聚合物材料正热膨胀调控研究进展

doi:10.11896/cldb.23120194

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Abstract Thermal expansion is the phenomenon where the geometric dimensions of a material increase as the temperature rises, and decrease as the temperature decreases. At present, the research focus at home and abroad is mostly on zero expansion and negative expansion materials, while research on positive expansion materials appears to be relatively scarce. Among metal materials, ceramic materials, polymer materials, and composite materials, polymer materials have the highest thermal expansion capacity. Among commonly used polymers, nylon 66 (PA-66) has the highest linear expansion coefficient, which is 162.3×10^-6 K^-1 at 25—85 ℃. In the fields of flexible sensors and soft robots, materials are required to have higher thermal expansion capabilities and even control their thermal expansion capabilities. The use of multiple materials with mismatched thermal expansion capabilities can cause defects such as surface cracks or interface peeling, thereby limiting the application of materials. In recent years, research methods for improving the thermal expansion capacity of polymer materials can be roughly divided into three types: matrix optimization, molecular design, and structural design. This article reviews the research progress of positively expanding polymer materials in recent years, with a focus on two methods: molecular design and structural design, and it is pointed out that both methods significantly improve the linear expansion coefficient of the material. This provides literature support for the later research on high thermal expansion polymer materials with linear relationship between size change and temperature change.

Key words： polymer thermal expansion molecular design structural design positive thermal expansion regulation

Published: 10 April 2025 Online: 2025-04-10

CLC number:

TQ317.9

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	Articles by authors
	WU Yan
	QIAO Yingjie
	BAI Chengying
	WANG Xiaodong
	ZHANG Xiaohong

Cite this article:

WU Yan,QIAO Yingjie,BAI Chengying, et al. Progress on Positive Thermal Expansion Control of Polymer Materials[J]. Materials Reports, 2025, 39(7): 23120194-11.

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https://www.mater-rep.com/EN/10.11896/cldb.23120194 OR https://www.mater-rep.com/EN/Y2025/V39/I7/23120194

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