| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Advances in Reticular Materials for Flame Retardant Polymers |
| PAN Yetang1,2,*, LI Tianyu1, XU Yunlei1, MIAO Weijia1
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1 School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China 2 National Engineering Research Center of Flame Retardant Materials, Beijing 100095, China |
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Abstract The emergence of reticular materials has introduced innovative approaches in the development of new composite materials, particularly in enhancing fire-retardant properties. Recent studies have focused on the flame retardancy effects and mechanisms of reticular materials in va-rious polymer matrices. Leveraging the characteristics of these materials—including their high specific surface area, large porosity, ease of che-mical functionalization, and excellent design flexibility in nanostructures, researchers have adjusted the properties of metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) for incorporation into diverse polymers, resulting in the design of composites with improved flame retardancy. The design of reticular composites represents a promising solution for enhancing the combustion performance of polymeric materials. Despite its importance, a comprehensive review on the progress of reticular materials in the field of flame retardancy is still lacking. Therefore, this paper provides a thorough review of the latest advancements in MOFs, COFs, and HOFs concerning flame-retardant polymer materials. It specifically examines modification strategies and flame-retardant effects for epoxy resins, polyurethanes, and other polymers. Finally, we offer a brief commentary on future research opportunities and challenges related to polymer composite flame retardants based on reticular materials.
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Published: 10 November 2025
Online: 2025-11-10
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