| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress on Chemical Vapor Deposition Synthesis of Two-dimensional Layered Transition Metal Dichalcogenides Alloys and Heterojunctions with Low Symmetry |
| XING Huanhuan1,†, HU Ping1,†, LUO Zheng2, MAO Liqiu1, SHENG Liping1,*, WANG Shanshan2,*
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1 National Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
2 Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China |
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Abstract Two-dimensional (2D) transition metal chalcogenide (TMDs) alloys and heterojunctions with low symmetry are a class of functional nanomaterials with layered structure outside the plane and few symmetrical elements inside the plane. It not only shows rich adjustable electronic band structure, but also shows unique anisotropic physical properties in optics, electricity, mechanics, etc. so it has broad application prospects in the fields of polarized light detector, anisotropic logic circuit, tactile sensor and so on. The controllable preparation of low symmetry 2D TMDs alloys and heterojunctions is a prerequisite for their excellent properties. In this work, according to the different types of elements, the chemical vapor deposition of two-dimensional rhenium (Re)-base low-symmetry alloys and two-dimensional tellurium (Te) -base low-symmetry alloys is summarized. Then, according to the difference of heterostructures, the latest progress in the preparation of low symmetry two-dimensional TMDs heterojunctions is reviewed from the aspects of vertical heterojunctions and horizontal heterojunctions. Finally, the problems and challenges in this field are summarized and prospected.
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Published: 25 December 2024
Online: 2024-12-20
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| Fund:National Natural Science Foundation of China (52172032, 52222201), Young Elite Scientist Sponsorship Program by CAST (YESS20200222), Hunan Natural Science Foundation(2022JJ20044), State Administration of Science, Technology, and Industry for National Defense (WDZC20195500503), and National University of Defense Technology (ZK18-01-03). |
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2024, Vol. 38 
