RESEARCH PAPER |
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Fabrication and Photoluminescence Property of ZnO Tetrapod and Multipod Nanostructures |
PENG Zhiwei, LIU Zhiyu, FU Gang
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School of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510006 |
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Abstract ZnO tetrapod and multipod nanostructures were successfully synthesized without the presence of carrier gas and ca-talyst through a simple thermal evaporation method. The morphology, structure and photoluminescence properties of ZnO nanostructures were characterized by field-emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy and fluorescence spectroscopy. The results demonstrated that the as-synthesized ZnO consisted of tetrapod and multipod nanostructures with a hexagonal wurtzite structure. The legs of the nanostructures had rod-like shape and grew preferably in the [0001] direction. The growth mechanisms of the ZnO tetrapod and multipod nanostructures were proposed. Room temperature photoluminescence (PL) spectra showed that the as-synthesized ZnO nanostructures had a strong green emission centered at 494 nm and a weak ultraviolet emission at 391 nm.
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Published:
Online: 2018-05-08
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1 Li J, Lin Y, Lu J F, et al. Single mode ZnO whispering-gallery submicron cavity and graphene improved lasing performance[J]. ACS Nano,2015,9(7):6794. 2 Hao Y H, Zhao J W, Qin L R, et al. Facile fabrication of UV photodetector based on spatial network of tetrapod ZnO nanostructures[J]. Micro Nano Lett,2012,7(3):200. 3 Tang X B, Li G M, Zhou S M. Ultraviolet electroluminescence of light-emitting diodes based on single n-ZnO/p-AlGaN heterojunction nanowires[J]. Nano Lett,2013,13(11):5046. 4 Zulkifli Z, et al. Highly transparent and conducting C∶ZnO thin film for field emission displays[J]. RSC Adv,2014,4(110):64763. 5 Rodrigues J, Cerqueira A F R, Sousa M G, et al. Exploring the potential of laser assisted flow deposition grown ZnO for photovoltaic applications[J]. Mater Chem Phys,2016,177:322. 6 Tang X S, Choo E S G, Li L, et al. Synthesis of ZnO nanoparticles with tunable emission colors and their cell labeling applications[J]. Chem Mater,2010,22(11):3383. 7 Xu S, Wang Z L. One-dimensional ZnO nanostructures: Solution growth and functional properties[J]. Nano Res,2011,4(11):1013. 8 Biswas I, Majumder M, Piyali Roy (Kundu), et al. Nanostructured ZnO thin film with improved optical and electrochemical properties prepared by hydrothermal electrochemical deposition technique[J]. Micro Nano Lett,2016,11(7):351. 9 Guo H L,Zhu Q,Wu X L,et al. Oxygen deficient ZnO1-x nanoshee-ts with high visible light photocatalytic activity[J]. Nanoscale,2015,7(16):7216. 10 Mousavi S H, et al. Growth and characterization of wurtzite ZnO nanocombs and nanosaws[J]. Mater Lett,2012,70:86. 11 Hussain S, Liu T, Kashif M, et al. Surfactant dependent growth of twinned ZnO nanodisks[J]. Mater Lett,2014,118(3):165. 12 Rakshit T, Manna I, Ray S K. Shape controlled Sn doped ZnO nanostructures for tunable optical emission and transport properties[J]. AIP Adv,2013,3(11):112112. 13 Peng Z W, Dai G Z, Zhou W C, et al. Photoluminescence and Raman analysis of novel ZnO tetrapod and multipod nanostructures[J]. Appl Surf Sci,2010,256(22):6814. 14 Bacsa R R, Jeannette D, Marc V, et al. Synthesis and structure-property correlation in shape-controlled ZnO nanoparticles prepared by chemical vapor synthesis and their application in dye-sensitized solar cells[J]. Adv Funct Mater,2009,19(6):875. 15 Najim M, et al. Ultra-wide bandwidth with enhanced microwave absorption of electroless Ni-P coated tetrapod-shaped ZnO nano- and microstructures[J]. Phys Chem Chem Phys,2015,17(35):22923. 16 Zhou X T, Lin T H, Liu Y H, et al. Structural, optical, and improved field-emission properties of tetrapod-shaped Sn-doped ZnO nanostructures synthesized via thermal evaporation[J]. ACS Appl Mater Interfaces,2013,5(20):10067. 17 Mishra Y K, Modi G, Cretu V, et al. Direct growth of freestanding ZnO tetrapod networks for multifunctional applications in photocatalysis, UV photodetection, and gas sensing[J]. ACS Appl Mater Interfaces,2015,7(26):14303. 18 Zhao Y N, Cao M S, Jin H B, et al. Catalyst-free synthesis, growth mechanism and optical properties of multipod ZnO with nanonail-like legs[J]. Scr Mater,2006,54(12):2057. 19 Silva R A, Orlandi M O. Influence of synthesis route on the radiation sensing properties of ZnO nanostructures[J]. J Nanomater,2016,2016(18):1. 20 Zhao G L, Xia L, Wu S S, et al. Ultrafast and mass production of ZnO nanotetrapods by induction-heating under air ambient[J]. Mater Lett,2014,118(3):126. 21 Lee C H, Chiu W H, Lee K M, et al. The influence of tetrapod-like ZnO morphology and electrolytes on energy conversion efficiency of dye-sensitized solar cells[J]. Electrochim Acta,2010,55(28):8422. 22 Jiang J Y, Li Y F, Tan S W, et al. Synthesis of zinc oxide nanotetrapods by a novel fast microemulsion-based hydrothermal method[J]. Mater Lett,2010,64(20):2191. 23 Umar A. Growth of multipod ZnO architectures made by accumulation of hexagonal nanorods for dye sensitized solar cell (DSSC) application[J]. J Nanosci Nanotechnol,2015,15(9):6801. 24 Alsultany F H, Hassan Z, Ahmed N M. Large-scale uniform ZnO tetrapods on catalyst free glass substrate by thermal evaporation method[J]. Mater Res Bull,2016,79:63. 25 Iwanaga H, Fujii M, Takeuchi S. Growth model of tetrapod zinc oxide particles[J]. J Cryst Growth,1993,134(3):275. 26 Dai Y, Zhang Y, Wang Z L. The octa-twin tetraleg ZnO nanostructures[J]. Solid State Commun,2003,126(11):629. 27 Zheng K, Xu C X, Zhu G P, et al. Formation of tetrapod and multipod ZnO whiskers[J]. Physica E,2008,40(8):2677. 28 Feng L B, Liu A H, Ma Y Y, et al. Structural and optical properties of ZnO whiskers grown on ZnO-coated silicon substrates by non-catalytic thermal evaporation process[J]. Physica E,2010,42(7):1928. |
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