NiFe<sub>2</sub>O<sub>4</sub>/rGO电极材料的制备及电催化HMF氧化性能研究

doi:10.11896/cldb.23110252

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Abstract The 2,5-furandicarboxylic acid (FDCA) synthesized by electro synthesis of 5-hydroxymethylfurfural (HMF) has a structure and properties similar to terephthalic acid, providing the possibility for developing biodegradable plastics and reducing white pollution. The NiFe₂O₄/rGO electrode material was successfully synthesized using CO₂ laser, and its microstructure presents a nano particle embedded graphene oxide structure. In situ Raman spectroscopy showed that compared with the Fe₅O₁₂/rGO electrode material, the NiFe₂O₄/rGO surface was reconstructed into NiOOH and FeOOH species during the HMF electrocatalytic oxidation process, confirming that the addition of Ni makes the material more prone to surface reconstruction. The surface reconstructed NiFe₂O₄/rGO electrode material showed a decrease in overpotential to 26 mV at 100 mA· cm^-2, and a decrease of approximately 182 mV compared to the oxygen production reaction (OER) overpotential. The electrode material after surface reconstruction has a larger specific surface area, which promotes the contact between reactants and electrode material. The conversion rate of reactants, selectivity of target products, and Faraday efficiency were 99.8%, 99.3%, and 87.6%, respectively. This study provides an effective approach for promoting surface reconstruction of catalytic materials through the addition of elements, thereby enhancing the electrocatalytic oxidation activity of HMF.

Key words： electrocatalysis CO₂ laser NiFe₂O₄/rGO electrode material surface reconstruction

Published: 25 July 2024 Online: 2024-08-12

CLC number:

O646.542

Fund:Funded Project of Shanxi Applied Basic Research Program (202203021222185), the Scientific Research Startup Fund of Taiyuan University of Science and Technology (20222092), the Excellent Award Fund of Taiyuan University of Science and Technology for Doctors Working in Shanxi (20232058), Taiyuan University of Science and Technology College Student Innovation and Entrepreneurship Project (XJ2023058).

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	Articles by authors
	WANG Honglei
	NIU Caiyun
	ZHU Hongyue
	LI Xiaoming
	ZHOU Dan
	SUN Zhigang
	HU Jifan
	YANG Changping

Cite this article:

WANG Honglei,NIU Caiyun,ZHU Hongyue, et al. Preparation of NiFe₂O₄/rGO Electrode Material and Its Electrocatalytic Performance for HMF Oxidation[J]. Materials Reports, 2024, 38(14): 23110252-6.

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http://www.mater-rep.com/EN/10.11896/cldb.23110252 OR http://www.mater-rep.com/EN/Y2024/V38/I14/23110252

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