熔盐电解法制备钇铝中间合金研究进展

doi:10.11896/cldb.24070152

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Abstract With the increasing demand for high temperature resistant, oxidation resistant, and corrosion resistant alloys in aeronautics, automobile, architecture, and other industries, yttrium aluminum intermediate alloys have received extensive attention due to their unique properties. The molten salt electrolysis method, as an efficient metal alloy preparation method, has many advantages of low reaction temperature, short preparation time and uniform alloy composition, which shows significant advantages in the preparation of yttrium aluminum intermediate alloy. In this review, many preparation methods of yttrium aluminum intermediate alloy are summarized, and then the characteristics of the mix melting, metallothermic reduction and molten salt electrolysis methods are compared. The research progress of yttrium aluminum intermediate alloy prepared by molten salt electrolysis method is emphatically introduced, including the advantages and disadvantages of the electrolysis process of chloride and fluoride molten system. Finally the prospects of the related research works of yttrium aluminum intermediate alloys are proposed.

Key words： yttrium aluminum intermediate alloy molten salt electrolysis method chloride molten system fluoride molten system electrochemistry

Published: Online: 2025-08-28

CLC number:

TF845.2

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	Articles by authors
	LI Liangxing
	XUE Lirong
	CHENG Yi
	WU Jiahang
	WANG Jinsong
	HUANG Xilin

Cite this article:

LI Liangxing,XUE Lirong,CHENG Yi, et al. A Review on Preparation of Yttrium Aluminum Intermediate Alloys by Molten Salt Electrolysis[J]. Materials Reports, 2025, 39(17): 24070152-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24070152 OR https://www.mater-rep.com/EN/Y2025/V39/I17/24070152

1 Medvedev A E, Murashkin M Y, Enikeev N A, et al. Journal of Alloys and Compounds, 2018, 745, 696.
2 Li J G, Wang N, Liu J D, et al. Journal of Materials Science & Technology, 2024, 195, 9.
3 Yu C, Chen L P, Zhou Q. Special Casting & Nonferrous Alloys, 2021, 41(2), 241(in Chinese).
余聪, 陈乐平, 周全. 特种铸造及有色合金, 2021, 41(2), 241.
4 Lv Q T, Zhang F, Wei H, et al. Vacuum, 2023, 215, 1.
5 Zhong J H, Zhu H B, Feng K, et al. Special Casting and Nonferrous Alloys, 2010, 30(10), 899(in Chinese).
钟建华, 朱洪斌, 冯凯, 等. 特种铸造及有色合金, 2010, 30(10), 899.
6 Xiao S J, Geng Y, Rui X, et al. Resources Policy, 2022, 76, 1.
7 Lin G J, Li L, Guo Z W, et al. Journal of Rare Earths, 2024, 42(3), 600.
8 Chen Y F, Zhu Z Q, Zhou J X. Materials Science and Engineering A, 2022, 850, 1.
9 Mei Z Q, Liu Z Y, Bai S, et al. Journal of Alloys and Compounds, 2021, 870, 1.
10 Wei Z F, Lei Y S, Yan H, et al. Journal of Rare Earths, 2019, 37(6), 659.
11 Guo T, Wang S D, Ye X S, et al. Scientia Sinica (Chimica), 2012, 42(9), 1328(in Chinese).
郭探, 王世栋, 叶秀深, 等. 中国科学(化学), 2012, 42(9), 1328.
12 Luo L S, Chen J L, Yan Q C. Chinese Rare Earths, 2023, 44(4), 1(in Chinese).
罗林生, 陈建利, 闫奇操. 稀土, 2023, 44(4), 1.
13 Wang Z J, Si N C. Rare Metal Materials and Engineering, 2015, 44(12), 2970.
14 Liang Y, Zou Y, Liu Y C, et al. Nonferrous Metals Engineering, 2018, 8(1), 53(in Chinese).
梁勇, 邹瑜, 刘玉城, 等. 有色金属工程, 2018, 8(1), 53.
15 Cao D L, Wang J K, Shi Z Y, et al. Journal of the Chinese Society of Rare Earth, 2008, 26(1), 82(in Chinese).
曹大力, 王吉坤, 石忠宇, 等. 中国稀土学报, 2008, 26(1), 82.
16 Liu Y C, Liang Y, Liu D B, et al. Journal of the Chinese Society of Rare Earth, 2021, 39(5), 759(in Chinese).
刘玉城, 梁勇, 刘道斌, 等. 中国稀土学报, 2021, 39(5), 759.
17 Wang M. Rare Metals and Cemented Carbides, 2023, 51(4), 13(in Chinese).
王明. 稀有金属与硬质合金, 2023, 51(4), 13.
18 Chen Y F, Zhu Z Q, Xu Y Y, et al. Journal of the Chinese Society of Rare Earth, 2024, 42(2), 304(in Chinese).
陈燕飞, 朱政强, 徐玉友, 等. 中国稀土学报, 2024, 42(2), 304.
19 Prof H, Bunsen R. Annalen der Physik, 1875, 231(8), 633.
20 Li M, Liao C Y, Ding A T, et al. Journal of Environmental Chemical Engineering, 2023, 11(3), 1.
21 Han W, Li M, Zhang M L, et al. Rare Metals, 2016, 35(11), 811.
22 Sinclair N S, Wasalathanthri R, Mainali B, et al. ECS Meeting Abstracts, 2022, 25, 2500.
23 Liu Y B, Chen G H, Yu B, et al. Chinese Rare Earths, 2021, 42(5), 133(in Chinese).
刘玉宝, 陈国华, 于兵, 等. 稀土, 2021, 42(5), 133.
24 Xu C, Hu X W, Yu J Y, et al. Rare Metals, 2023, 42(11), 3886.
25 Zhao M S, Zhao Q J, Tang D X. Journal of the Chinese Society of Rare Earth, 1983, 2, 41(in Chinese).
赵敏寿, 赵奇金, 唐定骧. 中国稀土学报, 1983, 2, 41.
26 He J W, Hua Z S, Liu H, et al. Journal of the Electrochemical Society, 2018, 165(11), 598.
27 Wang Y L, Sun R F, Yang L X, et al. Journal of the Electrochemical Society, 2023, 170(10), 16506.
28 Castrillejo Y, Bermejo M R, Martínez A M, et al. Journal of Mining and Metallurgy Section B:Metallurgy, 2010, 1-2(1-2), 109.
29 Yan Y D, Yang X N, Huang Y, et al. Rare Metal Materials and Engineering, 2016, 45(2), 272.
30 Han W, Li W L, Chen J Z, et al. RSC Advances, 2019, 9(46), 26718.
31 Han W, Li W L, Li M, et al. Journal of Solid State Electrochemistry, 2018, 22(8), 2435.
32 Wang Y C, Liu Q, Zhang S, et al. Separation and Purification Technology, 2022, 294, 1.
33 Chen Y X. Chinese Rare Earths, 2014, 35(2), 99(in Chinese).
陈宇昕. 稀土, 2014, 35(2), 99.
34 Pang S M, Yan S H, Li Z A, et al. Chinese Journal of Rare Metals, 2011, 35(3), 440(in Chinese).
庞思明, 颜世宏, 李宗安, 等. 稀有金属, 2011, 35(3), 440.
35 Liao C F, Que L H, Fu Z H, et al. Metals, 2024, 14(4), 1.
36 Vogel H, Flerus B, Stoffer F, et al. Journal of Sustainable Metallurgy, 2016, 3(1), 99.
37 Yu B, Yan Q C. Journal of Rare Earths, 2023, 41(4), 632.
38 Yang S H, Yang F L, Liao C F, et al. Journal of Rare Earths, 2010, 28(1), 385.
39 Lei J B. Research on the preparation of alloy of bismuth, antimony and iron by molten salt electrolysis. Master's Thesis, Jiangxi University of Science and Technology, China, 2010 (in Chinese).
雷杰兵. 熔盐电解制取钆、钇与铁的合金的试验研究. 硕士学位论文, 江西理工大学, 2010.
40 Yu G Q, Zhou L, Liu F Q, et al. Journal of Rare Earths, 2022, 40(12), 1945.
41 Wang X, Liao C F, Jiao Y F, et al. Journal of Rare Earths, 2018, 36(3), 324.
42 Dos Santos I A, Klimm D, Baldochi S L, et al. Journal of Crystal Growth, 2012, 360, 172.
43 Liu J J, Zeng X L. Journal of Shanghai Second Polytechnic University, 1996, 13(1), 71(in Chinese).
刘剑军, 曾兴兰. 上海第二工业大学学报, 1996, 13(1), 71.
44 Zhu X P, Sun S C, Lu S D, et al. Thermochimica Acta, 2016, 636, 42.
45 Zhu X P. The study on physicochemical properties of REF₃-LiF-RE₂O₃ molten salts. Ph. D. Thesis, Northeastern University, China, 2018 (in Chinese).
朱小平. REF₃-LiF-RE₂O₃熔盐电解质体系物理化学性质的研究. 博士学位论文, 东北大学, 2018.
46 Reddy R G, Kumar S G. Materials Transactions B(Process Metallurgy), 1994, 25(1), 91.
47 Yu B, Kang J, Huang H T, et al. Nonferrous Metals Engineering, 2021, 11(3), 63 (in Chinese).
于兵, 康佳, 黄海涛, 等. 有色金属工程, 2021, 11(3), 63.
48 Kang J, Yu B, Huang H T, et al. Nonferrous Metals (Extractive Metallurgy), 2020(11), 89(in Chinese).
康佳, 于兵, 黄海涛, 等. 有色金属(冶炼部分), 2020(11), 89.
49 Wang Y J. Rare Metals and Cemented Carbides, 1992(3), 25(in Chinese).
王毅军. 稀有金属与硬质合金, 1992(3), 25.
50 Shi Q R, Zhao L Z, Duan S Z. Rare Metals, 1998, 17(4), 251.
51 Huang H T, Yu B, Yan Q C, et al. Rare Metals and Cemented Carbides, 2021, 49(3), 5(in Chinese).
黄海涛, 于兵, 闫奇操, 等. 稀有金属与硬质合金, 2021, 49(3), 5.
52 Wang H Z, Zhan Y Z, Pang M J. Computational Materials Science, 2012, 58, 17.
53 Li N, Zhang Q Q, Niu L Y, et al. Materials Science and Engineering A, 2014, 617, 139.
54 Özer T. Canadian Journal of Physics, 2020, 98(4), 1.
55 Jiang S Y, Li S C. Materials Science and Technology, 2014, 22(4), 124(in Chinese).
蒋淑英, 李世春. 材料科学与工艺, 2014, 22(4), 124.
56 Chen G Z, Fray D J, Farthing T W. Nature, 2000, 407(6802), 361.
57 Schwandt C, Doughty G R, Fary D J. Key Engineering Materials, 2010, 436, 13.
58 John F D. JOM, 2001, 53(10), 27.
59 Bertolini M, Shaw L, England L, et al. Key Engineering Materials, 2010, 436, 75.
60 Zhang C Z, Li G D, Yun Y H. Rare Metal materials and Engineering, 2006, 35(5), 736(in Chinese).
张常在, 李国栋, 云月厚. 稀有金属材料与工程, 2006, 35(5), 736.
61 Wei Y S. Study on preparation of yttrium aluminum alloy by FFC method. Master's Thesis, General Research Institute for Nonferrous Metals, China, 2016(in Chinese).
魏岳山. FFC法制备钇铝合金的研究. 硕士学位论文, 北京有色金属研究总院, 2016.
62 Wei Y S, Yan S H, Zhou L, et al. Rare Metals, 2017, 42(3), 1067.
63 Dan L Y, Liu N, Li Z Q, et al. Rare Metal Materials and Engineering, 2021, 50(7), 2409(in Chinese).
但林阳, 刘楠, 李泽全, 等. 稀有金属材料与工程, 2021, 50(7), 2409.