INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Photo-Assisted Potentiodynamic Deposition and Photothermal Properties of Ni-CeO2 Black Protective Coatings |
WU Shiwei, YANG Yumeng*, DUAN Xuejia, LAN Shifeng, LI Shuming, ZHU Benfeng, WEI Guoying
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College of Materials and Chemistry, China Jiliang University, Hangzhou 310018, China |
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Abstract Nickel coatings, as important engineering materials, have been widely used in many industrial fields. Ceria, as an important rare earth oxide, has also attracted great attention of scholars. In this work, Ni-CeO2 composite black coatings were prepared by photo-assisted potentiodynamic deposition. The effects of light, deposition potential range and temperature on the structure, composition and properties of the coatings were studied. The coatings prepared under different conditions were characterized by cyclic voltammetry, Tafel polarization curves, contact angle measurement, stylus profiler, ultraviolet-visible-near-infrared spectrophotometer, dual-band emittance measuring instrument, scanning electron microscopy and energy dispersive spectrometry. The results show that the Ni-CeO2 composite black coating prepared at the deposition potential range of 0—-1.5 V, the temperature of 50 ℃ and with the photo illumination has the best comprehensive properties: the corrosion current density of 9.642 × 10-6 A·cm-2, water contact angle of 125.95°, the absorptivity above 94% and the emissivity of 0.592. When the deposition potential range is 0—-3.5 V, the coating has the highest emissivity of 0.757. Photo illumination not only affects the deposition rate of CeO2, but also significantly increases the deposition rate of Ni. This study provides an idea to prepare black composite coatings with high absorptivity and emissivity, which can be expected to be applied in photothermal conversion and optical instruments.
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Published: 25 July 2024
Online: 2024-08-12
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Fund:National Natural Science Foundation of China (52001300,52171083). |
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