| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress of High-entropy Oxides in Electrode Materials for Sodium-ion Batteries |
| JIANG Yue1, XIAO Mingjun1,2,*
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1 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China 2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China |
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Abstract With the increasingly serious energy crisis and environmental pollution, it is urgent to develop new, more environmentally friendly and efficient new energy materials to alleviate the energy shortage and reduce the impact on the environment as much as possible. Among the many exploration directions of new energy materials, sodium-ion batteries (SIBs) have received extensive research from scholars due to the abundance and low price of sodium resources, showing great potential. At the same time, high-entropy oxides (HEOs) are widely used in energy storage and conversion due to the multi-metal oxide effect, and are most widely used in SIBs. However, there are few detailed reviews of HEO as an electrode material for SIBs. Most of the studies may only focus on a local aspect, lacking a comprehensive, systematic and in-depth review and summary. Based on this, this paper systematically reviews the basic definition and synthesis methods of HEO, and focuses on its application and performance changes in SIBs electrodes. This review provides a solution for the development of HEO in SIBs and provides guidance for promoting its industrialization in SIBs.
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Published: 25 December 2025
Online: 2025-12-17
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1 Wanison R, Syahputra W N H, Niti K L, et al. Journal of Energy Storage, 2024, 100, 113497. 2 Zhao Y, Kang Y, Wozny J, et al. Nature Reviews Materials, 2023, 8(9), 623. 3 Sawhney M, Wahid A, Muhkerjee S, et al. Chemphyschem, 2022, 23(5), e202100860. 4 Liu Y, Liu X, Wang T, et al. Sustainable Energy & Fuels, 2017, 1(5), 986. 5 Pei L, Kang J, He C, et al. Advanced Functional Materials, 2024, 15, 2422809. 6 Zhou S, Sun Y, Gao T, et al. Angewandte Chemie International Edition, 2023, 62(42), e202311930. 7 Lun Z, Ouyang B K, Won D H, et al. Nature Materials, 2020, 20(2), 214. 8 Chen T Y, Wang S Y, Kuo C H, et al. Journal of Materials Chemistry A, 2020, 41, 21756. 9 Bin X, Gang W, Tongde W, et al. Nano Energy, 2022, 95, 106962. 10 Fang S, Bresser D, Passerini S, et al. Advanced Energy Materials, 2020, 10, 1902485. 11 Liu X, Li X, Li Y, et al. EcoMat, 2022, 4(6), e12261. 12 Lin Y, Luo S, Zhao W, et al. Journal of Energy Chemistry, 2024, 98(12), 31. 13 Wang P Y, Chen D G, Zhu D G. Materials Reports, 2024, 38(22), 23040299(in Chinese). 王培远, 邓根成, 朱登贵. 材料导报, 2024, 38(22), 23040299. 14 Zhang Y. Diamond & Abrasives Engineering, 2022, 42(1), 30 (in Chinese). 张扬. 金刚石与磨料磨具工程, 2022, 42(1), 30. 15 Wang R, Kang Q L, Xu H Y. Journal of Inorganic Chemistry, 2023, 39(12), 2241 (in Chinese). 王睿, 康巧玲, 徐昊宇. 无机化学学报, 2023, 39(12), 2241. 16 Ran B, Li H, Cheng R, et al. Advanced Science, 2024, 11(25), e2401034. 17 Chang L, Shun L, Yunpeng Z, et al. Progress in Materials Science, 2024, 148, 48101385. 18 Yogesh Sharma Q Z, Alessandro R, Elizabeth S, et al. Physical Review Materials, 2020, 10, 1103. 19 Mao A, Xiang H Z, Zhang Z G, et al. Journal of Magnetism and Magnetic Materials, 2020, 497, 165884. 20 Wang Q, Sarkar A, Wang D, et al. Energy & Environmental Science, 2019, 12(8), 2433. 21 Chen H, Fu J, Zhang P F, et al. Journal of Materials Chemistry A, 2018, 10, 1039. 22 Braun J L, Rost C M, Lim M, et al. Advanced Materials, 2018, 30(51), 1805004. 23 Zhang X, Wang X, Lv X, et al. ChemSusChem, 2024, 18, e202401663. 24 Bonnet E, Grenier J C, Bassat J M, et al. Journal of the European Ceramic Society, 2021, 41(8), 4505. 25 Wang Y, Liu Y. Science China Materials, DOI:10. 1007/s40843-024-3117-8. 26 Yue J L, Xiong F, Shadik Z, et al. Journal of Power Sources, 2024, 627, 235735. 27 Wu C, Xu Y, Song J, et al. Chemical Engineering Journal, 2024, 500, 157264. 28 Li X, Zhang W, Lv K, et al. Journal of Power Sources, 2024, 620, 235259. 29 Garcia N G, Gonçalves J M, Real C, et al. Energy Storage Materials, 2024, 67, 103213. 30 Guo H, Avdeev M, Sun K, et al. Chemical Engineering Journal, 2021, 412, 128704. 31 Cai Q, Liu X, Hu H, et al. Asia-Pacific Journal of Chemical Engineering, 2024, 19(5), 001. 32 Kim H. ACS Materials Au, 2023, 3(6), 571. 33 Chen B, Zhang W-B, Yin Y, et al. Journal of Energy Storage, 2025, 109, 115228. 34 Li H J, Duan Y R, Zhao Z X, et al. Chemical Engineering Journal, 2023, 469, 143951. 35 Wen Y, Lin C, Shen H, et al. Chemical Engineering Journal, 2025, 506, 160126. 36 Bierbaum M, Leahy B D, Alemi A A, et al. Physical Review X, 2017, 74, 041007. 37 Lambe W A, Brady P M. Microscopy and Microanalysis, 2020, 4S2, 896. 38 Dwyer C. Physical Review Letters, 2023, 1305, 056101. 39 Salmeron M, Eren B. Chemical Reviews, 2020, 1212, 1. 40 Ando T. Current Opinion in Chemical Biology, 2019, 51, 105. 41 Stevie F A, Donley C L. Journal of Vacuum Science & Technology A, 2020, 386, 063204. 42 Shul’pina I L, Suvorov E V, Smirnova I A, et al. Technical Physics, 2024, 68, 778. 43 Tomboc G M, Zhang X, Choi S, et al. Advanced Functional Materials, 2022, 32(43), 2205142. 44 Ophus C. Microscopy And Microanalysis, 2019, 25(3), 563. 45 Xu M, Kumar A, LeBeau J M. Microscopy and Microanalysis, 2022, 28(6), 1952. 46 Chellali M R, Sarkar A, Nandam S H, et al. Scripta Materialia, 2019, 166, 58. 47 Fracchia M, Manzoli M, Anselmi-Tamburini U, et al. Scripta Materialia, 2020, 188, 26. 48 Mazza A R, Gao X, Rossi D J, et al. Journal of Vacuum Science & Technology A, 2022, 40, 013404. 49 Wang H J, Gao J Q, Mei Y, et al. Angewandte Chemie International Edition, 2024, 64, e202418605. 50 Liu C Z, Liu M Z, Cheng Z X, et al. Ceramics International, 2024, 50(13), 24397. 51 González-Rivas M U, Aamlid S S, Rutherford M R, et al. arXiv-PHYS-Materials Science, 2024, 146(38), 25889. 52 Xiang H. The Chinese Journal of Process Engineering, 2020, 20(3), 245(in Chinese). 项厚政. 过程工程学报, 2020, 20(3), 245. 53 Wang D, Liu Z, Du S, et al. Journal of Materials Chemistry A, 2019, 7(42), 24211. 54 Wang D, Duan C, He H, et al. Journal of Colloid and Interface Science, 2023, 646, 89. 55 Esposito S. Materials, 2019, 12(4), 668. 56 Santos J R D, Raimundo R A, Oliveira J F G d A, et al. Journal of Electroanalytical Chemistry, 2024, 961, 118191. 57 Asim M, Hussain A, Khan S, et al. Molecules, 2022, 27(18), 5951. 58 He M, Liu S, Wu J, et al. Progress in Solid State Chemistry, 2024, 74, 100452. 59 Gao H, Li J, Zhang F, et al. Advanced Energy Materials, 2024, 14(20), e2304529. 60 Tong Z, Yuesen L, Zihao S, et al. Journal of Energy Chemistry, 2024, 103, 294. 61 Jayamkondan Y, Penki T R, Nayak P K. Materials Today Energy, 2023, 36, 101360. 62 Ding F, Wang H, Zhang Q, et al. Journal of the American Chemical Society, 2023, 145(25), 13592. 63 Huang Z, Wang S, Guo X, et al. Advanced Materials, 2024, 36(50), 2410857. 64 Pang Y, Wang Y, Jiang C, et al. ChemSusChem, 2024, 17, e202400768. 65 Yao L, Zou P, Wang C, et al. Advanced Energy Materials, 2022, 12(41), 2201989. 66 Peng B, Chen Y, Zhao L, et al. Energy Storage Materials, 2023, 56, 631. 67 Chen H, Qiu N, Wu B, et al. RSC Advances, 2020, 10(16), 9736. 68 Chen T Y, Wang S Y, Kuo C H, et al. Journal of Materials Chemistry A, 2020, 41, 21343. 69 Xiang H Z, Xie H X, Chen Y X, et al. Journal of Materials Science, 2021, 56(13), 8127. 70 Nguyen T X, Patra J, Chang J-K, et al. Journal of Materials Chemistry A, 2020, 8(36), 18963. 71 Luo X F, Patra J, Chuang W T, et al. Advanced Science, 2022, 9(21), e2201219. 72 Qiu N, Chen H, Yang Z, et al. Journal of Alloys and Compounds, 2019, 777, 767. 73 Wang S Y, Chen T Y, Kuo C H, et al. Materials Chemistry and Physics, 2021, 274, 125105. 74 Su J, Cao Z, Jiang Z, et al. International Journal of Applied Ceramic Technology, 2022, 19(4), 2004. 75 Yen J Z, Yang Y C, Tuan H Y. Chemical Engineering Journal, 2022, 450, 137924. 76 Song Z, Liu R, Liu W D, et al. Advanced Energy and Sustainability Research, 2023, 4(11), 2300102. 77 Ni Q, Bai Y, Wu F, et al. Advanced Science, 2017, 4(3), 1600275. 78 Jin T, Li H, Zhu K, et al. Chemical Society Reviews, 2020, 49(8), 2342. 79 Liu J, Wang Q, Chen L, et al. Electrochimica Acta, 2022, 426, 140579. 80 Rajagopalan R, Chen B, Zhang Z, et al. Advanced Materials, 2017, 29(12), 1605694. 81 Li H X, Xu M, Long H W, et al. Advanced Science, 2022, 9(25), e2202082. 82 Chen Y, Liao X, Xie M, et al. ACS Sustainable Chemistry & Engineering, 2024, 12(36), 13401. 83 Peng Z Q, Ma E. Environmental Chemistry, 2024, 44(8), 1 (in Chinese). 彭志强, 马恩. 环境化学, 2024, 44(8), 1. 84 Zhang Y M, Wang Y F. Energy Engineering, 2024, 44(4), 1 (in Chinese). 张艳梅, 王一菲. 能源工程, 2024, 44(4), 1. 85 Chen J, Wei L, Mahmood A, et al. Energy Storage Materials, 2020, 25, 585. 86 Wang W, Gang Y, Hu Z, et al. Nature Communications, 2020, 11(1), 980. 87 Wang Y, Liu J, Jiang N, et al. Small, 2024, 20(44), e2403211. 88 Liu X Y, Gong H G, Han C Y, et al. Energy Storage Materials, 2023, 57, 118. 89 Wu J, Wang G, Li K, et al. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2024, 702, 135099. 90 Jiang W, Wang T, Chen H, et al. Nano Energy, 2021, 79, 105464. 91 Lei Y, Wang S, Zhao L, et al. Advanced Science, 2024, 11(28), 2402340. 92 Slater M D, Kim D, Lee E, et al. Advanced Functional Materials, 2012, 23(8), 947. 93 He Z, Huang Y, Liu H, et al. Nano Energy, 2024, 129, 109996. 94 Perveen T, Siddiq M, Shahzad N, et al. Renewable and Sustainable Energy Reviews, 2020, 119, 109549. 95 Xu M, Chen X, Saju S K, et al. Journal of Materials Science, 2024, 60(3), 1116. 96 Dahn D A S J R. Journal of the Electrochemical Society, 2000, 147, 1271. 97 Dong L, Tian Y, Luo C, et al. Materials, 2024, 17(7), 1542. 98 Yang X b, Wang H Q, Song Y Y, et al. ACS Applied Materials & Interfaces, 2022, 14, 26873. 99 Yu Z, Xin W, Lan X X, et al. Processes, 2021, 10(1), 49. 100 Zou X, Zhang Y R, Huang Z P, et al. Chemical Communications, 2023, 59(91), 13535. 101 Xiao B, Liu X, Xie Z, et al. Chemical Engineering Journal, 2025, 503, 158269. 102 Ze H, Xiao H L, Q T. Journal of Taiyuan University of Technology 2024, 55(3), 445. 103 Fang S, Bresser D, Passerini S. Advanced Energy Materials, 2019, 10, 1902485. |
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