利用微电极阵列技术研究合金的腐蚀

doi:10.11896/cldb.18110069

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Abstract With the booming development and improvement of the industries, the employment of alloy materials also increases. However, the corrosion problem of alloy materials has caused incalculable losses to industrial production and ecological environment. In order to reduce the da-mage and impact of various aspects caused by alloy corrosion, domestic and foreign scholars have carried out a large number of researches on alloy corrosion mechanism and protection, and some research progress has been made.
Microelectrode array technology is a new type of electrochemical test method between macroscopic classical electrochemical technology and micro-area scanning probe technology. It can not only obtain the overall average information of the large-area electrode of the alloy, but also detect the characteristics of potential and current distribution in the local micro-area of the alloy. Compared with the macroscopic classical electrochemical technology, it can more accurately test the heterogeneous electrochemical information in the local corrosion process of the alloy. The optimization of such microelectrode arrays has been realized with the continuous research and development of scholars at home and abroad. By the combination of other electrochemical testing techniques and surface science and technology methods, the physical, chemical and electrochemical information of the alloy/corrosion solution interface has been enriched. In recent years, a great deal of experts and scholars have used this microelectrode array technology combined with other testing techniques to study the local corrosion process and mechanism of common alloys under diffe-rent environments and corrosion conditions, and achieved important research progress. The research on the galvanic corrosion behavior and evolution law of different material metals has made a major breakthrough. In addition, the development and application of real-time coupled multi-electrode array sensor (CMAS) probes play an important role in online monitoring/detection of local corrosion of alloys.
In this paper, we reviewed the progress of microelectrode array technology in the study of galvanic corrosion, surface coating failure and the influence of corrosion environment on alloy. Then we summarized the merits and demerits of microelectrode array technology in characterizing the local electrochemical heterogeneity of the alloy and the future trend was prospected.

Key words： alloy microelectrode array general corrosion local corrosion galvanic corrosion electrochemistry coating failure

Published: 30 September 2019

CLC number:

TG171

Fund:This work was financially supported by the Fundamental Research Funds for the Central Universities (18CX02128A), and the National Natural Science Foundation of China (51701239).

About author:: Hongmei Bu received her B.E. degree from the College of Materials Science and Engineering, China University of Petroleum (East China) in 2017. She is currently pursuing her master’s degree at Materials Science and Engineering, China University of Petroleum (East China) under the supervision of Prof. Yan Li and associate professor Jiantao Qi. Her research was funded by the NSFC project of “Multiscale Characterization and Controllable Preparation of Functional Conversion Coatings on Magnesium Alloys”.
Jiantao Qi received his bachelor degree in the College of Chemical Engineering, China University of Petroleum (CUP, East China) in 2011 and the doctoral degree from Corrosion and Protection Centre, School of Mate-rials, University of Manchester in 2015. He has rich engineering and research experience as an independent postdoc researcher, competing the LATEST 2 project with Prof. George Thompson (OBE, RAE Fellow) at University of Manchester and the NEPAL FUI project in the PCS lab (ENSCP-CNRS) with cooperation of Prof. Philippe Marcus. He started as a lecture in the CUP at June 2016 and was promoted to be a full associate professor and supervisor of master students at Dec. 2017. His research focuses on corrosion and protection of alloys, including surface modification, functional conversion coatings, physics and chemistry at the surface and interface, SERS Raman, XPS, RBS, electrochemical assessments and corrosion protection strategy.

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Cite this article:

BU Hongmei,LI Xiaowei,QI Jiantao, et al. Microelectrode Array Technology Used for Investigating the Corrosion of Alloys[J]. Materials Reports, 2019, 33(23): 3963-3970.

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http://www.mater-rep.com/EN/10.11896/cldb.18110069 OR http://www.mater-rep.com/EN/Y2019/V33/I23/3963

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