a few available techniques to prepare ANFs, which can be mainly divided into top-to-bottom and bottom-to-top two strategies. The top-to-bottom strategy refers to the electrospinning, rotary jet-spinning, mechanical disintegration synergized by alkaline and alkaline dissolution, whilst the bottom-to-top strategy points to the polymerization assisted by dispersion. Among these ANFs preparation techniques, alkaline dissolution is the most widely used one which has not only achieved the efficient and controllable preparation of ANFs, but also has better retained the advantages of aramid fibers in terms of structure and performance. Combined with the dual advantages of excellent performances of aramid fiber and special nanoscale effects of nanofiber, ANFs can effectively solve the problems of high chemical inertness, low reactive activity and poor interfacial adhesion of aramid fibers as a novel nanoscale building block. This makes ANFs display promising prospects in composite reinforcement, battery separator, adsorption filtration, electrical insulation and flexible electrode fields. Nevertheless, some problems also exist in the preparation and application of ANFs: first, ANFs preparation techniques still has the difficulty in their long preparation period, high energy consumption, large fiber size and low film forming strength; the application studies of ANFs are still in the laboratory research stage, and there is still a long distance to achieve their real scale, functionalization and utilization of high-performance.
　　This review focuses on the research progress of ANFs. Firstly, the preparation techniques of ANFs are introduced. Then the applications of ANFs in various fields are analyzed, and we present the main problems that ANFs are facing and some prospects are given. The purpose of this work is to offer a reference for the low energy consumption but high efficiency preparation and high-value utilization of ANFs.

Key words： para-aramid aramid nanofibers(ANFs) efficient preparation nanocomposites electronic energy device

Published: 16 January 2020

CLC number:

TQ342.72

About author:: Meiyun Zhangreceived her Ph.D. degree in pulp and paper industry from Tianjin University of Science and Technology. Her research interest mainly include high-performance paper-based functional materials. She took charge of over twenty research projects successively, including the Key Research and Development Project in the National 13th Five-Year Plan (as chief scientist), the National 863 Project and the National Natural Scie-nce Foundation. She has received many honors including the National Ten Thousands Distinguished Teachers Program, the Expert with Special Allowance from the Government of the State Council, the Natio-nal Outstanding Teacher, the National Outstanding Scientific and Technological Worker, the China’s Cailun Prize for Papermaking, the Top Talent of Shaanxi in the Key Fields and the Expert of Shaanxi with Outstanding Contributions. She has received 14 awards of science and technology at the provincial level or above, and published more than 490 papers, 6 invited books and 56 patents;Jingjing Luoreceived her B.S. degree in paperma-king industry from Shaanxi University of Science & Technology in 2016. She is currently pursuing her M.S. Degree at the Institute of Bioresources Chemical and Materials Engineering,Shaanxi University of Science and Technology under the supervision of Prof. Zhang. Her research has focused on the preparation and application of aramid nanofibers;Bin Yangreceived his B.E. degree in 2010 in papermaking engineering from Shaanxi University of Science & Technology. After graduation from Shaanxi University of Science & Technology in 2013, he works in Shaanxi University of Science & Technology. His research inte-rests are high-performance paper-based materials and advanced functional fiber-based nanomaterials. He is currently pursuing his Ph.D. of materials science at Northwestern Polytechnical University. He has received 2 awards of science and technology, and published more than 10 papers in ACS Nano, ACS Sustain. Chem. Eng., Compos. Part B-Eng., etc.

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Cite this article:

ZHANG Meiyun,LUO Jingjing,YANG Bin, et al. Research Progress of Preparation and Application of Aramid Nanofibers[J]. Materials Reports, 2020, 34(5): 5158-5166.

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http://www.mater-rep.com/EN/10.11896/cldb.18120041 OR http://www.mater-rep.com/EN/Y2020/V34/I5/5158

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