1ST CONFERENCE ON RESEARCH AND APPLICATION OF ADVANCED CEMENTITIOUS MATERIALS |
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Synergistic Effect of Nano Silica and Fly Ash on the Cement-based Materials |
ZHANG Xiuzhi1,2, LIU Mingle1,2, DU Xiaohan3, YANG Xiangzi1,2, ZHOU Zonghui1,2
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1 School of Materials Science & Engineering, University of Jinan, Jinan 250022; 2 Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, Jinan 250022; 3 School of Civil and Transportation Engineering, Hebei University of Technology, Tianjin 300401 |
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Abstract The synergistic effect of nano silica and fly ash on cement based materials was studied by adjusting the ratio of nano SiO2 and fly ash. The results showed that the effect of nano silica and fly ash on cement is better than that of adding single nano silica. The early compressive strength reduction by fly ash can be compensated by adding 3% nano silica and less than 30% fly ash into mortar without the decrement of 28 days compressive strength. The drying shrinkage of mortar increased with the increase of nano SiO2, but the fly ash can relieve the drying shrinkage of nano SiO2. With the increase of nano silica, the freeze thaw resistance and chloride corrosion resistance of the specimens were improved, and 3% nanometer silica and 30%fly ash could further enhance the durability of cement-based materials. Nano SiO2 can shorten the induction period of cement hydration and accelerated the process of cement hydration, and the total heat release was increased when nano SiO2 was added. When adding nano SiO2 into the cement-fly ash system, the content of non evaporated water was increased obviously in the early stage, but the increment of the non evaporated water in the late stage was slow. The synergistic effect of nanosilica and fly ash improves the performance of cement mortar, which is beneficial to the performance complementarity.
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Published: 25 December 2017
Online: 2018-05-08
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1 Sarkar A, Sahani A K, Roy D K S, et al. Compressive strength of sustainable concrete combining blast furnace slag and fly ash[J]. IUP J Struct Eng, 2016,9(1):17. 2 Temuujin J, Ruescher C, Minjigmaa A, et al. Characterization of effloresences of ambient and elevated temperature cured fly ash based geopolymer type concretes[J]. Adv Mater Res, 2016,1139:25. 3 Criado M, Sobrados I, Bastidas J M, et al. Corrosion behaviour of coated steel rebars in carbonated and chloride-contaminated alkali-activated fly ash mortar[J]. Prog Org Coat, 2016,99:12. 4 Mehdipour I, Vahdani M, Amini K, et al. Linking stability characteristics to material performance of self-consolidating concrete-equivalent-mortar incorporating fly ash and metakaolin[J]. Constr Build Mater, 2016,105:206. 5 Chi M. Synthesis and characterization of mortars with circulating fluidized bed combustion fly ash and ground granulated blast-furnace slag[J]. Constr Build Mater, 2016,123:565. 6 Rong Z D, et al. Effects of nano-SiO2 particles on the mechanical and microstructural properties of ultra-high performance cementitious composites[J]. Cem Concr Compos, 2015,56:25. 7 Fallah S, Nematzadeh M. Mechanical properties and durability of high-strength concrete containing macro-polymeric and polypropylene fibers with nano-silica and silica fume[J]. Constr Build Mater, 2017,132:170. 8 Chithra S, Kumar S R R S, Chinnaraju K. The effect of colloidal nano-silica on workability, mechanical and durability properties of high performance concrete with copper slag as partial fine aggregate[J]. Constr Build Mater, 2016,113:794. 9 Shah S P, Hou P, Konsta-Gdoutos M S. Nano-modification of cementitious material: Toward a stronger and durable concrete[J]. J Sustainable Cement-Based Mater, 2016,5(1-2): 2. 10 Karoriya D, Gupta R. Performance of concrete with fly ash and kaolin inclusion[J]. Imperial J Interdisciplinary Res, 2016,2(7):179. 11Wang D, Yang P, et al. Effect of SiO2 oligomers on water absorption of cementitious materials[J]. Cem Concr Res, 2016,87:22. 12Shaikh F U A, Supit S W M. Chloride induced corrosion durability of high volume fly ash concretes containing nano particles[J]. Constr Build Mater, 2015,99:208. 13Liu M, Zhou Z, Zhang X, et al. The synergistic effect of nano-silica with blast furnace slag in cement based materials[J]. Constr Build Mater, 2016,126:624. 14Land G, Stephan D. The influence of nano-silica on the hydration of ordinary Portland cement[J]. J Mater Sci, 2012,47(2):1012. 15Xu Xun,Lu Zhongyuan. Effect of nano-silicon dioxide on hydration and hardening of portland cement[J]. J Chin Ceram Soc, 2007,35(4):478(in Chinese). 徐迅, 卢忠远. 纳米二氧化硅对硅酸盐水泥水化硬化的影响[J]. 硅酸盐学报, 2007,35(4):478. 16Zhang M, Li H. Pore structure and chloride permeability of concrete containing nano-particles for pavement[J]. Constr Build Mater, 2011,25(2):608. 17Zahedi M, Ramezanianpour A A, Ramezanianpour A M. Evaluation of the mechanical properties and durability of cement mortars containing nanosilica and rice husk ash under chloride ion penetration[J]. Constr Build Mater, 2015,78:354.18Lu Feifeng, Wu Yong, Gan Lifeng, et al. Effect of fly ash and admixtures on the hydration heat evolution process of portland cement[J]. Mater Rev: Res, 2011,25(3):124(in Chinese). 卢飞峰, 吴勇, 甘莉芬, 等. 掺粉煤灰和不同外加剂对水泥水化放热过程的影响[J]. 材料导报:研究篇, 2011,25(3):124. 19Zhu Hongbo, Wu Kaifan, Li Chen, et al. Nano coating fly ash by fluidized bed reactor vapordeposition (FBR-VD) and its hydration characteristics at early age[J]. J Build Mater, 2016,19(2):229. 20Neville A M. Properties of concrete[M]. 3th Edition. London: ELBS with Longman, 1981:275. 21Asgari H, Ramezanianpour A, Butt H J. Effect of water and nano-silica solution on the early stages cement hydration[J]. Constr Build Mater, 2016,129:12. |
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