| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Study on the Microphase Separation Mechanism and Mechanical Property Degradation of Laminated Polyurethane Bearings Subjected to Water Aging |
| YU Xiaotao1, YUAN Yong1,*, WANG Siqi2
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1 School of Civil and Hydraulic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China 2 School of Civil Engineering and Architecture, Wuhan University of Engineering, Wuhan 430205, China |
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Abstract In order to investigate the effect of water aging on the performance of polyurethane seismic isolation bearings, this study systematically investigated the water-aging effects on polyurethane elastomers (PUE) and laminated polyurethane elastomeric bearings(LPEB) through simulative experiments. The results revealed that water molecules permeated the PUE matrix, triggering the collapse of amorphous hard-segment microdomains and inducing a plasticization effect. This microstructural degradation led to a 52% reduction in tensile strength and a 3.4% decline in hardness, while the elongation at break increased due to enhanced segmental mobility. The mechanical properties stabilized as the water concentration gradient between the material’s interior and exterior equilibrated. For LPEB, water infiltration significantly compromised stiffness, with vertical stiffness and horizontal equivalent stiffness dropping to 10.3% and 21.2% of their initial values, respectively. Similar stabilization trends were observed in LPEB mechanical performance once dynamic water equilibrium was achieved. These findings highlight the critical role of water-induced microphase separation in governing the long-term durability of polyurethane-based seismic isolation systems, and provide a quantitative reference for the durability design of bridge seismic isolation bearings in hot and humid regions.
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Published: 25 January 2026
Online: 2026-01-27
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