咪唑离子液体基中低温相变材料热物性及储热应用

doi:10.11896/cldb.23090077

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Abstract Ionic liquids (ILs) have the advantages of adjustable phase transition temperature, low non-flammability/volatility, good thermal and chemical stability in terms of thermal physical properties, and are increasingly receiving attention in the field of thermal energy storage. Recently, NASA utilized eutectic phase change materials (PCM) composed of functional ionic liquids to manage the extreme space environment (solar ra-diation and extreme cold/hot) of manned spacecraft for future deep exploration. Although the concept of storing latent heat during the phase transition of ionic liquids is well-known, it has not yet been adopted in large-scale applications, and its potential still needs to be further explored. At present, most research focuses on the performance of ionic liquids as heat transfer fluids, with little research and application on their phase change energy storage. The purpose of this article is to provide necessary information for selecting well-researched ionic liquids and promote further research in this field. The article first discusses the defects of traditional phase change materials, and then reviews and summarizes commonly used ionic liquids from the aspects of chemical structure, phase change mechanism, and thermophysical properties. Finally, the application of ionic liquid-based phase change materials was introduced in detail. This paper proposed the structural design optimization of ionic liquids (ILs), undercooling control strategies, enthalpy enhancement pathways, and preparation cost control as research entry points, providing direction for subsequent research.

Key words： phase change material imidazole ionic liquid thermophysical property phase change energy storage phase change behavior

Published: 10 April 2025 Online: 2025-04-10

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TK02

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	WANG Shaohui
	LI Qi
	ZHOU Meimei
	YANG Chunyun
	XIE Huicheng
	WU Yuting
	LU Yuanwei

Cite this article:

WANG Shaohui,LI Qi,ZHOU Meimei, et al. Thermophysical Properties and Thermal Storage Applications of Imidazole Ionic Liquid Based Medium and Low Temperature Phase Change Materials[J]. Materials Reports, 2025, 39(7): 23090077-14.

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https://www.mater-rep.com/EN/10.11896/cldb.23090077 OR https://www.mater-rep.com/EN/Y2025/V39/I7/23090077

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