PEDOT基对电极染料敏化太阳能电池研究进展*

doi:10.11896/j.issn.1005-023X.2017.07.003

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Abstract Dye-sensitized solar cells (DSSC) is an attracting issue of the new solar cell field. Its low-light electricity generating capacity has been further explored and developed. The application of transparent and flexible DSSC on wearable devices has also attracted more and more attention. The performance of the DSSC highly depends on the conduct electrode (CE), therefore the selection of the material for CE arises as a key issue. Poly(3,4-ethylenedioxythiophene) (PEDOT), a high molecular conductive polymer, has shown its potential as CE material in recent years because of its high conductivity, catalytic ability of the electrolyte, transparency and flexibility. In this paper, we focus on PEDOT and doped PEDOT using for CEs of the DSSCs. The preparation methods of PEDOT and doped PEDOT have been discussed and the progresses of the researches on the application of these materials as CEs of DSSCs have been reviewed. We propose that in situ polymerization is the promising method for preparing PEDOT film CE, whereas physical coating is the potential route for large-scale fabrication. This review provides references for the development of the CEs of DSSCs.

Key words： dye-sensitized solar cells conduct electrode PEDOT(poly(3 4-ethylenedioxythiophene))

Published: 10 April 2017 Online: 2018-05-08

CLC number:

TB30

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	Articles by authors
	LI Yuyu
	SHEN Hujiang
	LIU Yan
	WANG Wei
	YUAN Huihui
	XIE Huaqing

Cite this article:

LI Yuyu,SHEN Hujiang,LIU Yan, et al. Progress in PEDOT-based Conduct Electrode for Dye-sensitized Solar Cells[J]. Materials Reports, 2017, 31(7): 19-25.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.07.003 OR https://www.mater-rep.com/EN/Y2017/V31/I7/19

1 Solar photovoltaic roadmap[R].International Energy Agency,2010.
2 Shawn A Sapp, Michael Elliott C, Cristiano Contado, et al. Substituted polypyridine complexes of cobalt(Ⅱ/Ⅲ) as efficient electron-transfer mediators in dye-sensitized solar cells[J]. Am Chem Soc,2002,124(37):8.
3 Michael Gr?tzel. Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells[J]. J Photochem Photobiol A: Chem,2004,164(3):14.
4 Brian O’Regan, Michael Gr?tzel. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J]. Nature,1991,353:737.
5 Simon Mathew, Aswani Yella, Peng Gao, et al. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers [J]. Nat Chem,2014,6(3):242
6 马廷丽,云斯宁. 染料敏化太阳能电池——从理论基础到技术应用 [M]. 北京:化学工业出版社,2013:1.
7 Min-Hsin Yeh, Chia-Liang Sun, Jheng-Sin Su, et al. A low-cost counter electrode of ITO glass coated with a graphene/Nafion??composite film for use in dye-sensitized solar cells[J]. Carbon,2012,50(11):4192.
8 Xue Y H, Liu J, Chen H, et al. Nitrogen-doped graphene foams as metal-free counter electrodes in high-performance dye-sensitized solar cells[J]. Angew Chem Int Ed,2012,51(48):4.
9 Zhang B, Wang K, Cui X D. Research development of conducting polymers as organic thermoelectric materials[J]. Chem Bull,2015,78(10):6(in Chinese).
张标,汪衎,崔旭东. 导电聚合物热电材料研究进展[J]. 化学通报,2015,78(10):6.
10 Groenendaal L, Jonas F, Freitag D, et al. Poly(3,4-ethylenedioxythiophene) and its derivatives: Past, present, and future[J]. Adv Mater,2000,7(12):14..
11 Olle Inganas, Catarina Carlberg, Teketel Yohannes. Polymer electrolytes in optical devices[J]. Electrochim Acta,1998,43:7.
12 Zhang M J, Li J X, Liu A H. Progress on fabrication of poly(3,4-ethylenedioxythiophene) film[J]. New Chem Mater,2013,41(4):3(in Chinese).
张美娟,李健雄,刘安华. 聚3,4-乙撑二氧噻吩薄膜制备的研究进展 [J]. 化工新型材料,2013, 41(4):3.
13 Saito Y K T, Wada Y, Yanagida S. Application of poly(3,4-ethylendioxythiophene) as counter electrode in dye-sensitized solar cells[J]. Chem Lett,2002,3:1060.
14 Okada I, Shiratori S. Rare-metal-free flexible counter electrodes for dye-sensitized solar-cells produced using wet processes only[J]. ACS Appl Mater Interfaces,2013,5(10):4144.
15 Wang J, Cai K, Shen S. A facile chemical reduction approach for effectively tuning thermoelectric properties of PEDOT films[J]. Org Electron,2015,17:151.
16 Chang L Y, Li Y Y, Li C T, et al. A composite catalytic film of Ni-NPs/PEDOT∶PSS for the counter electrodes in dye-sensitized solar cells[J]. Electrochim Acta,2014,146:697.
17 Maiaugree W, Towannang M, et al. Composited NiSO4 and PEDOT∶PSS counter electrode for efficient dye-sensitized solar cell based on organic T2/T- electrolyte[J]. Mater Lett,2013,111:197.
18 Anothumakkool B, Game O, Bhange S N, et al. Enhanced catalytic activity of polyethylenedioxythiophene towards tri-iodide reduction in DSSCs via 1-dimensional alignment using hollow carbon nanofibers[J]. Nanoscale,2014,6(17):10332.
19 Tsai Y L, Li C T, Huang T Y, et al. Electrocatalytic SiC nanoparticles/PEDOT∶PSS composite thin films as the counter electrodes of dye-sensitized solar cells[J]. ChemElectroChem,2014,1(6):1031.
20 Lee C P, Lin C A, Wei T C, et al. Economical low-light photovol-taics by using the Pt-free dye-sensitized solar cell with graphene dot/PEDOT∶PSS counter electrodes[J]. Nano Energy,2015,18:109.
21 Kwon J, Park N G, et al. Highly efficient monolithic dye-sensitized solar cells[J]. ACS Appl Mater Interfaces,2013,5(6):2070.
22 Xu S, Luo Y, Liu G, et al. Bifacial dye-sensitized solar cells using highly transparent PEDOT∶PSS films as counter electrodes[J]. Electrochim Acta,2015,156:20.
23 Susmitha K, Naresh Kumar M, Rajkumar G, et al. Enhanced dye sensitized solar cell performance with high surface area thin ZnO film and PEDOT∶PSS[J]. Solar Energy,2015,118: 126.
24 Zheng M, Huo J, et al. Pt-Co and Pt-Ni hollow nanos-pheres supported with PEDOT∶PSS used as high performance counter electrodes in dye-sensitized solar cells[J]. Solar Energy,2015,122:727.
25 Yue G, Wu J, Xiao Y, et al. Application of poly(3,4-ethylenedioxythiophene):Polystyrenesulfonate/polypyrrole counter electrode for dye-sensitized solar cells[J]. J Phys Chem C,2012,116(34):18057.
26 Yue G T, Zhang D, Tan F, et al. Enhanced performance of dye-sensitized solar cells based on an electrodeposited-poly(3,4-ethylene-dioxythiophene)/platinum composite counter electrode[J]. Synth Met,2014,197:204.
27 Han R, Lu S, Wang Y, et al. Influence of monomer concentration during polymerization on performance and catalytic mechanism of resultant poly(3,4-ethylenedioxythiophene) counter electrodes for dye-sensitized solar cells[J]. Electrochimica Acta,2015,173:796.
28 Gao M, Xu Y, et al. Effect of electropolymerization time on the performance of poly(3,4-ethylenedioxythiophene) counter electrode for dye-sensitized solar cells[J]. Appl Surf Sci, 2014,289(1):145.
29 Lin Y F, Li C T, Ho K C. A template-free synthesis of the hierarchical hydroxymethyl PEDOT tube-coral array and its application in dye-sensitized solar cells[J]. J Mater Chem A,2016, 4(2):384.
30 Li C T, Lee C P, Fan M S, et al. Ionic liquid-doped poly(3,4-ethy-lenedioxythiophene) counter electrodes for dye-sensitized solar cells: Cationic and anionic effects on the photovoltaic performance[J]. Nano Energy,2014,9:1.
31 Koussi-Daoud S, Schaming D, Martin P, et al. Gold nanoparticles and poly(3,4-ethy-lenedioxythiophene) (PEDOT) hybrid films as counter-electrodes for enhanced efficiency in dye-sensitized solar cells[J]. Electrochim Acta,2014,125:601.
32 Chen P Y, Li C T, Lee C P, et al. PEDOT-decorated nitrogen-doped graphene as the transparent composite film for the counter electrode of a dye-sensitized solar cell [J]. Nano Energy, 2015,12:374.
33 Tao X Y, Chen X, Xiong Z, et al. Research progress of plymerization dposition in-situ tansparent and cnducting plyaniline films[J]. Chem Propellants Polym Mater,2005,3(9):4(in Chinese).
陶雪钰,陈骁,熊忠,等. 原位聚合沉积透明导电聚苯胺薄膜的研究进展 [J]. 化学推进剂与高分子材料,2005,3(9):4.
34 Yoo D, Kim J, Kim J H. Direct synthesis of highly conductive poly(3,4-ethylenedioxythiophene)∶poly(4-styrenesulfonate) (PEDOT∶PSS)/graphene composites and their applications in energy harvesting systems [J]. Nano Res,2014,7(5):717.
35 Kim D H, Atanasov S E, Lemaire P, et al. Platinum-free cathode for dye-sensitized solar cells using poly(3,4-ethylenedioxythiophene) (PEDOT) formed via oxidative molecular layer deposition [J]. ACS Appl Mater Interfaces,2015,7(7):3866.
36 Anothumakkool B, Agrawal I, Bhange S N, et al. Pt- and TCO-free flexible cathode for DSSC from highly conducting and flexible PEDOT paper prepared via in situ interfacial polymerization[J]. ACS Appl Mater Interfaces,2016,8(1):553.
37 Xia X, Wu W, Ma J, et al. Antimony tin oxide porous layers improve the poly(3,4-ethylenedioxythiophene) counter electrode fabricated by vapor deposition for dye-sensitized solar cells [J]. RSC Adv,2015,5(21):15772.
38 Zheng M, Huo J, Tu Y, et al. An in situ polymerized PEDOT/Fe3O4 composite as a Pt-free counter electrode for highly efficient dye sensitized solar cells[J]. RSC Adv,2016,6(2):1637.