| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Preparation and Electrochemical Performance of Single-crystal High-nickel Cathode Materials LiNi0.83Co0.11Mn0.06O2 |
| HUANG Yuxuan1,2,3,4, WANG Ying2,3,4, TANG Renheng2,3,4, XIAO Fangming2,3,4, ZENG Liming2,3,4,*, HUANG Hui1,*
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1 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China 2 Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, China 3 Key Laboratory of Separation and Comprehensive Utilization of Rare Metals, Guangzhou 510650, China 4 Guangdong Provincial Key Laboratory of Rare Earth Development and Application, Guangzhou 510650, China |
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Abstract Single-crystal high-nickel ternary cathode materials have become one of the potential cathode materials due to their high capacity, excellent cycling performance and other advantages. In this work, single-crystal high-nickel LiNi0.83Co0.11Mn0.06O2 cathode materials were synthesized by high-temperature solid-phase method, and the effects of different holding times on the structure and electrochemical performance of the materials were investigated. The results showed that after pre-sintered at 500 ℃ for 4 h, the cathode material continuously sintered at 850 ℃ for 23 h, afforded a first discharge capacity of 203.4 mAh·g-1 at 0.2C, a first Coulomb efficiency of 83.9%, and a capacity retention rate of 89.5% after 100 cycles at 1C charging and discharging. This study offers a feasible strategy for the development of single-crystal high-nickel ternary cat-hode materials with high cycling stability.
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Published: 25 December 2025
Online: 2025-12-17
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