POLYMERS AND POLYMER MATRIX COMPOSITES |
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Research Progress on Adsorption of Metal-organic Framework Based Materials for Heavy Metal Ions |
LI Tianze1,2, MA Yingxia1,*, LI Miaoshi1, YE Xiaofei1, CHAI Xiaojun2,*
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1 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, School of Materials Science & Engineering, Lanzhou University of Techno-logy, Lanzhou 730050, China 2 Gansu Academy of Eco-environmental Sciences, Lanzhou 730020, China |
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Abstract Metal-organic frameworks (MOFs), a kind of novel porous materials, have drawn significant attentions in research of water treatment field due to their characteristics such as high specific surface area, adjustable pore size and structure, facile surface modification and functiona-lization and so on. In recent years, many researchers have designed and synthesized a variety of MOFs materials and investigated their adsorption performance and adsorption mechanism for heavy metal ions in aqueous solution. In order to further improve the adsorption capacity, structural stability and adsorption selectivity, researchers have also developed various MOFs-based materials by introducing different functional groups or unsaturated metal sites into the MOFs to obtain modified MOFs materials, combining with other materials to construct MOFs composites, and post-processing the MOFs to prepare MOFs-derived carbon materials. This paper reviews the construction methods of MOFs materials, modified MOFs materials, MOFs composites and MOFs-derived carbon materials reported in recent years, expounds the adsorption performance for heavy metal ions in aqueous solution and the adsorption mechanisms, analyzes the current problems of the MOFs-based materials in the practical application, and prospects the key research directions in the future.
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Published: 10 December 2024
Online: 2024-12-10
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Fund:Key Project of the Natural Science Foundation of Gansu Province,China (23JRRA818). |
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