利用吸附技术提取盐湖卤水中锂的研究进展<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.017.017

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Abstract The research progress of lithium extraction in salt lake brines by inorganic adsorbents is reviewed. The principle of extracting lithium and development status of aluminum based adsorbent, layered ion exchange adsorbent, titanium, antimony and manganese based lithium ionic sieves are described in detail. The advantages and the deficiencies in the process of extracting lithium of all kinds of adsorbents are pointed out according to their structural characteristics, and the corresponding improvement measurements are also proposed. As a new, efficient and green agent for lithium extraction, manganese based adsorbents show good development prospect. The preparation methods and doping modification of manganese oxides lithium ion sieve are discussed, and the development prospects are also expounded.

Key words： salt-lake brines adsorption extract lithium ionic sieve

Published: 10 September 2017 Online: 2018-05-07

CLC number:

TB383

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	Articles by authors
	XU Naicai
	SHI Dandan
	LI Sixia
	LIU Zhong
	DONG Yaping
	LI Wu

Cite this article:

XU Naicai,SHI Dandan,LI Sixia, et al. Advances in Extracting Lithium from Salt-lake Brines by Adsorption Technique[J]. Materials Reports, 2017, 31(17): 116-121.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.017.017 OR https://www.mater-rep.com/EN/Y2017/V31/I17/116

1 Dai Z X, Li S Z.Irresistible trend—Extracting lithium resources from salt Lakes[J]. J China Univ Geosci,1999,260(1):45(in Chinese).
戴自希, 李树枝. 不可抗拒的趋势——从盐湖中提取锂资源[J].中国地质,1999,260(1):45.
2 Li L, Liu F, Wu F, et al. Progress of research on the manganese oxide ion-sieve for extracting lithium [J]. J Inorg Mater,2012,27(10):1009(in Chinese).
李丽, 刘芳, 吴峰, 等. 提锂用锰氧化物离子筛的研究进展[J]. 无机材料学报,2012,27(10):1009.
3 Swain B. Recovery and recycling of lithium: A review [J]. Sep Purif Technol,2017,172:388.
4 Song S T, Deng X C, Sun J Z. Research of preparation and use of lithium hydroxide [J]. J Salt Lake Res,2005,13(2):60(in Chinese).
宋士涛, 邓小川, 孙建之. 卤水制备氢氧化锂研究进展[J]. 盐湖研究,2005,13(2):60.
5 Liu G. Research on the extracting of Li⁺ by precipitation of Al(OH)₃ and the recycling of aluminum [D]. Chengdu:Chengdu University of Technology,2011(in Chinese).
刘高. 氢氧化铝沉淀法提锂工艺及铝的循环利用研究[D].成都:成都理工大学,2011(in Chinese).
6 Bauman, William C. Recovery of lithium from brines: US,5599516[P].1997.
7 Bauman, William C. Composition from the lithium values from brine and process of making using said composition [P]. Compiler: US,6280693[P].2001.
8 Dong Q, Li Y J, Piao X L,et al. Recovery of lithium from salt Lake bittern using aluminum salt adsorbent [J]. Chin J Rare Metals,2007,31(3):357(in Chinese).
董茜, 李燕杰, 朴香兰, 等. 铝盐吸附剂从盐湖卤水中吸附锂的研究[J].稀有金属,2007,31(3):357.
9 Li J, Xiong X B. Current research status and prospect of extraction of lithium from salt Lake brine with aluminum salt based sorbent [J]. Inorg Chem Ind,2010,42(10):9(in Chinese).
李杰, 熊小波. 铝盐吸附剂盐湖卤水提锂的研究现状及展望[J]. 无机盐工业,2010,42(10):9.
10 刘树仁. 用氧化锑作锂的吸附剂效率高[J]. 有色冶炼,1984,2(15):8.
11 Feng Q, Kanoh H, Oil K. Manganese oxide porous crystals[J]. J Mater Chem,1999,9:319.
12 Wang X M. Study on extracting lithium ion from saline bittern water [D]. Fuzhou:Fujian Normal University,2008(in Chinese).
王小敏. 盐湖卤水中提取锂离子的研究[D]. 福州:福建师范大学,2008.
13 Krepel D, Hod O. Lithium adsorption on armchair graphene nano-ribbons[J]. Surf Sci,2011,605:1633.
14 Xu B, Wang L, Chen H J, et al. Adsorption and diffusion of lithium on 1T-MoS₂ monolayer[J]. Comp Mater Sci,2014,93:86.
15 Yan S W, Zhong H, et al. Preparation for the granulated titanium dioxide inorganic ion-exchange and recovery of lithium of lithium from brine [J]. Ion Exchange Adsorpt,1994,10(3):219(in Chinese).
闫树旺, 钟辉,等. 粒状二氧化钛交换剂的研制及从卤水中提锂[J]. 离子交换与吸附,1994,10(3):219.
16 Zhang L Y, Zhou D L, et al. Preparation of H₂TiO₃-lithium adsorbent by the sol-gel process and its adsorption performance[J]. Appl Surf Sci,2016,368:82.
17 Zheng C H. Synthesis of new composite based on titanium and study on lithium adsorption property [D]. Qingdao: Qingdao University of Science and Technology,2007(in Chinese).
郑春辉. 新型含钛复合物的合成及其体力性能研究[D]. 青岛:青岛科技大学,2007.
18 Zheng J G. Study on the preparation and Li⁺ adsorption exchange property of titanium and zirconium compound oxides [D]. Qingdao: Qingdao University of Science and Technology,2016(in Chinese).
郑建国. 钛、锆复合氧化物的合成及对Li⁺的吸附交换性能研究[D]. 青岛:青岛科技大学,2016.
19 阿部光雄,等编. 当代离子交换技术[M].王元,等译.北京: 化学工业出版社,1993.
20 Chitrakar R, Sonoda A, Sakane K. A new type of manganese oxide(MnO₂·0.5H₂O) derived from Li_1.6Mn_1.6O₄ and its Li ion sieve properties [J]. Chem Mater,2000,12:3151.
21 Xiao X L, Dai Z F, Zhu Z H, et al. Extracting lithium from brines by absorption method [J]. J Salt Lake Res,2005,13(2):66(in Chinese).
肖小玲, 戴志锋, 祝增虎, 等. 吸附法盐湖卤水提锂的研究进展[J]. 盐湖研究,2005,13(2):66.
22 Bai L H. Study on solvothermal synthesis and Li-storage properties of antimony-based materials [D]. Lanzhou:Northwest Normal University,2013(in Chinese).
白莲花. 锑基材料的溶剂热制备及其储锂性能研究[D]. 兰州:西北师范大学,2013.
23 Xiao J L, Nie X Y, Sun S Y. Lithium ion adsorption-desorption properties on spinel Li₄Mn₅O₁₂ and pH-dependent ion-exchange model [J]. Adv Powder Technol,2015,26(2):589.
24 Yan H W, Huang X J, Chen L Q. Microwave synthesis of LiMn₂O₄cathode material[J]. J Power Sources,1999,81-82:647.
25 Xu H, Chen C G, Song Y H. Synthesis and properties of lithium ion-sieve precursor Li₄Mn₅O₁₂ [J]. J Inorg Mater,2013,28(7):720(in Chinese).
许慧,陈昌国,宋应华. 锂离子筛前驱体Li₄Mn₅O₁₂的制备及性能研究[J]. 无机材料学报,2013,28(7):720.
26 Michalska M, Lipinska L, Mirkowska M. Nanocrystalline lithium-manganese oxide spinels for Li-ion batteries—Sol-gel synthesis and characterization of their structure and selected physical properties [J]. Solid State Ionics,2011,188(1):160.
27 Feng Q, Miyai Y, Kanoh H. Li⁺ and Mg²⁺ extraction and Li⁺ insertion reactions with LiMg_0.5Mn_1.5O₄ spinel in the aqueous phase [J]. Chem Mater,1993,5(3):311.
28 Zhang Q H, Li S P, Sun S Y. LiMn₂O₄ spinel direct synthesis and lithium ion selective adsorption [J]. Chem Eng Sci,2010,65(1):169.
29 Ji Z Y, Yuan J S, Li X G. Synthesis of Li-adsorbent and its adsorption property [J]. Chem Eng,2007,35(8):9(in Chinese).
纪志永, 袁俊生, 李鑫钢. 锂吸附剂的合成及其吸附性能[J]. 化学工程,2007,35(8):9.
30 Dong D Q, Liu W N, Liu Y F. Synthesis of LiNi_0.05Mn_1.95O₄ and its ion-exchange thermodynamics for Li⁺ [J]. Acta Phys-Chim Sin,2009,25(7):1279(in Chinese).
董殿权, 刘维娜, 刘亦凡. LiNi_0.05Mn_1.95O₄的合成及其对Li⁺的离子交换热力学[J]. 物理化学学报,2009,25(7):1279.
31 Hagh N M, Amatucci G G. Effect of cation and anion doping on microstructure and electrochemical properties of the LiMn_1.5Ni_0.5O_4-δ spinel [J]. J Power Sources,2014,256:457.
32 Chen B Z, Ma L W, Shi X C, et al. Research progress on preparation methods for precursors of lithium ion-sieve [J]. Inorg Chem Ind,2009,41(7):1(in Chinese).
陈白珍, 马立文, 石西昌, 等. 锂离子筛前驱体制备方法的研究进展[J]. 无机盐工业,2009,41(7):1.
33 Lee H R, Lee B, Chung K Y. Scalable synthesis and electrochemical investigations of fluorine-doped lithium manganese spinel oxide [J]. Electrochim Acta,2014,136:396.
34 Dong D Q, Liu W N, Wu Y F, et al. Synthesis of spinal Ni-doped manganese oxide lithium ion-sieve by sol-gel method [J]. J Qingdao Univ Technol,2009,30(4):288(in Chinese).
董殿权, 刘维娜, 吴延芳,等. 溶胶-凝胶法制备尖晶石结构镍锰氧化物型锂离子筛[J]. 青岛科技大学学报,2009,30(4):288.
35 Ma L W, Chen B Z, et al. Al-doped lithium manganese oxide: Pre-paration and stability in acid medium [J]. Chin J Inorg Chem,2010,26(3):413(in Chinese).
马立文, 陈白珍, 等. LiAl_xMn_2-xO₄的制备及其在酸介质中的稳定性[J]. 无机材料学报,2010,26(3):413.
36 Qin Y H, Ma S D, Zhang Y K. Preparation and electrochemical property of Ti doped LiMn₂O₄ [J]. J Funct Mater,2007,38(10):1658(in Chinese).
秦毅红, 马尚德, 张云可. 钛掺杂尖晶石LiMn₂O₄的制备及电化学性能[J]. 功能材料,2007,38(10):1658.
37 Tian L Y, Ma W, Han M. Adsorption behavior of Li⁺ onto nano-lithium ion sieve from hybrid magnesium/lithium manganese oxide [J]. Chem Eng J,2010,156(1):134.
38 Zhou H M, Yuan J S, Zhang L, et al. Hydrothermal synthesis of doped chromium spinel-type lithium ion-sieve and its lithium absorption properties [J]. J Funct Mater,2010,42(Z-VI):621(in Chinese).
周慧敏, 袁俊生, 张亮,等. 水热法合成铬掺杂尖晶石型锂离子筛及其锂吸附性能[J]. 功能材料,2010,42(Z-VI):621.
39 Lu H Y. Studies on the preparation of spinel Li_1.6Mn_1.6O₄ and lithium ion-sieve adsorption properties [D]. Xiangtan:Xiangtan University,2011(in Chinese).
陆红岩. 尖晶石型Li1.6Mn1.6O4的制备及锂离子筛吸附特性研究[D]. 湘潭:湘潭大学,2011.
40 Yu X Y, Yu S X, Zhou W Y, et al. Synthesis and characterization of Cr-doping modified spinel LiMn_2-xCr_xO_4-3xF_3x as cathode materials [J]. J Chin Ceram Soc,2010,38(6):1053(in Chinese).
禹筱元, 余仕禧, 周武艺, 等. 复合掺杂改性LiMn_2-xCr_xO_4-3xF_3x正极材料的制备及性能[J]. 硅酸盐学报,2010,38(6):1053.
41 Dong Q, Piao X L, Zhu S L. Adsorption techniques and progress on the extraction of lithium from salt lake brines [J]. J Salt Chem Ind,2007,36(3):31(in Chinese).
董茜, 朴香兰, 主慎林. 从盐湖卤水中提取锂的吸附技术及研究进展[J]. 盐业与化工,2007,36(3):31.
42 Shiu J Y, Lin J R, Lee D C, et al. Method for adsorbing lithium ions from a lithium containing aqueous solution by a granular adsorbent: US,2003231996[P].2003.