近紫外白光LED用Ba3Y1-x-yB3O9∶xEu3+,yBi3+高效红色荧光粉的制备与发光性能

doi:10.11896/cldb.19050130

材料导报

2020, Vol. 34

Issue (14): 14023-14026 https://doi.org/10.11896/cldb.19050130

无机非金属及其复合材料

近紫外白光LED用Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺高效红色荧光粉的制备与发光性能

温慧霞, 樊彬, 李红喜, 许成功, 王玉莹, 赵文玉

内蒙古科技大学化学与化工学院, 包头 014010

Preparation and Luminescence Properties of Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺ High-efficiency Red Phosphors for Near-UV White LEDs

WEN Huixia, FAN Bin, LI Hongxi, XU Chenggong, WANG Yuying, ZHAO Wenyu

School of Chemistry and Chemical Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China

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摘要采用传统高温固相法在较低温度下制备Eu³⁺/Bi³⁺共掺杂Ba₃YB₃O₉红色荧光粉,利用XRD仪和荧光光谱仪对样品Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺的晶体结构和发光性质进行了表征。XRD结果表明,Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺为纯相晶体。激发和发射光谱表明,样品可以被近紫外350～420 nm波段激发,最强激发峰位于393 nm,发射光谱呈现出Eu³⁺的特征峰,谱带峰值位置在593 nm、613 nm,分别对应⁵D₀-⁷F₁、⁵D₀-⁷F₂特征跃迁。最强发射对应的掺杂浓度是0.12 mol。Ba₃Y_0.87B₃O₉∶0.12Eu³⁺,0.01Bi³⁺的CIE坐标为(0.643,0.356)时最接近标准红色坐标,获得极佳的演色性。样品Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺可以用作近紫外激发三基色白光LED的红色荧光粉。

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关键词: 红色荧光粉 Eu³⁺掺杂高温固相法白光LED

Abstract: The Eu³⁺/Bi³⁺ ion co-doped Ba₃YB₃O₉ red phosphor was prepared by the traditional high temperature solid phase method at low temperature. The crystal structure and luminescence properties of the samples Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺ were characterized by XRD and the fluorescence spectrometer. XRD results illustrated that Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺ were pure phase crystals. The excitation and emission spectra showed that the sample could be excited by the near-ultraviolet 350—420 nm band. The strongest excitation peak was located at 393 nm. The emission spectrum showed the characteristic peak of Eu³⁺. The peak position of the band was at 593 nm and 613 nm, corresponding to⁵D₀-⁷F₁, ⁵D₀-⁷F₂ feature transition. The doping concentration corresponding to the strongest emission was 0.12 mol. The CIE coordinate of the concentration of Ba₃Y_0.87B₃O₉∶0.12Eu³⁺, 0.01Bi³⁺is (0.643, 0.356) which was closest to red, and excellent color rendering was obtained. The sample Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺ phosphor was red phosphor for near-ultraviolet excitation trichromatic white LED with potential application.

Key words: red phosphor Eu³⁺ doping high temperature solid state method W-LEDs

出版日期: 2020-07-25 发布日期: 2020-07-14

ZTFLH:

O482.31

基金资助: 内蒙古自然科学基金(2018MS02002)

作者简介: 温慧霞,女,内蒙古科技大学化学与化工学院硕士研究生。主要研究光学材料制备与性能。
赵文玉,博士,硕士研究生导师,内蒙古科技大学化学与化工学院副教授。曾任中国台湾长庚大学可靠度科学技术研究中心博士后研究员(02/2016—02/2017),从事光学材料制备与性能及其老化机理研究。在国内外重要期刊发表文章20多篇,申报发明专利2项。

引用本文:

温慧霞, 樊彬, 李红喜, 许成功, 王玉莹, 赵文玉. 近紫外白光LED用Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺高效红色荧光粉的制备与发光性能[J]. 材料导报, 2020, 34(14): 14023-14026.
WEN Huixia, FAN Bin, LI Hongxi, XU Chenggong, WANG Yuying, ZHAO Wenyu. Preparation and Luminescence Properties of Ba₃Y_1-x-yB₃O₉∶xEu³⁺,yBi³⁺ High-efficiency Red Phosphors for Near-UV White LEDs. Materials Reports, 2020, 34(14): 14023-14026.

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http://www.mater-rep.com/CN/10.11896/cldb.19050130 或 http://www.mater-rep.com/CN/Y2020/V34/I14/14023

1 Li B, Wang S Y, Sun Q, et al. Dyes and Pigments, 2018, 154, 252.
2 Xie Z, Zhou W W, Zhao W, et al. Chemical Physics Letters, 2017, 685, 177.
3 Kaur S, Jayasimhadri M, Rao A S. Journal of Alloys and Compounds, 2017, 697, 367.
4 Zhu Y H, Wang H B, Jiang Q S, et al. China Light and Lighting, 2014(8), 1(in Chinese).
朱月华,王海波,姜青松,等. 中国照明电器, 2014(8), 1.
5 Zhang X G, Zhang J L, Gong M L. Optical Materials, 2014, 36(4), 850.
6 Hussain S K, Yu J S. Journal of Luminescence, 2017, 183, 39.
7 Park S J, Je B S, Jang J W, et al. Journal of Alloys and Compounds, 2019,789,367.
8 Li X X. Advanced Materials Research, 2014, 906, 60.
9 Gül G C, Kurtulus F. Archives of Materials Science and Engineering, 2016, 78(1), 5.
10 Ning H Y, Cheng Z Y, Dong C, et al. Chinese Journal of Luminescence, 2018, 39(8), 1087(in Chinese).
宁宏宇, 程志远, 董超, 等. 发光学报, 2018, 39(8), 1087.
11 Dong Y, Jiang J Q, Liu G, et al. Journal of Functional Materials, 2004(3), 352(in Chinese).
董岩, 蒋建清, 刘刚, 等. 功能材料, 2004(3), 352.
12 Vijayakumar R, Guo H, Huang X Y. Dyes and Pigments, 2018, 156, 8.
13 Li Z, Pian Q L, Li L, et al. Optik, 2018, 161, 38.
14 Zhai Y Q, Zhao X, Yang S, et al. Chinese Journal of Luminescence, 2017, 38(8), 987(in Chinese).
翟永清,赵鑫,杨帅,等. 发光学报, 2017, 38(8), 987.
15 Xie F Y, Dong Z Y, Wen D W, et al. Ceramics International, 2015, 41(8), 9610.
16 Guo H, Huang X Y, Zeng Y J. Journal of Alloys and Compounds, 2018,741, 300.
17 Yu R J, Noh H M, Moon B K, et al. Journal of Alloys and Compounds, 2013, 576, 236.
18 Zhang Z W, Wang L J, Han L, et al. Materials Letters, 2015, 160, 302.
19 Sun W Z, Li H Y, Zheng B, et al. Journal of Alloys and Compounds, 2019,774, 477.
20 Zhu H K, Xia Z G, Liu H K, et al. Materials Research Bulletin, 2013, 48(9),3513.
21 Zhang X G, Zhu Z P, Guo Z Y, et al. Dyes and Pigments, 2018,156, 67.
22 Zeuner M, Hintze F, Schnick W. Chemistry of Materials, 2009,21(2), 336.
23 Piao X Q, Machida K, Horikawa T, et al. Journal of Rare Earths, 2008, 26(2), 198.

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