| POLYMERS AND POLYMER MATRIX COMPOSITES |
|
|
|
|
|
| Advances in Organogels with State and Colorimetric Response to Fluoride |
| WEI Xueyu1, YANG Xiaofan2, BAI Binglian3, XU Xiaoping1, LI Jiyuan1, LIU Zhigang4
|
1.School of Architecture and Civil Engineering, Anhui Polytechnic University, Wuhu 241000;
2.College of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu 241000;
3.College of Physics, Jilin University, Changchun 130012;
4.Ningbo Water Supply Co. Ltd., Ningbo 315041 |
|
|
|
Abstract The fluoride-responsive organogels, the recognization and combination of the gelators with fluoride anions through hydrogen bonding will induce the red shift of UV absorption wavelength and then the change of color, realizing the colorimetric response. At the same time, the main driving force of gel formation is destroyed, and the gel-sol transition is induced to achieve the state response. The fluoride-responsive organogels capable of responding to external fluoride anions show obvious advantages in fluoride anion detection, because the convenient and quick detection by naked eyes, and the detection of fluoride anions to quasi solid can be realized. Therefore, the fluoride-responsive organogels have attracted more and more attention.
It has been reported that many fluoride-responsive organogels only hold single response mode to fluoride anions. Specifically speaking, the addition of fluoride anions can only induce the gel-sol transition and fail to induce color change of the system, or it only bring about color change of the system rather than the gel-sol transition. Accordingly, the fluoride-responsive organogels capable of both response modes, namely presenting gel-sol transition and color changes, to fluoride anions are superior in fluoride detection.
Up to now, the researches on fluoride-responsive organogels with dual response modes to fluoride anions have been reported. Most researches focus on organogels based on intermolecular hydrogen bonding, their gelators contain functional groups like amide, hydrazone, urea, hydrazine, and so forth, and the main driving force for the formation of organogels lies in intermolecular hydrogen bonding interaction. Thanks to the strong electronegativity of fluoride anions, the deprotonation of gelators will take place, resulting in the destruction or color change of the organogels. Consequently, the response mechanism of fluorine ions primarily consists of hydrogen bonding interaction and deprotonation process. However, the responsive process of fluoride anions and gelators are quite different in various systems, which is not only directly related to the type of hydrogen bond provided by the gelators, but also affected by the conjugated groups, the nature and location of the substituents. Therefore, a comprehensive summary concerning the fluorine-responsive organogels is necessary.
Based on this, combining with the recent research results of our group on fluoride-responsive organogels, we summarize the fluoride-responsive organogels reported in the literatures in recent years, especially the organogel systems which showed both reversible color change and gel-sol transition by fluoride anions stimuli, for the sake of providing some references for molecular design of the organogels with fluoride anions response.
|
|
Published: 10 May 2019
|
|
|
| Fund:This work was supported by the Natural Science Foundation of Jilin Province (20170101112JC), Preliminary Research Project of National Natural Science Foundation of Anhui Polytechnic University (zryy1310), Anhui Provincial Natural Science Foundation (1808085ME133) and the Key Project of Anhui University of Natural Science Foundation (KJ2017A119). |
About author:: Xueyu Wei, teacher, School of Architecture and Civil Engineering in Anhui Polytechnic University, receiving his Master’s degree in 2007 from Ningxia University. He has hosted and participated in 3 provincial and ministerial projects and published dozens of research papers.
Binglian Bai is a professor of College of Physics at Jilin University. She received her Ph.D. degree from Institute of Materials Science and Engineering, Jilin University, in 2007. She has published 70 SCI papers. Recently, her research interests are stimuli-responsive supramole-cular organogels. |
|
|
1 Padie C, Zeitler K. New Journal of Chemistry,2011,35,994.
2 Ren J, Wu Z, Zhou Y, et al. Dyes and Pigments,2011,91,442.
3 Gai L Z, Chen H C, Zou B, et al. Chemical Communication,2012,48,10721.
4 Buckland D, Bhosale S V, Langford S J. Tetrahedron Letter,2011,52,1990.
5 He X M, Hu S Z, Liu K, et al. Organic Letter,2006,8,333.
6 Cho E J, Ryu B J, Lee Y J, et al. Organic Letter,2005,7,2607.
7 Esteban-Gómez D, Fabbrizzi L, Licchelli M. Journal of Organic Chemistry,2005,70,5717.
8 Vázquez M, Fabbrizzi L, Taglietti A, et al. Angewandte Chemie International Edition,2004,43,1962.
9 Jose D A, Kumar D K, Ganguly B, et al. Organic Letter,2004,6,3445.
10 Mizuno T, Wei W H, Eller L R, et al. Journal of the American Chemical Society,2002,124,1134.
11 Woods J C, Camiolo S, Light M E, et al. Journal of the American Chemical Society,2002,124,86442.
12 Cho E J, Moon J W, Ko S W, et al. Journal of the American Chemical Society,2003,125,12376.
13 Lee J Y, Cho E J, Mukamel S, et al. Journal of Organic Chemistry,2004,69,943.
14 Liu B, Tian H. Chemistry Letters,2005,34,686.
15 Boiocchi M, Boca L D, Gómez D E, et al. Journal of the American Che-mical Society,2004,126,16507.
16 Zhao Y, Li Y, Qin Z, et al. Dalton Transactions,2012,41,13338.
17 Zhou Y, Zhang J, Yoon J. Chemical Reviews,2014,114,5511.
18 Santos-Figueroa L E, Moragues M E, Climent A, et al. Chemical Society Reviews,2013,42,3489.
19 Parthiban C, Elango K P. Sensors & Actuators B: Chemical,2015,215,544.
20 Chowdhury A R, Ghosh P, Roy B G, et al. Sensors & Actuators B: Chemical,2015,220,347.
21 Wang L, Fang G, Cao D. Sensors & Actuators B: Chemical,2015,221,63.
22 Biswas S, Gangopadhyay M, Barman S, et al. Sensors & Actuators B: Chemical,2016,222,823.
23 Fu Y, Fan C, Liu G, et al. Sensors & Actuators B: Chemical,2017,239,295.
24 Nemati M, Hosseinzadeh R, Zadmard R, et al. Sensors & Actuators B: Chemical,2017,241,690.
25 Chowdhury A R, Roy B G, Jana S, et al. Sensors & Actuators B: Chemical,2017,241,706.
26 Nie L, Zhang Q, Hu L, et al. Sensors & Actuators B: Chemical,2017,245,314.
27 Parthiban C, Elango K P. Sensors & Actuators B: Chemical,2017,245,321.
28 Sessler J L, Cho D G, Lynch V. Journal of the American Chemical Society,2006,128,16518.
29 Shiraishi Y, Maehara H, Hirai T. Organic & Biomolecular Chemistry,2009,7,2072.
30 Tu T, Fang W, Sun Z. Advanced Materials,2013,25,5304.
31 Maeda H. Chemistry—A European Journal,2008,14,11274.
32 Yang X, Zhang G, Zhang D. Journal of Materials Chemistry,2012,22,38.
33 Terech P, Weiss R G. Chemical Reviews,1997,97,3133.
34 Jones C D, Steed J W. Chemical Society Reviews,2016,45,6546.
35 Yang H, Yi T, Zhou Z, et al. Langmuir,2007,23,8224.
36 Lloyd G O, Piepenbrock M O M, Foster J A, et al. Soft Matter,2012,8,204.
37 Yamanaka M, Nakamura T, Nakagawa T, et al. Tetrahedron Letter,2007,48,8990.
38 Teng M, Kuang G, Jia X, et al. Journal of Materials Chemistry,2009,19,5648.
39 Xu D, Liu X, Lu R, et al. Organic & Biomolecular Chemistry,2011,9,1523.
40 Liu C, Su M, Li X, et al. Soft Matter,2015,11,5727.
41 Baddi S, Palanisamy A. Sensors & Actuators B: Chemical,2017,245,711.
42 Ren Y Y, Xu Z, Li G Q, et al. Dalton Transactions,2017,46,333.
43 Wang C, Zhang D, Zhu D. Langmuir,2007,23,1478.
44 Lin Q, Zhu X, Fu Y, et al. Soft Matter,2014,10,5715.
45 Lin Q, Zhu X, Fu Y, et al. Dyes and Pigments,2015,113,748.
46 Džolicć Z, Cametti M, Cort A D, et al. Chemical Communication,2007,34,3535.
47 Wang S, Shen W, Feng Y, et al. Chemical Communication,2006,14,1497.
48 Zhang Y, Jiang S. Organic & Biomolecular Chemistry,2012,10,6973.
49 Xue P, Zhang Y, Jia J, et al. Soft Matter,2011,7,8296.
50 Xue P, Lu R, Jia J, et al. Chemistry—A European Journal,2012,18,3549.
51 Xue P, Sun J, Xu Q, et al. Organic & Biomolecular Chemistry,2013,11,1840.
52 Geng L, Feng G, Wang S, et al. Journal of Fluorine Chemistry,2015,170,24.
53 Zhang X, Lee S, Liu Y, et al. Scientific Reports,2014,4,4593.
54 Kim T H, Kwon N Y, Lee T S. Tetrahedron Letter,2010,51,5596.
55 Rajamalli P, Prasad E. Organic Letter,2011,13,3714.
56 Rajamalli P, Prasad E. Soft Matter,2012,8,8896.
57 Rajamalli P, Prasad E. Langmuir,2013,29,1609.
58 Wei J, Chai Q, He L, et al. Tetrahedron,2016,72,3073.
59 Zhang Y, Lin Q, Wei T, et al. Chemical Communication,2009,40,6074.
60 Ghosh K, Pati C. Tetrahedron Letter,2016,57,5469.
61 Yu X, Xie D, Li Y, et al. Sensors & Actuators B: Chemical,2017,251,828.
62 Kim T H, Choi M S, Sohn B, et al. Chemical Communication,2008,20,2364.
63 Ghosh K, Kar D. Organic & Biomolecular Chemistry,2012,10,8800.
64 Liu J, Yang Y, Chen C, et al. Langmuir,2010,26,9040.
65 Mehdi H, Pang H, Gong W, et al. Organic & Biomolecular Chemistry,2016,14,5956.
66 Bai B, Ma J, Wei J, et al. Organic & Biomolecular Chemistry,2014,12,3478.
67 Bai B, Mao X, Wei J, et al. Sensors & Actuators B: Chemical,2015,211,268.
68 Gu X, Bai B, Wang H, et al. RSC Advances,2017,7,218.
69 Bai B, Zhang M, Wei J, et al. Tetrahedron,2016,72,5363.
70 Gu X, Bai B, Wei Z, et al. Journal of Molecular Liquids,2016,222,425.
71 Lee J, Kwon J E, You Y, et al. Langmuir,2014,30,2842.
72 Zang L, Shang H, Wei D, et al. Sensors & Actuators B: Chemical,2013,185,389.
73 Boiani M, Baschieri A, Cesari C, et al. New Journal of Chemistry,2012,36,1469.
74 Chen H, Feng Y, Deng G, et al. Chemistry—A European Journal,2015,21,11018.
75 Xing L, Yang B, Wang X, et al. Langmuir,2013,29,2843.
76 Li R, Wang S, Li Q, et al. Dyes and Pigments,2017,137,111. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2019, Vol. 33 
