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材料导报  2020, Vol. 34 Issue (7): 7010-7014    https://doi.org/10.11896/cldb.19070181
  材料与可持续发展(三)环境友好——环境友好材料与环境修复材料* |
Fe-Si-B非晶合金对溶液中Cu (Ⅱ)的去除效率
张香云, 杜进英, 袁子洲, 李金祺
兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
Removal Efficiency of Cu(Ⅱ) by Fe-Si-B Amorphous Alloy
ZHANG Xiangyun, DU Jinying, YUAN Zizhou, LI Jinqi
State Key Laboratory of Gansu Advanced Processing and Recycling of Non-ferrous Metal, Lanzhou University of Technology, Lanzhou 730050, China
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摘要 采用单辊甩带法成功制备了Fe-Si-B非晶合金条带,并以300目铁粉为参比物,研究了其对溶液中Cu (Ⅱ)的去除效果。结果表明,60 min内,1 g/L的Fe-Si-B非晶合金条带对100 mg/L Cu (Ⅱ)的去除效率大于98%,且去除过程符合伪一级动力学模型。相同条件下,Fe-Si-B非晶合金条带去除Cu (Ⅱ)的表面积约化反应速率常数是300目铁粉的167倍。通过分析不同环境因素对Fe-Si-B非晶合金条带去除Cu (Ⅱ)效率的影响,发现反应速率与温度、pH值成正比,与Cu (Ⅱ)浓度成反比。在重复使用六次后,Fe-Si-B非晶合金条带仍保持67%的去除效率。
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张香云
杜进英
袁子洲
李金祺
关键词:  Fe-Si-B非晶合金  Cu(Ⅱ)  去除效率    
Abstract: In this work, the Fe-Si-B amorphous alloy ribbons were successfully prepared by melt-spinning technique and compared with commercial 300 mesh iron powders for Cu(Ⅱ) removal efficiency. The results show that Fe-Si-B amorphous alloy ribbons were efficient in removing Cu(Ⅱ) from aqueous solution containing 100 mg/L of Cu(Ⅱ), where more than 98% of Cu(Ⅱ) was removed within 60 min using 1 g/L Fe-Si-B amorphous alloy ribbons, and the removal process can be described by a pseudo-first-order kinetic model. Under the same conditions, the surface normalized reaction rate constants for the removal of Cu(Ⅱ) by Fe-Si-B amorphous alloy ribbons is 167 times than that of 300 mesh iron powders. And the removal rate is proportional to solution pH and temperature, but inversely proportional to Cu(Ⅱ) concentration. In addition, it was found that the ribbons still exhibited 67% removal efficiency after six repeated uses.
Key words:  Fe-Si-B amorphous alloy    Cu (Ⅱ)    removal efficiency
                    发布日期:  2020-04-10
ZTFLH:  TG139.8  
通讯作者:  yuanzz@lut.cn   
作者简介:  张香云,2015年获得兰州理工大学博士学位。目前是兰州理工大学副教授。主要从事非晶合金的研究工作,在国内外重要期刊发表文章20多篇。
袁子洲,2008年获得兰州理工大学博士学位。目前是兰州理工大学教授。主要从事消失模铸造及非晶合金的研究工作,在国内外重要期刊上发表文章百余篇。
引用本文:    
张香云, 杜进英, 袁子洲, 李金祺. Fe-Si-B非晶合金对溶液中Cu (Ⅱ)的去除效率[J]. 材料导报, 2020, 34(7): 7010-7014.
ZHANG Xiangyun, DU Jinying, YUAN Zizhou, LI Jinqi. Removal Efficiency of Cu(Ⅱ) by Fe-Si-B Amorphous Alloy. Materials Reports, 2020, 34(7): 7010-7014.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19070181  或          http://www.mater-rep.com/CN/Y2020/V34/I7/7010
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